• Journal of the Korean Chemical Society
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• v.60 no.6
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• pp.410-414
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• 2016

The anharmonic frequency of a local OH stretching mode of a water monomer and dimer was calculated using various levels of density functional theory. The quantum chemical potential energy curves as a function of the OH bond distance were calculated, and they were fitted with the Morse potential function to analytically obtain the fundamental transition frequency. By comparing those values with the frequencies similarly calculated using an ab initio quantum chemical method, the coupled cluster theory including both single and double excitations with the perturbative inclusion of triple excitation in the complete basis limit, the accuracy of various density functional methods in the calculation of anharmonic vibration frequency of water molecules was assessed. For a water monomer, X3LYP and B3LYP methods give the best accuracy, whereas for a water dimer, B972, LCBLYP, ${\omega}B97X$, ${\omega}B97$ methods show the best performance.

• Journal of the Korean Chemical Society
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• v.24 no.6
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• pp.457-462
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• 1980

Phosphates and phosphoric amides were synthesized by the reaction of phosphoryl chloride with allyl alcohol, 2,3-dibromopropanol, 2-pyrrolidone and ethylenimine. All of these compounds were thermally very unstable. Allyl phosphorodichoridate and diallyl phosphorochloridate gave significant amount of polymeric products when they were distilled. IR spectra showed characteristic P=O stretching bands between 1300 and $1200 cm^{-1}$ and NMR spectra were very complicated due to the long range coupling effect of phosphorus atom. And mass spectrum of 2,3-dibromopropyl phosphorodichloridate gave no indication of molecular ion peak.

• Journal of Computational Design and Engineering
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• v.3 no.4
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• pp.330-336
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• 2016

The present work is concerned with heat and mass transfer of an electrically conducting second grade MHD fluid past a semi-infinite stretching sheet with convective surface heat flux. The analysis accounts for thermophoresis and thermal radiation. A similarity transformations is used to reduce the governing equations into a dimensionless form. The local similarity equations are derived and solved using Nachtsheim-Swigert shooting iteration technique together with Runge-Kutta sixth order integration scheme. Results for various flow characteristics are presented through graphs and tables delineating the effect of various parameters characterizing the flow. Our analysis explores that the rate of heat transfer enhances with increasing the values of the surface convection parameter. Also the fluid velocity and temperature in the boundary layer region rise significantly for increasing the values of thermal radiation parameter.

• Journal of computational fluids engineering
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• v.11 no.3 s.34
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• pp.14-21
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• 2006

A numerical simulation of the binary collision dynamics of water drops for size ratios of 1 and 0.75, for the Weber number range of 5 to 100, and for all impact parameter is reported. Two different types of separating collisions, namely reflexive and stretching separations, are identified. A numerical method is based on a fractional-step method with a finite volume formulation and the interface is tracked with Volume of Fluid(VOF) method, including surface tension. Numerical results for size ratios 1 and 0.75 are reasonablely compared with Ashgriz and Poo's experimental results.

• Proceedings of the Korea Inteligent Information System Society Conference
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• 2007.05a
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• pp.365-372
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• 2007

본 논문에서는 콘크리트 표면 균열 영상에서 균열의 특징들을 추출하기 위하여, 영상 처리 기법을 개선하여 균열의 특징(길이,폭,방향)들을 자동으로 추출 및 분석 할 수 있는 기법을 제안한다. 기존의 영상 처리 기법에서는 비교적 잡음이 적고 균열이 적은 영상을 대상으로 균열을 추출하는 알고리즘을 제시하였기 때문에 많은 잡음과 균열을 가지는 영상에 대해서는 균열 검출 성능이 떨어지는 경향이 있다. 따라서, 본 논문에서 제안한 균열 추출 및 분석 알고리즘은 컬러 영상에서 Histogram Stretching 기법을 적용하여 영상의 콘트라스트 특성을 향상 시킨 후, Robert 연산자를 다시 적용해 균열을 강조하고, 강조된 균열을 Multiple 연산을 이용하여 밝기 차이를 크게 한 후, 개선된 적응 이진화기법을 이용하여 균열의 후보 영역을 추출한다. 추출된 균열 후보 영역을 형상 분석과 위치 및 방향분석을 이용하여 잡음을 제거하고 균열의 특징을 분석한다. 실제 콘크리트 표면 균열 영상을 대상으로 실험한 결과, 균열 검출 성능이 기존의 방법보다 본 논문에서 제안한 방법이 더 우수함을 확인하였다.

• Proceedings of the KSME Conference
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• 2007.05a
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• pp.1045-1050
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• 2007

Equations of motion of rotating cantilever curved beams are derived based on a dynamic modeling method developed in this paper. The Kane's method is employed to derive the equations of motion. Different from the classical linear modeling method which employs two cylindrical deformation variables, the present modeling method employs a non-cylindrical variable along with a cylindrical variable to describe the elastic deformation. The derived equations (governing the stretching and the bending motions) are coupled but linear. So they can be directly used for the vibration analysis. The coupling effect between the stretching and the bending motions which could not be considered in the conventional modeling method is considered in this modeling method. The natural frequencies of the rotating curved beams versus the rotating speed are calculated for various radii of curvature and hub radius ratios.

• Transactions of the Korean Society of Automotive Engineers
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• v.2 no.1
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• pp.73-83
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• 1994

Press formabilities of aluminum sheets for automobile body were investigated. Plane strain stretching test (called RIST-PSST), cupping test and U bending test were performed to assess the press formability of aluminum sheets respectively. The results showed that aluminum sheets are generally inferior to cold-rolled steel sheet of deep drawing quality (CSP3N) in press formability. The limiting punch height (LPH) and limiting plane strain (FLCo) of aluminum sheets are 50%-70% level compared to that of CSP3N. Moreover, the limiting drawing ratios(LDR) of aluminum sheets are ranged between 1.95 and 2.1. The poor press formability of aluminum sheets is responsible for low values of total elongation and plastic anisotropy parameter in tensile characteristic. The shape fixability of aluminum sheets evaluated in U bending test is very poor due to its low elastic modulus compared to CSP3N.

• Journal of the Korean Society for Industrial and Applied Mathematics
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• v.19 no.1
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• pp.83-102
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• 2015

The present paper analyses the radiation effects of mass transfer on steady nonlinear MHD boundary layer flow of a viscous incompressible fluid over a nonlinear porous stretching surface in a porous medium in presence of heat generation. The liquid metal is assumed to be gray, emitting, and absorbing but non-scattering medium. Governing nonlinear partial differential equations are transformed to nonlinear ordinary differential equations by utilizing suitable similarity transformation. The resulting nonlinear ordinary differential equations are solved numerically using Runge-Kutta fourth order method along with shooting technique. Comparison with previously published work is obtained and good agreement is found. The effects of various governing parameters on the liquid metal fluid dimensionless velocity, dimensionless temperature, dimensionless concentration, skin-friction coefficient, Nusselt number and Sherwood number are discussed with the aid of graphs.

• Macromolecular Research
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• v.10 no.2
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• pp.127-134
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• 2002

Microporous polypropylene hollow fiber membrane was fabricated from isotactic polypropylene-soybean oil system by melt spinning process. Addition of nucleating agent accelerated the crystallization rate and elevated the crystallization temperature. Nucleating agent increased the number of nuclei and spherulites, which offered more inter-spherulitic amorphous sites for stretching. Benzoic acid, adipic acid, and dibenzylidene sorbitol were selected as nucleating agents, and their characteristics and effects were investigated by thermal and optical analyses. Spherulite growth and micropore formation characteristics were correlated with the kind of nucleating agent. Benzoic acid and adipic acid showed the remarkable nucleating effect, while dibenzylidene sorbitol was less effective than those. Nucleating agents also helped the sample have uniform microporous structure. Increase of nucleating agent composition enhanced the nucleation effect to some extent. Nucleating agents played very important roles in enhancing the membrane porosity and water flux.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2004.05a
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• pp.400-403
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• 2004

A non-heat기leafed steel does not need quenching and tempering processes that are called a heat treatment differently from conventional steel. Since the tensile strength of this steel is higher than 900MPa, a conventional forming process should be changed to incremental forming process such as a cross wedge rolling that requires lower load capacity than conventional ones. In this paper, the cold cross wedge rolling (CWR) die has been designed using CAD/CAE In order to produce near-net-shaped component of ball stud of non-heat-treated cold steel. Finite element analyses were applied in order to investigate process parameters of CWR. Results provide that the stretching angle and the forming angie at knifing zone in CWR process is important parameter to be the stable process under the low friction coefficient condition.