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Effects of Si Addition on the Microstructure and Properties of Cr-Al alloy for High Temperature Coating (고온 코팅용 Cr-Al합금의 미세조직 및 특성에 미치는 Si 첨가의 영향)

  • Kim, Jeong-Min;Kim, Il-Hyun;Kim, Hyun-Gil
    • Korean Journal of Materials Research
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    • v.29 no.1
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    • pp.7-10
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    • 2019
  • Cr-Al alloys are attracting attention as oxidation resistant coating materials for high temperature metallic materials due to their excellent high temperature stability. However, the mechanical properties and oxidation resistance of Cr-Al alloys can be further enhanced, and such attempts are made in this study. To improve the properties of Cr-Al alloys, Si is added up to 5 wt%. Casting specimens with different amounts of Si content are prepared by a vacuum arc remelting method and isothermally heated under steam conditions at $1,100^{\circ}C$ for 1 hour. The as-cast microstructure of low Si alloys is mainly composed of only a Cr phase, while $Al_8Cr_5$ and $Cr_3Si$ phases are also observed in the 5 % Si alloy. In the high Si alloy, only Cr and $Cr_3Si$ phases remain after the isothermal heating at $1,100^{\circ}C$. It is found that Si additions slightly decrease the oxidation resistance of the Cr-Al alloy. However, the microhardness of the Cr-Al alloy is observed to increase with an increasing Si content.

Improvement of Paper Strength using Pretreated Precipitated Calcium Carbonate (PCC) (종이의 강도향상을 위한 경질탄산칼슘(PCC) 전처리에 대한 연구)

  • Kim, Chul-Hwan;Lee, Ji-Young;Gwak, Hye-Joeng;Chung, Ho-Kyung;Back, Kyung-Kil;Lee, Hui-Jin;Kim, Sung-Ho;Kang, Ha-Ryoun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.1
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    • pp.41-47
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    • 2010
  • Increasing ash content of the paper is one of the most effective methods for saving raw materials and steam consumption and improving optical properties and better print quality. However, the increase of filler loading or filler content using a conventional wet end system is limited due to severe loss in strength properties, affecting runnability and product quality. This is because the filler has no ability to make bonding with cellulosic fibers. Therefore, if the technology to give filler the bonding ability is developed, the ash content of the paper can be increased more than ever. This study was carried out to modify PCC by coating its surface with starch contributing to better bonding with fibers. To prepare the modified PCC, cationic starch was selected as a polymer and then pretreatment was done by mixing PCC and cationic starch. Consequently, the pretreated PCC contributed to higher tensile strength, stiffness and opacity than the conventional filler, such as GCC and untreated PCC. However, CIE whiteness and ISO brightness decreased slightly compared to conventional fillers.

Characteristics of egg coagulates cooked conventionally or by microwaves (Microwave 처리가 알찜의 품질 특성에 미치는 영향)

  • Oh, Hae-Sook;Myoung, Choon-Ok
    • Korean journal of food and cookery science
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    • v.10 no.4
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    • pp.351-356
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    • 1994
  • Comparisions were made for cooking times, internal temperatures, thiamin contents and textural properties of various portion weights of egg mixture cooked in a microwave oven at high and/or low power levels and in a conventional double boiler. The mean internal temperatures of conventionally cooked egg mixtures were 76.4~80.7$^{\circ}C$. When cooking was made by steaming, the mean internal temperature were comparable among samples. With the microwave cooking, the range of mean temperature was 83.8~96.4$^{\circ}C$, and they were significantly higher than the conventionally cooked egg mixtures. The hardness determination was conducted using universal testing machine and a taste panel. Samples cooked with steam or with larger portion weight had softer texture than samples cooked by microwaves or smaller amount, respectively. Mean internal temperature was significantly(r=0.99, p<0.05) correlated with mechanical hardness determination. Statistical analyses indicated no significant difference in the thiamin content among various treatments.

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The Anti-Corrosion Properties of Coated Reinforcing Bar Using Polymer Cement Slurry (폴리머 시멘트 슬러리에 의한 철근의 방청성능)

  • 김영집;김연홍;윤보원;조영국;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.05a
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    • pp.201-206
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    • 2002
  • The purpose of this study is to improve the anti-corrosive properties of coated reinforcing bar using polymer cement slurry. Poymer cement slurry are prepared with three types of polymer dispersions and corrosion inhibiting admixture. And tested for corrosion accelerating tests such as immersion in NaCl 10% solution NaCl 10% solution spray, high temperature and pressure steam in condition of 8cycles, carbonation before and after, penetration of NaCl solution. From the test results, it is concluded that the anti-corrosive properties are considerably improved by coating using polymer cement slurry at surface of reinforcing bar. And this trend is marked by adding of corrosion inhibiting admixture. The difference of the anti-corrosive properties is hardly recognized according to types of polymer dispersions. The anti-corrosive properties of coated reinforcing bar using polymer foment slurry are improved to a great extent compared to those of plain reinforcing bar accordiy to increasing content of chloride ion in cement concrete.

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Analysis of Volatile Flavor Components of Pimpinella brachycarpa (참나물의 휘발성 향기성분 분석)

  • 송희순;최향숙;이미순
    • Korean journal of food and cookery science
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    • v.13 no.5
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    • pp.674-680
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    • 1997
  • Volatile flavor components of fresh, shady air dried, and presteamed shady air dried Chamnamul (Pimpinella brachycarpa) were collected by simultaneous steam distillation-extraction method, and essential oils were analyzed by gas chromatography-mass spectrometry (GC/MS). Twenty five, 17 and 23 volatile flavor components were identified in essential oils extracted from the fresh, shady air dried, and presteamed shady air dried Chamnamul samples, respectively; however, the kinds of individual components and its percent content of the total volatiles were varied depending on samples. The principal components of Chamnamul were isobutanal, trans caryophyllene, trans ${\beta}$-farnesene, and ${\alpha}$-selinene. Terpenoid compounds reached 44.11%, 33.91% and 72.63% respectively in fresh, shady air dried, and presteamed shady air dried Chamnamul.

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Hydrothermal Pre-treatment and Gasification of Solid Wastes to Produce Electrical Power and Hydrogen

  • Yoshikawa, Kunio
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2006.09a
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    • pp.3-12
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    • 2006
  • The main feature of these total technologies is that we can constitute the optimum treatment scheme fitting to the property of wastes, amount of wastes and energy requirement. For high moisture content wastes or biomass resources, high pressure steam process (MMCS) for crush, dry and deodorize wastes to produce high quality fertilizer of fuel is most appropriate. For dry or semi-dry solid wastes, the STAR-MEET system can be applied to produce low-BTU gases for power generation using duel fueled diesel engines of Stirling engines, and the REPRES and HyPR-MEET systems can be applied to produce hydrogen rich medium-BTU gas. For waste plastics and oils, liquefaction technology is best fit to produce light oil or kerosene equivalent fuel oils. These total technologies are completely different from the existent waste treatment technologies based on land-filling or incineration, and are expected to disseminate all over the world in the near future.

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Water tree growing and Electrical breakdown Characteristics of XLPE/SXLPE blends (XLPE/SXLPE 블렌드의 수트리 성장 및 절연파괴 특성)

  • 고정우;서광석
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.55-58
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    • 1999
  • Crosslinked polyethylene/silane crosslinked polyethylene (XLPE/SXLPE) blends were prepared by a twin screw extruder and their water tree growing and electrical breakdown characteristics of XLPE were improved by the addition of SXLPE, when samples were crosslinked only by the thermorolysis of DCP (dicumyl perosxide). However, steam curing process was not good for water tree characteristics. It was also found that the rate of water tree growing of XLPE/SXLPE blend increased when the content of SXLPE was 50 %. AC breadown strength slightly increased by the addition of SXLPE to XLPE when samples were crosslinked only by the thermorolysis of DCP.

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Adsorption of nitrate onto nitrogen-doped activated carbon fibers prepared by chemical vapor deposition

  • Yoo, Pyunghwa;Amano, Yoshimasa;Machida, Motoi
    • Korean Journal of Chemical Engineering
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    • v.35 no.12
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    • pp.2468-2473
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    • 2018
  • Nitrogen-doped activated carbon fibers (ACFs) were prepared by chemical vapor deposition using melamine powder and acetonitrile for introducing quaternary nitrogen on the commercial ACFs, subsequently heated at $950^{\circ}C$ and activated by steam. Adsorption experiments of nitrate in aqueous solution were also conducted to evaluate adsorption capacity of the prepared ACFs using ion chromatography. The amount of introduced nitrogen content and nitrogen species on activated carbon fibers was examined by CHN elemental analyzer and X-ray photoelectron spectroscopy, respectively. As a result, adsorption capacity of quaternary nitrogen-doped ACF (ST-ML-AN-ST) was 0.75 mmol/g, indicating ca. two-times higher than that of untreated ACF (0.38 mmol/g). According to the adsorption data, the Langmuir isotherm model was the best fit. The prepared samples were also regenerated using hydrochloric acid. After regeneration, the adsorption capacity of the nitrogen-doped ACF (ST-ML-AN-ST) showed ca. 80% on average, implying that a portion of nitrates was adsorbed on the prepared ACFs irreversibly.

Basic Characterization of Resource-recycling Secondary Products of Cement by Using Sludge Solids as The Main Material (회수수 슬러지 고형분을 주재료로 한 자원순환형 시멘트 2차 제품 생산의 기초적 특성 평가)

  • Kim, Min-Sung;Hong, Sung-Jun;Kim, Young-Jin;Ryu, Dong-Woo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.118-119
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    • 2021
  • In this study, we confirmed the basic characteristics of paste and mortar 1:1, 1:2, 1:3 composition using concrete sludge solid content for the purpose of developing a resource-recycling cement secondary products. The 1:2 mortar formulation showed the best compressive strength. The steam curing strength is superior in the order of C20, BS40, BS20 and Control. it is judged that the FA combination is not suitable.

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GC-MS and GC-FID Analysis of Citronella Oil Products for Indicator Ingredient Identification

  • Sumin Kang;Wooil Kim;Jin Wuk Lee;Sangwon Cha
    • Mass Spectrometry Letters
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    • v.14 no.4
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    • pp.160-165
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    • 2023
  • Citronella oil, an essential oil extracted through steam distillation from the leaves and stems of Cymbopogon, is a natural complex substance (NCS) regulated by the Korean government for its use in insect repellents. The component ratios of NCSs like citronella oil vary due to differences in manufacturing processes and origins, presenting a challenge in identifying and quantifying these substances in consumer chemical products. This study analysed ten commercially available products of the most commonly used types of citronella oil, specifically Java and Ceylon types, using gas chromatography (GC)-mass spectrometry (MS) and GC with flame ionization detection (FID). Through chromatographic data, we aimed to determine the components that can qualitatively identify citronella oil and the indicator ingredients that can be used for content analysis.