• Title/Summary/Keyword: SR

Search Result 4,857, Processing Time 0.033 seconds

Preparation of High Purity $SrTiO_3$ by Coprecipitation and Strontium Titanyl Oxalates (공심법과 (Sr-Ti)수산염에 의한 고순도의 $SrTiO_3$ 합성에 관한 연구)

  • 이종권;이병하
    • Journal of the Korean Ceramic Society
    • /
    • v.20 no.2
    • /
    • pp.107-114
    • /
    • 1983
  • Formation of Strontium titanate from the products of coprecipitation takes place at 110$0^{\circ}C$ which is 200-30$0^{\circ}C$ lower than that from mechanical mixtures of $SrCO_3$ and $TiO_2$. This is apparently due to the nature of the compounds formed by the reaction of mixtures of aqueous solutions of $SrCl_2$ and $TiCl_4$ with an ammoniacal solution of ammoni-um carbonate and ammonium hydroxide. A procedure is described for preparing strontium titanyl oxalate tetrahydrate in the several mole ratio of $TiCl_4$ to $SrCl_2$. STrontium titanyl oxalates decompose to titanate at elevated temperature. The coprecipitates and the fired specimen were subjected to examined thermal and X-ray analyses and microstruc-ture by SEM.

  • PDF

Development of BiPbSrCaCuO Superconductor by Diffusion of Dual-Layer Sample (이중층 시료에서 확산에 의한 BiPbSrCaCuO 초전도체 개발)

  • 최성환;박성진;유현수;강형곤;한병성
    • The Transactions of the Korean Institute of Electrical Engineers
    • /
    • v.43 no.5
    • /
    • pp.795-801
    • /
    • 1994
  • The BiPbSrCaCuO superconductor was fabricated by diffusion of The dual layer composed of SrS12TCaS11TCuS12TOS1xT in upper layer and BiS12TPbSI0.3TCuS12TOS1yT in lower layer, and varified growh-mechanism of BiPbSrCaCuO superconducting phase. And, we produced optimum conditions of spread volume and each stage of sintering time were upper layer:Lower layer=1:0.2, 1:0.4, 1:0.6 and 24hr., 120hr., 210hr. From the result, the optimum conditions are spread volume(Upper layer:Lower layer=1:0.6), sintering time(210hrs.) at 820$^{\circ}C$.The BiPbSrCaCuO superconductor, fabricated optimum condition, showed zero resistance at critical temperature of 70k.

Preparation and Luminescent Properties of (Sr,Ba)TiO3:Pr, Al Phosphors ((Sr,Ba)TiO3:Pr,Al 형광체의 제조와 발광특성)

  • Park, Chang-Sub;Yu, Il
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.21 no.9
    • /
    • pp.825-828
    • /
    • 2008
  • $Sr_xBa_{(1-x)}TiO_3$ red phosphors doped with Pr(0.13 mol%) and Al(O.23 mol%) were synthesized by solid state reaction method. Orthorhombic perovskite structure with increasing value of x in $Sr_xBa_{(1-x)}TiO_3$:Pr,Al phosphors changed to cubic perovskite structure. Emission bands at 615 nm and 492 nm in $Sr_{0.25}Ba_{0.75}TiO_3$:Pr,Al and $BaTiO_3$:Pr,Al phosphors were observed at room temperature. The main cause of green luminescence at 492 nm was explained by the change of the 4f5d band.

The Effect of Different Iron Oxides Produced from Steel Plants in the Magnetic Properties of Cabined Sr-ferrite Powders. (염산폐액 정제방법에 따른 산화철이 Sr-ferrite의 히소특성에 미치는 영향)

  • 김효준;조태식;양충진;남효덕
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1997.11a
    • /
    • pp.124-127
    • /
    • 1997
  • The magnetic properties of calcined Sr-ferrites, related to the iron oxides, produced from three different process in steel plants, have been investigated. The powder f.characteristics of iron oxides are much affected on the magnetic properties of calcined Sr-ferrite Powders. It was possible to improve the magnetic property of calcined Sr-ferrites with the iron oxide powders of small size and narrow size distribution. The maximum magnetic properties of calcined Sr-ferrites, showing 69 emu/g of saturation magnetization and 4020 Oe of intrinsic coercivity, are achieved at the following conditions; the iron oxides from the chemirite process(EP), mole ratio of 5.8, and calcination condition of 120$0^{\circ}C$/1hr.

  • PDF

Bi(Pb)SrCaCuO superconductor fabricated by interdiffusion of SrCaCuO and BiPbCuO double layers (SrCaCuO와 BiPbCuO 이중층의 상호확산에 의해 제조된 Bi(Pb)SrCaCuO 초전도체)

  • 최효상;이중근;정동철;한병성
    • Electrical & Electronic Materials
    • /
    • v.9 no.7
    • /
    • pp.680-689
    • /
    • 1996
  • SrCaCuO와 BiPbCuO 화합물로 이루어진 이중층시료가 만들어 졌으며, 소결과정에서 나타나는 확산과 입자간의 상호작용으로 108K의 임계온도를 나타내었다. 이 시료는 820.deg. C에서 0-210 시간동안 소결되었다. 초전도체의 생성, 성장메카니즘과 임계온도의 관계가 연구되었으며, 최적조건은 820.deg. C에서 210시간 소결하고 SrCaCuO와 BiPbCuO의 도포비가 1:0.6인 시편에서 나타났다. 또한 이중층시료에서 가장 좋은 조성비는 S $r_{2}$C $a_{2}$C $u_{2}$ $O_{x}$와 B $i_{1.9}$P $b_{0.5}$C $u_{3}$ $O_{y}$ 이었다.다.

  • PDF

EBSD studies of the grain size and grain orientation distribution of $SrTiO_3$ (EBSD를 이용한 $SrTiO_3$의 입자 크기 및 입자 배향 분포)

  • Park, Myung-Beom;Shih, Shao-Ju;Cho, Nam-Hee;Cockayne, David J.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2006.06a
    • /
    • pp.46-46
    • /
    • 2006
  • $SrTiO_3$ was annealed at two different annealing times (1 h and 16 h) to investigate the annealing effect on the grain size and orientation distribution. Electron backscattered diffraction (EBSD) was used to analyze the grain size and grain orientation distributions of the $SrTiO_3$. It is possible to understand the annealing effect on the microstructure evolution, by comparing the grain size and orientation distribution of the $SrTiO_3$ as a function of annealing time.

  • PDF

Crystallographic Study on the Selectivity and Distribution of Sr2+ Ions Within Zeolite A In the Presence of Competing Na+ Ions in Aqueous Exchange Solution (Na+ 경쟁이온이 존재하는 수용액에서 Zeolite A 내 Sr2+ 이온의 선택성 및 분포에 관한 결정학적 연구)

  • kim, Hu Sik;Park, Jong Sam;Lim, Woo Taik
    • Korean Journal of Mineralogy and Petrology
    • /
    • v.35 no.1
    • /
    • pp.41-50
    • /
    • 2022
  • To study the properties of Sr2+ exchange into zeolite A with increasing the molar concentration of Na+ in given exchange solution, four single crystals of fully dehydrated Sr2+- and Na+- exchanged zeolite A were prepared by the bath method using mixed ion-exchange solutions. The Sr(NO3)2:NaNO3 molar rations of the ion exchange solution were 1:1(crystal 1), 1:100(crystal 2), 1:250(crystal 3), and 1:500 (crystal 4), respectively, with a total concentration of 0.05 M. The single-crystals were then vacuum dehydration at 623 K and 1×10-4 Pa for 2 days. Their single-crystal structures were determined by single-crystal synchrotron X-ray diffraction techniques in the cubic space group Pm3-m, at 100(1) K, and were then refined to the final error indices of R1/wR2=0.047/0.146, 0.048/0.142, 0.036/0.128, and 0.040/0.156 for crystals 1, 2, 3, and 4, respectively. In crystals 1 and 2, the 6 Sr2+ ions are found at three different crystallographic sites. In crystal 3, 1 Sr2+ and 10 Na+ ions are found in large cavity and sodalite unit. In crystal 4, only 12 Na+ ions occupy three equipoints. The degree of Sr2+ ion-exchange decreased sharply from 100 to 16.7 to 0% as the initial Na+ concentration increase and the Sr2+ concentration decrease. In addition, the unit cell constant of the zeolite framework decreased with this lower level of Sr2+ exchange.

On the Behavior of the Signed Regressor Least Mean Squares Adaptation with Gaussian Inputs (가우시안 입력신호에 대한 Signed Regressor 최소 평균자승 적응 방식의 동작 특성)

  • 조성호
    • The Journal of Korean Institute of Communications and Information Sciences
    • /
    • v.18 no.7
    • /
    • pp.1028-1035
    • /
    • 1993
  • The signed regressor (SR) algorithm employs one bit quantization on the input regressor (or tap input) in such a way that the quantized input sequences become +1 or -1. The algorithm is computationally more efficient by nature than the popular least mean square (LMS) algorithm. The behavior of the SR algorithm unfortunately is heavily dependent on the characteristics of the input signal, and there are some Inputs for which the SR algorithm becomes unstable. It is known, however, that such a stability problem does not take place with the SR algorithm when the input signal is Gaussian, such as in the case of speech processing. In this paper, we explore a statistical analysis of the SR algorithm. Under the assumption that signals involved are zero-mean and Gaussian, and further employing the commonly used independence assumption, we derive a set of nonlinear evolution equations that characterizes the mean and mean-squared behavior of the SR algorithm. Experimental results that show very good agreement with our theoretical derivations are also presented.

  • PDF

Structural and Microwave Dielectric Properties of the $0.9MgTiO_3-0.1SrTiO_3$ Ceramics with Sintering Temperature (소결온도에 따른 $0.9MgTiO_3-0.1SrTiO_3$ 세라믹스의 구조 및 마이크로파 유전특성)

  • Choe, Ui-Seon;Lee, Mun-Gi;Ryu, Gi-Won;Bae, Seon-Gi;Lee, Yeong-Hui
    • The Transactions of the Korean Institute of Electrical Engineers C
    • /
    • v.49 no.5
    • /
    • pp.294-298
    • /
    • 2000
  • The $MgTiO_3\; and \;$0.9MgTiO_3-0.1SrTiO_3$ ceramics were fabricated by the conventional mixed-oxide method. The sintering temperature and time were $1300^{\circ}C~1600^{\circ}C$, 2hr., respectively. The structural and microwave dielectric properties were investigated with sintering temperature and the application for the satellite communication microwave dielectric resonator was investigated. The coexistence of cubic $SrTiO_3$ and hexagonal TEX>$MgTiO_3$ structures in $0.9MgTiO_3-0.1SrTiO_3$ ceramics were found from X-ray diffraction patterns. In the case of $MgTiO_3$ ceramics, sphere phase and needle-like phase were coexisted. The $0.9MgTiO_3-0.1SrTiO_3$ ceramics observed sphere phase. The dielectric constants and temperature coefficient of resonant $frequency(\tauf)$ were increased with addition of $SrTiO_3$ but the quality factor was decreased. The dielectric constant, quality factor and $\tau$f of the;$0.9MgTiO_3-0.1SrTiO_3$ ceramics were 22.61, 10.928(at 1GHz) and $+50.26ppm/^{\circ}C$, respectively.

  • PDF

Photoluminescence and long after -glow characteristics of $Sr_{1-x}Eu_xAl_2O_4$phosphor ($Sr_{1-x}Eu_xAl_2O_4$ 형광체의 발광 및 장잔광특성)

  • 이영기;김병규
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.8 no.3
    • /
    • pp.493-497
    • /
    • 1998
  • The synthesis of $Sr_{1-x}Eu_xAl_2O_4$ (x=0.005~0.2;mol%) phosphors and its properties of both photoluminescence and long-phosphorescent were investigated as a function of $Eu_2O_3$ composition. The peak wavelengths (520 nm) of phosphorescence spectra were found not to vary with the $Eu_2O_3$ composition (x) of $Sr_{1-x}Eu_xAl_2O_4$ crystals. Single phase of $SrAl_2O_4$ which determined by XRD and PL was obtained with the compositions of x<0.05 mol%. After the removal of light excitation (360 nm), the excellent after-glow characteristics of the phosphorescence were obtained with the $Eu_2O_3$ compositions of x<0.05 mol%, although the after-glow intensities for all phosphors vary exponentially with the times.

  • PDF