• Title/Summary/Keyword: SR

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Thermodynamic Calculations on the Chemical Behavior of SrO During Electrolytic Oxide Reduction

  • Jeon, Min Ku;Kim, Sung-Wook;Lee, Sang-Kwon;Choi, Eun-Young
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.3
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    • pp.415-420
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    • 2020
  • Strontium is known as a salt-soluble element during the electrolytic oxide reduction (EOR) process. The chemical behavior of SrO during EOR was investigated via thermodynamic calculations to provide quantitative data on the chemical status of Sr. To achieve this, thermodynamic calculations were conducted using HSC chemistry software for various EOR conditions. It was revealed that SrO reacts with LiCl salt to produce SrCl2, even in the presence of Li2O, and that the ratio of SrCl2 depends on the initial concentration of Li2O dissolved in LiCl. It was found that SrO reacts with Li to produce Sr during EOR and that the reduced Sr reacts with LiCl salt to produce SrCl2. As a result, the proportions of metallic forms were lower in Sr than in La and Nd under various EOR conditions. The thermodynamic calculations indicated that the three chemical forms of SrO, SrCl2, and Sr co-exist in the EOR system under an equilibrium with Li, Li2O, and LiCl.

Synthesis of $SrTiO_3$ from the Mixtures of $SrCO_3$ and $TiO_2$ ($SrCO_3$$TiO_2$를 사용한 $SrTiO_3$의 합성반응에 관한 연구)

  • 이종권;이병하
    • Journal of the Korean Ceramic Society
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    • v.20 no.1
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    • pp.43-48
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    • 1983
  • The formation of strontium titanate from several molar $SrCO_3$ and $TiO_2$ mixtures was studied in air and $CO_2$ gas Mixtures of $SrCO_3$ and $TiO_2$ were heated in air at 400-$600^{\circ}C$ DTA-TG was used to obtain thermal histories of simples heated in air and $CO_2$ gas. X-ray diffraction analysis was used to determine both the phase composition and the amounts of each phase present. The phase relationship of various compounds $SrTiO_3$, $Sr_2TiO_4$, $Sr_2Ti_3O_7$ and $Sr_4Ti_3O_{10}$ formed by the sintering in each composition was shown by the calibration curves. High temperature X-ray analysis was used to determine both the formation process and deformation process of each products. Small amount of SrTiO3 is formed first at the surface af contact SrTiO3 reacts with $SrCO_3$ to form Sr2TiO4 this is affected on the $CO_2$ pressure.

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Determination of Sr-90 in the Vetebrae of Reference Korean (표준 한국인 척추골내의 Sr-90 함량 측정에 관한 연구)

  • Yung Jin Kim;Gook Hyun Chung
    • Nuclear Engineering and Technology
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    • v.16 no.3
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    • pp.131-135
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    • 1984
  • The determination of Sr-90 in 93 Korean vertebrae was carried out using modified method of tri-n-butyl phosphate extraction. As a result, the average content of Sr-90 in Korean vertebrae was 2.29 pCi/g Ca in the female and 1.73 pCi/g Ca in the male and the average level of both sexes was 2.01 pCi/g Ca, which was slightly higher than those of other countries. On the other hand, the Sr-90 injected into intraperitonal cavity of rat was accumulated in bones mostly and distributed evenly to various types of hones. The rate of accumulation and removal was not dependent on the amount of Sr-90 injected and over one half Sr-90 injected was accumulated in bones within one day and then it was removed gradually after two days from the injection.

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Optimal Conditions for Pretreated Sample for Sr Isotope Analysis by MC-ICP-MS: A Comparison Between Eichrom (SR-R50-S)'s and Bio-Rad(AG®50W-X8)'s Resins (다검출기 유도결합 플라즈마 질량분석기에 의한 Sr 동위원소 분석을 위해 전처리된 시료의 최적 조건: Eichrom사 Sr 수지(SR-R50-S)와 Bio-Rad사 수지(AG®50W-X8) 비교)

  • Myoung Jung, Kim;Seung-Gu, Lee
    • Korean Journal of Mineralogy and Petrology
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    • v.35 no.4
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    • pp.507-520
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    • 2022
  • The Sr isotope ratio, which is used as basic data for rock formation time, crustal and mantle evolution studies, is determined by mass spectrometer such as thermal ionization mass spectrometry (TIMS) or multi-detector inductively coupled plasma mass spectrometry (MC-ICP-MS). In this technical report, we compared how incomplete chemical separation of elements affects the determination of Sr isotope ratios. For the experiment, commercial resin, NBS987(NIST SRM987) Sr isotope standard, and rock standard samples from the Geological Survey of Japan (GSJ) such as JG1a, JB3 and JA1 were used. As a result of the comparative experiment, it was clearly observed that the measured values of 87Sr/86Sr change when Rb remains due to incomplete separation of the NBS987 Sr isotope standard sample as well as the rock standard samples of GSJ. This indicates that complete separation is an important factor since the calculated value deviates from the true value even though correction for isotope interference by isobar is performed when measuring the isotope ratio with MC-ICP-MS. This also suggests that, when reporting the measurement result of Sr isotope ratio using MC-ICP-MS, the measurement strength of 85Rb should be reported together with the measurement strength of all isotopes of Sr so that isotope interference by isobar can be judged.

Properties of the $(La_{1-x}Sr_x)(Ga_{1-y}Mg_y)O_{3-\delta}$ Based Electrolyte for Solid Oxide Fuel Cell (고체산화물 연료전지 $(La_{1-x}Sr_x)(Ga_{1-y}Mg_y)O_{3-\delta}$계 전해질의 제조 및 특성평가)

  • 박상선;이미재;윤기현;최병현
    • 한국전기화학회:학술대회논문집
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    • 2002.07a
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    • pp.271-276
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    • 2002
  • 고체산화물 연료전지의 구성요소인 전해질의 $(La_{1-x}Sr_x)(Ga_{1-y}Mg_y)O_{3-\delta}$계의 결정상 및 미세구조특성을 연구하였다. Mg의 첨가량이 증가할수록 Sr의 고용량도 증가하였으며 Sr의 함량이 많으면 2차상인 $LaSrGa_3O_7$상이 생성되었으며 Mg의 첨가량이 증가함에 따라서는 $LaSrGaO_4$상이 생성되었다. $LaSrGaO_4$상이 생성된 경우에는 낮은 전도도를 나타내었으며 $LaSrGa_3O_7$상의 경우에는 전기전도도에 큰 영향을 미치지 않았다. 또한 Sr과 Mg 첨가량의 증가는 grain 성장을 억제하였으며 $(La_{0.8}Sr_{0.2})(Ga_{0.8}Mg_{0.2})O_{3-\delta}$$1000^{\circ}C$에서 0.1S/cm 정도의 전기전도도를 나타내었다.

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Effect of Sr/Zr Ratio and Organic Vehicle Addition on Bond Strength of $SrZrO_3 $ Thin Films ($SrZrO_3 $박막의 접착강도에 미치는 Sr/Zr 몰비와 유기화합물 첨가효과)

  • 이세종;이득용;예경환;송요승
    • Progress in Superconductivity and Cryogenics
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    • v.4 no.1
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    • pp.13-16
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    • 2002
  • $SrZrO_3 $resistive oxide barriers on Ag sheathed Bi2223 tapes were prepared by the sol-gel and dip coating method to reduce AC coupling loss. The performance of the dip-coated $SrZrO_3 $ thin films was evaluated in terms of bond strength by varying the Sr/Zr mol ratio and the amount of organic vehicle (ethyl cellulose and a-terpineol) additives. The bond strength of the coatings increased as the Sr/Zr ratio decreased and the amount of organic vehicle rose, respectively. It was found that the effect of organic vehicle addition was more pronounced, suggesting that the adherence of the $SrZrO_3 $ films on Bi2223 tapes was governed primarily by the amount of organic vehicle additive.

Queuing Analysis Model for the SR-ARQ Protocol with a Finite Retransmission Persistence (제한된 재전송 횟수를 지원하는 SR-ARQ 프로토콜의 큐잉 지연 분석 모델)

  • Han, Je-Chan;Kim, Beom-Joon;Lee, Jai-Yong
    • The KIPS Transactions:PartC
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    • v.15C no.6
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    • pp.523-530
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    • 2008
  • In this paper, we analyze the mean queuing delay of selective-repeat automatic repeat request (SR-ARQ) protocol with the finite retransmission persistence. The retransmission persistence means the willingness of the protocol to retransmit a lost (or corrupted) packet to ensure reliable packet delivery across a lossy link. According to the retransmission persistence, SR-ARQ protocols have a different performance in terms of both packet delay and link reliability. So far, however, there is no serious study in the effect of the retransmission persistence on the SR-ARQ performance. We present a simple M/G/1 queuing model for the SR-ARQ protocol with the finite retransmission persistence by using the ideal SR-ARQ approximation. The mean queuing delay is obtained from the queuing model and verified its accuracy through the simulation results using the OPNET simulator. Both the analytical predictions and simulation results clearly show the effect of retransmission persistence on the queuing delay of the SR-ARQ protocol in various network conditions: packet loss rate and traffic condition over a wireless link.

A Study on the Analysis of 89Sr and 90Sr with Cerenkov Radiation and Liquid Scintillation Counting Method (첼렌코프광과 액체섬광계수법을 이용한 89Sr 및 90Sr 분석에 대한 연구)

  • Lee, Myung-Ho;Chung, Geun-Ho;Cho, Young-Hyun;Choi, Geun-Sik;Lee, Chang-Woo
    • Analytical Science and Technology
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    • v.15 no.1
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    • pp.20-25
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    • 2002
  • An accurate and simple analytical technique for $^{89}Sr$ and $^{90}Sr$, overcoming the demerits of the conventional method, has been developed with extraction chromatography and liquid scintillation counting. The Sr fraction was separated from hindrance elements with oxalate coprecipitation or cation exchange resin and purified with Sr-Spec column. With liquid scintillation counter, $^{89}Sr$ was measured by Cerenkov radiation method, and $^{90}Sr$ was measured by spectrum unfolding method. The developed radioactive strontium separation method was validated by application to the IAEA-reference material (IAEA-375, Soil) and radioactive waste samples.

Rb-Sr Isotopic Composition of Mesozoic Sancheong Syenite and Its Geologic Implication (중생대 산청섬장암의 Rb-Sr 조성과 의미)

  • Park Kye-Hun;Kim Dong-Yeon;Song Yong-Sun;Cheong Chang-Sik
    • The Journal of the Petrological Society of Korea
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    • v.15 no.1 s.43
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    • pp.1-9
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    • 2006
  • Sr isotopic compositions are determined from the syenite of Sancheong area, yielding age of $211{\pm}23(2\sigma)$ Ma and $^{87}Sr/^{86}Sr$ initial ratio of $0.70598{\pm}0.00060$. Such result confirms that Sancheong syenite was emplaced during the Mesozoic around the Triassic-Jurassic boundary. Rather low initial $^{87}Sr/^{86}Sr$ ratio suggests insignificant influence of old crustal materials. There are strong contrast in rock types of plutonic associations between Sancheong-Macheon area and adjacent Hamyang-Geochang area to the north, i.e. syenite-diorite-gabbro and granite-granodiorite respectively. $^{87}Sr/^{86}Sr$ initial ratios also show distinction between these areas. Such differences suggest regional contrast in tectonic environments between them.

Synthesis and luminescence properties of $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ phosphors ($Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ 형광체의 합성과 발광 특성)

  • Sung, Hye-Jin;Huh, Young-Duk
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.16 no.6
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    • pp.267-272
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    • 2006
  • A series of $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ phosphors have been synthesized by solid-state reaction. The photoluminescence and structural properties of $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ have been examined. The $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ phosphors have a strong absorption at 400 nm, which is the emission wavelength of a violet light emitting diode (LED). The emission peaks of $SrGa_2S_4:Ce,Na$are located at 448 nm and 485 nm. The partial replacement of Sr by Ca in $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ causes a red shift of emission wavelengths. The $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ can be used as blue emitting phosphors pumped by the violet LED for fabricating the multi-band white LED.