• Proceedings of the Korean Magnestics Society Conference
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• 2015.11a
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• pp.154-154
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• 2015

• Bulletin of the Korean Chemical Society
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• v.12 no.5
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• pp.499-504
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• 1991

EPR spectra of the high $T_c$ superconductor $YBa_2Cu_3O_{7-y}$ (YBCO) doped with $Pd^{2+} or Zn^{2+}$ have been measured at several temperatures and dopant concentrations. The spectral intensity of $YBa_2({Cu_{1-x}}{Pd_x})_3O_{7-y}$ is proportional to the dopant concentration. The behavior of $YBa_2(Cu_{1-x}Zn_x)_3O_{7-y}$ is quite different: the spectral intensity remains almost constant up to x=0.10 and then increases rapidly above x=0.10. The results are interpreted in terms of localized and antiferromagnetically spin-paired d holes in both CuO chain and planes. The $Pd_{2+}$ ion substitutes on the CuO chain consisting of "CuOCu dimers", and a $Cu_{2+}$ ion with an unpaired spin is gene rated for each $Pd_{2+}$ ion substituted. On the other hand, $Zn_{2+}$ substitutes on the CuO planes, and all or most of the spins in the two-dimensional plane manage to pair up in the region of low dopant concentration. When the dopant concentration exceeds a certain limit, it becomes more difficult for the spins to find partners, and the number of unpaired spins increases rapidly with increasing dopant concentration. The $Zn_{2+}$ ion is more effective than the $Pd_{2+}$ ion in suppressing the superconductivity of YBCO. This is attributed to the fact that $Zn_{2+}$ substitutes on the CuO planes which are mainly responsible for the superconductivity, while $Pd_{2+}$ substitutes on the CuO chain which is of secondary importance in the superconductivity.

• Proceedings of the KSRS Conference
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• 2005.10a
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• pp.134-137
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• 2005

Unsupervised spectral angle classification (USAC) is the algorithm that can extract ground object information with the minimum 'Spectral Angle' operation on behalf of 'Spectral Euclidian Distance' in the clustering process. In this study, our algorithm uses the unit vector instead of the spectral distance to compute the mean of cluster in the unsupervised classification. The proposed algorithm (MUSAC) is applied to the Hyperion and ETM+ data and the results are compared with K-Meails and former USAC algorithm (FUSAC). USAC is capable of clearly classifying water and dark forest area and produces more accurate results than K-Means. Atmospheric correction for more accurate results was adapted on the Hyperion data (Hyperion-FLAASH) but the results did not have any effect on the accuracy. Thus we anticipate that the 'Spectral Angle' can be one of the most accurate classifiers of not only multispectral images but also hyperspectral images. Furthermore the cluster unit vector can be an efficient technique for determination of each cluster mean in the USAC.

• The Bulletin of The Korean Astronomical Society
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• v.39 no.2
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• pp.46-46
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• 2014

Interactions such as mergers and flybys play a fundamental role in shaping galaxy morphology. We used the Horizon Run 4 cosmological N-body simulations to study the frequency and the type of halo interactions as a function of the environment, the separation p, the mass ratio q, and the target halo mass. We defined targets as haloes more massive than 10^11 Msun/h, and a target is interacting if it is located within the virial radius of a neighbour halo more massive than 0.4 times the target mass. We find that the interaction rate as a function of time has a universal shape for different halo mass and large-scale density, with an increase and saturation. Larger density yield steeper slopes and larger final interaction rates, while larger masses saturate later. Most interactions happen at large-scale density contrast ${\delta}$ about 10^3, regardless of the redshift. We also report the existence of two modes of interactions in the (p,q) plane, reflecting the nature (satellite or main halo) of the target halo. These two trends strongly evolve with redshift, target mass, and large-scale density. Interacting pairs have similar spins parameters and aligned spins, with radial trajectories, and prograde encounters for non-radial trajectories. The satellite trajectories become less and less radial as time proceed. This effect is stronger for higher-mass target, but independent of the large-scale density.

• Journal of the Korean Society of Tobacco Science
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• v.29 no.2
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• pp.146-151
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• 2007

Gas phase and particulate phase radicals in mainstream cigarette smoke were determined Electron Spin Resonance(ESR) spectroscopy. The free radicals in particulate phase have been investigated by benzene extract of Cambridge Filter Pad containing the smoke condensate. Spin trapping method in conjunction with ESR was used to investigate free radicals in the gas phase of cigarette smoke. Several analytical experiments were conducted in order to determine the optimal conditions for maximum signal intensities and reproducibility of results. All the tests were optimized and normalized using the University of Kentucky 2R4F reference cigarette. The optimal conditions were 0.6 mL for analysis volume of ESR, $4{\sim}5\;mL$ for collection volume of spin-adducts, and PBN for quantification of free radicals in gas phase. The radical levels of Kentucky 2R4F cigarettes were found $2.18{\times}10^{14}\;spins/cig.$ and $2.10{\times}10^{15}\;spins/cig.$ in gas phase.

• Bulletin of the Korean Chemical Society
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• v.24 no.6
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• pp.864-880
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• 2003

A unified picture for magnetism, superconductivity, quantum optics and other properties of molecule-based materials has been presented on the basis of effective model Hamiltonians, where necessary parameter values have been determined by the first principle calculations of cluster models and/or band models. These properties of the matetials are qualitatively discussed on the basis of the spin and pseudo-spin Hamiltonian models, where several quantum operators are expressed by spin variables under the two level approximation. As an example, ab initio broken-symmetry DFT calculations are performed for cyclic magnetic ring constructed of 34 hydrogen atoms in order to obtain effective exchange integrals in the spin Hamiltonian model. The natural orbital analysis of the DFT solution was performed to obtain symmetry-adapted molecular orbitals and their occupation numbers. Several chemical indices such as information entropy and unpaired electron density were calculated on the basis of the occupation numbers to elucidate the spin and pair correlations, and bonding characteristic (kinetic correlation) of this mesoscopic magnetic ring. Both classical and quantum effects for spin alignments and singlet spin-pair formations are discussed on the basis of the true spin Hamiltonian model in detail. Quantum effects are also discussed in the case of superconductivity, atom optics and quantum optics based on the pseudo spin Hamiltonian models. The coherent and squeezed states of spins, atoms and quantum field are discussed to obtain a unified picture for correlation, coherence and decoherence in future materials. Implications of theoretical results are examined in relation to recent experiments on molecule-based materials and molecular design of future molecular soft materials in the intersection area between molecular and biomolecular materials.

• Journal of the Korean Magnetics Society
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• v.22 no.6
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• pp.204-209
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• 2012

We measure the ferromagnetic resonance signals in order to analyze the exchange coupling energy due to the uncompensated antiferromagnetic spins in exchange coupled CoFe/MnIr bilayers. The exchange bias fields ($H_{ex}$) and rotatable anisotropy fields ($H_{ra}$) are obtained from the ferromagnetic resonance fields measured with in-plane angle in thermal annealed samples with $t_{AF}$= 0, 3, and 10 nm. The sum of the $H_{ex}$ and $H_{ra}$ do not depend on the MnIr thickness, which means that all the uncompensated AF spins are aligned to one direction in $300^{\circ}C$ annealed samples. Therefore, the uncompensated AF spins are divided into two different parts. One parts are fixed at the interface between CoFe/MnIr bilayers and induces the $H_{ex}$, other parts are rotatable with magnetic field and induces the $H_{ra}$. Finally, the exchange coupling energy can be expressed by the sum of the exchange bias energy and rotatable anisotropy energy.

• Proceedings of the Korean Magnestics Society Conference
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• 2007.05a
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• pp.160.2-160.2
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• 2007

• Proceedings of the Korean Magnestics Society Conference
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• 2007.05a
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• pp.159.1-159.1
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• 2007

• Analytical Science and Technology
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• v.18 no.1
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• pp.85-88
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• 2005

Antiphase character of cross peaks in long-range COSY is modulated by changing the fixed delay time and used to assign diastereotopic methylene protons on rigid systems which could produce unpredictable NOE phenomena because of complicate coupling spins.