• Journal of Advanced Marine Engineering and Technology
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• 제33권3호
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• pp.373-377
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• 2009

It is well known that SOx and NOx concentration has a considerable influence on the $N_2O$ emission of the greenhouse gas properties. The quantity of SOx generated during combustion, on fuel specific basis, is directly related to the sulfur content of the fuel oil. However, restricting the fuel oil sulfur content is only a partial response to limiting the overall quantity of SOx emissions, as there remains no over control on the fuel oil consumption other than the commercial pressure which have always directed the attention. This study was carried out as a new basic experiment method of emission control, manly targeted to the vessel. In the experiment, where the scrubbing was achieved through spray tower with high alkaline water made from the electrolysis of seawater, the combined action was to neutralize the exhaust gases (SOx, PM, CO etc.), dilute it, and wash it out. The results showed that SOx reduction of around 95 percent or over could be achieved when using in the high alkaline water, and also leaded to a reduction in the stability of the each pollutant components including the PM (Particulate Matter). The results suggest that the seawater electrolysis method has a very effective reduction of emissions without heavy cost, or catalysts particularly on board.

• 한국입자에어로졸학회지
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• 제15권4호
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• pp.159-171
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• 2019

The cap-and-trade system against the air pollutants in the Seoul Metropolitan Area (SMA), Korea has been implemented since 2008 and will be implemented other areas in Korea on 2020. In this study, to identify the outcome and effectiveness of the cap-and-trade system in the SMA, (1) the rate of change for NOx and SOx emissions, (2) differences between the real emission and allocated amount, and (3) the status of trading are reviewed. It was found that the NOx and SOx emissions from the sources under the cap-and-trade system decreased in the SMA but the reduction was mainly due to the reduction of fuel usage not related to the system. It was found that the average percentage of annual emission in the SMA to the allocated amount between 2008 and 2018 was 66.9% for NOx and 69.3% for SOx, respectively. It suggests that there was over allocation of the emission amounts. The average trading prices in the SMA were 0.193 $/kg for NOx and 0.128 $/kg for SOx, far lower than those in RECLAIM, 131.942 $/kg and 81.677 $/kg, respectively. It was suggested that (1) the cap system for NOx and SOx emissions should be implemented only for the area with high emission ratio from large point sources, (2) the trade system is not suitable for the effective implementation of the cap system, and (3) Korean government should not allow over allocation in order to ensure sound market function without delaying the introduction of technology.

• 한국대기환경학회지
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• 제14권3호
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• pp.261-266
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• 1998

Recently, air pollution is increased according to increase of vehicle. So many countries are studying about DOC for diesel emission decrease. However, there are many difficulty in applying to DOC . In this study, SOx exhaust gas equipped with DOC was studied and we obtained several test results as following. First, in diesel oxidation catalyst, additives such as Pt is very effective for 503 and sulfate. Second, the oxidative activity for 502 has decreased to add such as Pt and the decrease of 502 is effect for the reduction of PM in high temperature . And finally, in high temperature, concentration of SOx is increased and temperature is affected by process from SOB to 503, whereas engine performance and fuel consumption are not affected by equipped DOC.

• 에너지공학
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• 제13권2호
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• pp.133-143
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• 2004

Simultaneous removal technology of particulate/NOx/SOx/HCl using CuO/3Al$_2$O$_3$ㆍ2SiO$_2$catalyst impregnated ceramic candle filters is an advanced air pollution process and provides significantly to reduce hazardous gases emitted from coal-fired power plant. This process uses a high-temperature catalytic filter for integrating SOx and HCl reduction through injection an alkali sorbent (such as hydrated lime or sodium bicarbonate), NOx removal through ammonia injection and selective catalytic reduction (SCR), and particulate collection on the catalytic filter surface. The advantages of the process include : compact integration of the emission control technologies into a single component; easy handling of dry sorbent and by-product; and improved SCR catalytic life due to lowered SOx, HCl and particulate levels. CuO/3Al$_2$O$_3$ㆍ2SiO$_2$ catalyst impregnated ceramic candle filters showed a possibility of simultaneous treatment from results which have ascertained high removal efficiency at various combined gases conditions, and in pilot plant test for 3 months, NO conversion was showed 90% over.

• 한국생산제조학회지
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• 제9권3호
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• pp.136-142
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• 2000

With the significant growth of the number of vehicles environmental problems is raised. NOx SOx, and PM emissions in diesel powered vehicles are larger than that in gasoline because the development of pollutants reduction techniques has not been yet achieved. So it is need to develop after-tratment or to convert into alternative fuel to satisfy emission regula-tion. Among the after-treatment systems to reduce the diesel emissions studies with diesel oxidation catalyst(DOC) are done greatly. In this study using DOC reduction efficiency with the change of temperature and catalyst loading was calculated through measurements of CO, HC, PM. and SOX.

• 해양환경안전학회지
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• 제25권5호
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• pp.572-580
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• 2019

최근 지구 환경문제에 대한 논의가 활발해지면서 국제 운송의 큰 부분을 차지하고 있는 해상운송에서도 배출물질 규제를 위한 정책이 시행되고 있다. 이 연구에서는 선속 제한에 의한 배출량의 감축 효과를 검토하기 위하여 기관 부하율을 적용하여 선박의 배출물질을 수치계산하였다. 2017년 1월 1일부터 12월 31일까지 부산 북항의 입출항 선박을 대상으로 선속제한구역 20마일권역을 설정하고 해당 구간에서의 선종별, 선속별로 배출량을 계산하고 분석하였다. 항행, 접 이안, 정박 중일 때를 모두 포함하여 가장 많은 배출물질을 발생시키는 선박은 컨테이너선 76.1 %, 일반화물선 7.2 %, 여객선 6.8 %의 순으로 계산되었다. 항행 및 접 이안 모드일 때는 일반화물선이 여객선보다 배출물질이 적었지만 정박 모드일 때는 여객선보다 많았다. 총 배출물질은 질소산화물, 황산화물, 입자상물질, 휘발성유기화합물의 순으로 각각 49.4 %, 45 %, 4 % 1.6 %로 구성되었다. 선속 제한이 없는 경우와 선박 속도를 12노트, 10노트, 8노트로 제한시킬 때 배출물질을 비교하면 속도 12노트 제한의 경우 질소산화물 39 %, 휘발성유기화합물 40 %, 입자상물질 42 %, 황산화물 38 %의 감소효과가 있고, 10노트 제한일 때 질소산화물 52 %, 휘발성유기화합물 54 %, 황산화물 56 %, SOx 50 %의 감소효과가 있으며, 8노트 제한일 때 질소산화물 62 %, 휘발성유기화합물 64 %, 입자상물질 67%, 황산화물 59 %의 감소효과가 있었다. 이처럼 선박의 속도 감소에 따라 배출물질 역시 크게 감소되는 연구결과를 확인할 수 있었으며, 향후 항만 배출물질 감소를 위해 선박의 속도를 제한하는 방안을 적극적으로 고려할 필요가 있다.

• 해양환경안전학회지
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• 제27권7호
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• pp.905-917
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• 2021

본 연구는 국내 항구도시 인천, 목포, 광양, 부산, 울산의 대기오염물질 배출특성, 대형선박 배기가스 배출량 및 사회적 비용을 산정하여 배출가스 저감방안의 필요성을 제시하였다. 부산은 선박 입항수가 많고 목포는 선박 입항수는 적지만 선박 배기가스에 의한 배출기여도는 두 항구도시 모두 높았다. 울산은 세계적 수준의 중화학공업, 광양은 제철소, 인천은 제조업과 선박 입항수가 목포보다 많았지만 배출기여도는 낮았다. 선박 배기가스 배출량 산정 결과, CO₂의 배출량이 가장 많고 다음으로는 NOx, SOx으로 배출량이 많았다. 선종별로는 부산, 울산, 인천은 유조선, 광양은 일반화물선, 목포는 여객선에서 각각 많았다. 사회적 비용 결과, 부산은 배출량이 많은 영향으로 사회적 비용이 높았으며, 항목별로는 PM이 높았다. 저황유 사용으로 PM, SOx 배출량을 직접적으로 줄이고, NOx의 배출량을 간접적으로 줄 일수 있다. 하지만 선박 배기가스 중 가장 많은 배출량을 보인 CO₂를 저감하기 위해서는 저황유의 보급만으로는 부족하다. CO₂ 배출량 감축을 위해서는 육상전원공급장치(Alternative Maritime Power)를 사용하는 등 화석연료를 사용하지 않는 저감방안 수립의 필요성을 제기하였다.

• Journal of Advanced Marine Engineering and Technology
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• 제30권1호
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• pp.81-87
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• 2006

In marine air pollution control, SCR (Selective Catalytic Reduction) is reconized as the most effect method to control NOx, but on the other hand. seawater scrubber applying the basic characteristic that is naturally alkaline (pH typically around 8.1) is viewed as an economical SOx removal system at present. Especially, seawater scrubber would not be necessary to follow any of the various land based flue gas desulfurization methods. i.e. wet, dry or alkali scrubbing. However, these methods are not readily adaptable to marine conditions due to the quantifies of consumables required i.e. lime or limestone, the means of operation and the commercial availability. This research is undertaken to develop a new method as the main target of eliminating all exhaust emissions, particularly vessel, because of easy access to seawater and apt to apply a wet scrubber system. First, using the acidic seawater by seawater electrolysis, nitric monoxide(NO) is adequately oxidized to nitric dioxide $(NO_2)$by ClOx-in the acidic seawater, the electrolyzed alkaline seawater by electrolysis which contains mainly NaOH together with alkali metal ions $(i.e\;Na^{+}\;K^{+},\;Mg_{2}\;^{+},\;Ca_{2}\;^{+})$, is used as the absorption medium of NOx, the SOx are absorbed by relatively high solubility compared to other components of exhaust pollutants. The results found that the NOx and SOx removals could be achieved nearly Perfect.

• 한국항만경제학회지
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• 제34권4호
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• pp.141-160
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• 2018

본 논문에서는 황산화물(SOx) 배출저감 규제에 대한 국적선사의 인식과 대응 전략을 분석하기 위해 국제해사기구(IMO)의 환경규제 현황과 선박으로부터의 대기오염방지를 위한 규칙인 국제해양오염방지협약(MARPOL) 부속서 VI, 황산화물(SOx) 배출저감 기술적 방안, 해운산업과 국적선사의 경영현황을 살펴 보았다. 그리고 국적선사들 대상으로 설문을 진행하여 국적선사의 규제와 영향에 대한 인식과 대응 전략을 분석하였다. 평가요인의 선정 작업을 거쳐 국적선사를 대상으로 설문을 실시하였다. 빈도 및 교차 분석을 진행하여 규모별, 주력선종별 선사의 인식과 대응 전략의 차이, 국적선사의 대응 전략의 방향성을 알아보았다. 관련 선행연구 및 문헌들을 검토하면서 그 동안 국내외에서 다양한 관점으로 황산화물(SOx) 배출저감에 관한 여러 연구들이 시행되어왔음을 확인하였다. 본 연구에서도 규제 대응을 위한 기술적 방안들과 경제성 분석 관련 기존 연구들을 고찰하여 평가요인을 선정하였다. 분석 결과 대형선사가 중소 벌크선사에 비해 규제 대응의 준비가 원활히 실행되고 있는 것으로 나타났으며, 선사 규모와 주력선종별 선사의 규제에 따르는 환경적인 영향에 대한 인식이나 대응 전략에 대한 방향성은 비슷한 것으로 나타났다. 규제의 시행까지 약 2년이 남은 상황에서 정부와 관련기관의 지원 정책과 선사별 체계적인 분석과 계획을 바탕으로 적절한 대응 방안을 모색할 필요가 있다. 본 연구를 통해 국적선사들을 대상으로 주력선종별 선사들의 인식과 대응 전략의 차이를 파악하였지만 구체적인 대응 전략이나 기업의 데이터 수집의 한계가 존재하였다. 향후 연구에서는 본 연구의 한계점을 극복하여 보다 심도 있는 연구가 진행되어야 할 것으로 사료된다. 해운산업 관계자들이 황산화물(SOx) 배출저감 규제 대응 준비에 대한 중요성을 인식하고 국가적으로 중요한 해운산업의 경쟁력을 확보하기 위하여 최적의 대응 전략이 수립되기를 기대한다.

• 대한기계학회논문집B
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• 제26권12호
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• pp.1722-1728
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• 2002

Most researches regarding emulsified fuel were in the areas of emulsifier, emulsified fuel manufacturing and emulsified fuel droplet combustion, but there were little papers published regarding emulsified fuel combustion and boiler efficiency in an industrial boiler. The main purpose of this study is to clarify whether improvements in the boiler efficiency and the reduction of pollutants such as CO, NOx, SOx and smoke exist or not when emulsified fuels are combusted in the commercial boiler. Main experimental parameters were water content in heavy oil , excess $O_2$, and boiler load. The fuels used in this experiment were 0.5 B-C, and 5 kinds of 0.5 B-C/water emulsified fuels. The combustion characteristics of heavy oil and its emulsions with water were investigated in an industrial boiler. The combustion stability was monitored and exhaust gases such as CO, NOx, SOx and smoke were measured with excess $O_2$ and combustion load. In case of emulsified fuel combustion, flame stability was poor and boiler efficiency was lowered by 1.6~5.7%, but emission levels of CO and smoke were improved.