• Title/Summary/Keyword: SOx Emissions

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An Experimental Study of N2O Concentration Profiles in Planner Premixed Flame (평면예혼합화염중의 N2O 농도변화에 관한 실험연구)

  • An, Suk-Heon
    • Journal of Advanced Marine Engineering and Technology
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    • v.33 no.2
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    • pp.267-271
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    • 2009
  • The Marine Environment Protection Committee(MEPC) which is the IMO's specialized committee on marine pollution related matters deals with GHG related issues to discuss and compile possible approaches on technical, operational and market based measures to address GHG emissions from ships. The nitrous oxide($N_2O$) which remains generally in the atmosphere for around 114 years is one of the green house gases. The global warming potential of $N_2O$ is 310 times than $CO_2$ in the given period 100 years. It seems that the $N_2O$ formation is influenced by the nitrogen compound contained in the fuel which is named as "Fuel N" during the combustion process or the NOx, SOx and $H_2O$ through the emission gases before exhausted into the atmosphere. This paper has carried out an experimental study of the $N_2O$ concentration profiles by the change of $NH_3$ flows in the planner premixed combustion with using $C_3H_8$ and air.

Demonstration of MCFC Power Plant on Fuels (연료에 따른 MCFC발전 실증연구)

  • Lee, Jong-Gyu;Jun, Jae-Ho;Park, Kyu-Ho;Choi, Doo-Sung;Park, Jae-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.117-120
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    • 2007
  • Fuel cells are currently attracting tremendous interest because of their huge potential in stationary applications, in terms of substantiality of our energy use. They also offer environmental advantages, combining significantly higher efficiency with very much lower emission of SOx, NOx, and residual hydrocarbons, and significantly reduced $CO_{2}$ emissions compared to conventional power generation. The molten carbonate fuel cell (MCFC) was introduced from Fuel Cell Energy(FCE), which the one MCFC was operating by LNG and the other was operating by ADG. The ADG contains normally CH4, CO2 and various impurities such as sulfur compounds and siloxanes. Using the ADG as a fuel, MCFC have the potential to provide significant environmental and economic benefits. However, such impurities would be harmful to fuel cells. In this work, a purification process for the ADG was designed and installed in order to utilize the gas as a fuel for MCFC.

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Development of Pilot-Scale Scrubber for Simultaneous Removal of $SO_2/NO$

  • Jung, Seung-Ho;Jeong, Gwi-Taek;Lee, Gwang-Yeon;Park, Don-Hee;Cha, Jin-Myeong
    • 한국생물공학회:학술대회논문집
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    • 2005.10a
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    • pp.468-474
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    • 2005
  • SOx and NOx are known major precursors of acid rain and thus the abatement of their emissions is a major target in air pollution control. To obtain basic data on the removal process of simultaneous $SO_2/NO$, the optimal reaction condition and the composition of reaction solution for simultaneous removal of $SO_2/NO$, ware investigated using a bubble column reactor. Pilot scrubber was consisted of scrubber, filter and control box. Dust removal rate was 83, 92, and 97% with catalyst flux of 0.5, 0.8, 1.5 L/min, respectively Average dust removal efficiency with a kind of nozzle was about 94 and 90% in STS FF6.5 (5/8in.) and 14 of P.P W(1.0in.), respectively Dust and $SO_2$ were removed more than 98-96% regardless of reactor number. In the case of NO gas, removal yield of 83.3% was achieved after 48 hours in 1 stage, also removal yield of 95.7% was reached in 2 stages. In tile case of application of STS (5/8 in.) and P.P (1.0 in.) as used fill packing, removal efficiency was reached higher than 98% without related to of kind of fill packing.

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Performance evaluation of nitrate removal in high TDS wet scrubber wastewater by ion exchange resin with dissolved air flotation (DAF) process

  • Kim, Bongchul;Yeo, Inseol;Park, Chan-gyu
    • Membrane and Water Treatment
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    • v.13 no.1
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    • pp.1-6
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    • 2022
  • The regulations of the International Maritime Organization (IMO) have been steadily strengthened in ship emissions. Accordingly, there is a growing need for development of related technologies for the removal of contaminants that may occur during the treatment of SOx and NOx using a wet scrubber. However, this system also leads to wastewater production when the exhaust gas is scrubbed. In this research, we evaluated the performance of an ion selective resin process in accordance with scrubber wastewater discharge regulations, specifically nitrate discharge, by the IMO. Accelerated real and synthetic wastewater of wet scrubbers, contained high amounts of TDS with high nitrate, is used as feed water in lab scale systems. Furthermore, a pilot scale dissolved air flotation (DAF) using microbubble generator with ion exchange resin process was combined and developed in order to apply for the treatment of wet scrubber wastewater. The results of the present study revealed that operating conditions, such as resin property, bed volume (BV), and inlet wastewater flow rate, significantly affect the removal performance. Finally, through a pilot test, DAF with ion exchange resin process showed a noticeable improvement of the nitrate removal rate compared to the single DAF process.

A Study on Estimating Ship's Emission in the Port Area of Mokpo Port (목포항 항만구역 내 선박 배기가스 배출량 산정에 대한 연구)

  • Bui, Hai-Dang;Kim, Hwayoung
    • Journal of Korea Port Economic Association
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    • v.39 no.3
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    • pp.47-60
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    • 2023
  • A thorough inventory of ship emissions, particularly ship's emission of in-port area is necessary to identify significant sources of exhaust gases such as NOx, SOx, PM, and CO2 and trends in emission levels over time, and reduce their serious effects on the environment and human health. Therefore, the goal of this study is to assess the volume of emissions from ships in Mokpo port, which serves as a gateway to the southwest coast of Korea, using a bottom-up methodology and data from the automatic identification system (AIS) and the Korean Port Management Information System (Port-MIS). In this work, an analysis of ship movement utilizing AIS data and an actual set of data on ship specification were gathered. By examining ship movement using AIS data, We also proposed a new approach for identifying cruising/maneuvering mode. Finally, the results were classified by ship operating mode, by exhaust gas, by ship type, and by berth, which provides a thorough and in-depth analysis of the air pollution caused by ships in Mokpo port.

Preliminary Study on Factor Technology of Selective Catalytic Reduction System in Marine Diesel Engine (선박용 디젤엔진 SCR 시스템 요소 기술에 관한 기초 연구)

  • Park, Yoon-Yong;Song, Ha-Cheol;Ahn, Gi-Ju;Shim, Chun-Sik
    • Journal of Navigation and Port Research
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    • v.40 no.4
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    • pp.173-181
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    • 2016
  • From 2016, controls on reduction of NOx and SOx emissions from the vessels that are operated in the emission control area were tightened. The selectivity catalytic reduction system of the denitrification equipment which NOx among the above controlled materials is very effective and used commercially very much. But it has the disadvantage that CSR is activated at high temperatures. Therefore, the SCR and SCR activation instrument that can react even at low temperatures by using micro-nano bubbles so that the above problems can be minimized were developed. And the computational fluid dynamics technique was used by ANSYS-CFX package to prepare the plan that improves the SCR system's efficiency. Simulation for the viscous flow analysis of the SCR system was executed by applying the Navier-Stokes equation to it as a governing equation. For the SCR system's shape, 3D modeling was done by using CATIA V5. SCR jet nozzle's position was checked by changing it to the intervals of 1/3, 1/2, and 2/3 from the inlet of the vent pipe to compare the SCR system's efficiency. And the number of nozzles was compared and analyzed by simulating 4, 6, and 8 holes to check an effect of the number on the SCR system's efficiency. The simulation result has found that the closer nozzles are to the inlet of the vent pipe and the more nozzles are, the more efficiency is improved.

Comparison of Environmental Efficiencies and Shadow Prices of Pollutants in Korean Cities (한국 도시의 환경효율성과 오염물 잠재가격 비교)

  • Kang, Sang-Mok
    • Journal of the Economic Geographical Society of Korea
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    • v.13 no.3
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    • pp.398-415
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    • 2010
  • The purpose of this paper is to grasp levels of cost burden in pollution treatment by measuring efficiencies and shadow prices by pollutants in Korean cities. The efficiencies and shadow prices of pollutants will be compared for cities divided by Seoul metropolitan area and non-Seoul metropolitan area. Annual shadow prices of NOx, SOx, and PM10 emissions in the cities of Seoul metropolitan area are 0.846, 0.318, 0.816, respectively for 1999-2005. The annual shadow prices in the cities of Non-Seoul metropolitan area are 0.848, 0.272, and 0.789, respectively over the same periods. The shadow prices of SOx showed similar levels between two areas but those of NOx and PM10 of cities in Seoul metropolitan area were higher. NOx emission quantities of both areas have similar increasing patterns because the NOx has mainly increased with augmentation of transportation regardless of Seoul metropolitan and non-Seoul metropolitan areas. It seems that the reason the shadow prices of two pollutants for the cities of Seoul metropolitan area are higher, is because environmental regulation is stronger in the cities of Seoul metropolitan area, the cities of Seoul metropolitan relatively show higher quantities of pollution reduction under given desirable outputs, and generally have industrial sectors with small pollution emission. In the future we need to reduce pollutants in the various respects such as adjustment of overall industry structure, energy consumption pattern, and reviews of arrangement of living space for the cities located on the downward-sloping segment of production frontier.

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Study on purification and extraction of nitrate salts from waste scrubbing liquid of de-SOx/de-NOx (탈질/탈황 폐 세정액으로부터 질산염 추출 및 정제 연구)

  • Kim, Woo-Ram;Jo, Young-Min;Lee, Heon-Seok;Oh, Soo-Kwan
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.48-55
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    • 2015
  • IMO to issue some restricted maritime legislation for reducing the adverse environmental impacts arising from such ship exhaust emissions. According to the IMO policy, every ship entering the Baltic SECAs has to equip the gas cleaning scrubber. The discharged waste solution by gas cleaning scrubber contains many types of salts, which to recover some valuable materials before disposal. This study try to achieve valuable salts including AN and AS throughout a few process such as selective organic solvents salting out, low temperature extraction and thermal evaporation. Amongst them, Thermal evaporation with repetition extraction using inorganic solvent was the most optimum to purify the extracted AN. This valuable salt was evaluated by Elemental analysis and Differential scanning calorimetry.

A Study on the Combustion Stability and Characteristics for D.O - Methanol Blending Oil in Diesel Engine (디젤기관에서의 경유-메탄올 혼합유의 연소 안전성과 연소특성에 관한 연구)

  • Kim, Sang-Am;Wang, Woo-Gyeong
    • Journal of Power System Engineering
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    • v.22 no.1
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    • pp.48-55
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    • 2018
  • It has recently been reported that methanol fuel has been used in the product carrier with established duel fuel engine, which has been greatly reducing emissions of $CO_2$, NOx and SOx from the engine. However, to use methanol alone as fuel oil in a general diesel engine, design modification of cylinder head is needed because the ignition aid device or the duel fuel injection system is needed. On the other hand, only if the mixer is installed on the fuel oil supply line, diesel oil - methanol blending oil can be used as fuel oil for the diesel engine, but there is a problem of the phase separation when two fuels are mixed. In this study, diesel oil and methanol were blended compulsorily in preventing the phase separation with installing agitators and a fuel oil boost pump on fuel line of a test engine. Also, cylinder pressure and fuel consumption quantity were measured according to engine load and methanol blending ratio, and indicated mean effective pressure, heat release rate and combustion temperature obtained from the single zone combustion model were analyzed to investigate the effects of latent heat of vaporization of methanol on combustion stability and characteristics. As a result, the combustion stability and characteristics of 10% methanol blending oil are closest to the those of diesel oil, and it could be used as fuel oil in existing diesel engines without deterioration of engine performance and combustion characteristics.

A Study on the Effect of Sulfur Content in Fuel Oil on the Emission of Air Pollutants According to Operating Conditions of Small Ship Engines (선박용 소형 엔진에서 연료유 내 황 함유량이 운전 조건에 따라 대기오염물질 배출에 미치는 영향에 관한 연구)

  • Lee, Kyeong-yeol;Rho, Beom-seok;Lee, Won-Ju;Choi, Jae-hyuk
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.24 no.6
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    • pp.834-840
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    • 2018
  • In this study, the characteristics of air pollutant emissions from ships' engines have been investigated by conducting E2 and E3 cycle mode tests. A engine 360Ps (Doosan L126TIH engine) and 400kW dynamometer Horiba-Schenck were utilized for engine tests. The FTIR analyzer and SPC were used to measure exhaust gas (NOx, SOx etc.) and PM (particulate matter), respectively. The results showed that the emissions of THC and CO produced from engine were increased with the increase of sulfur content in fuel oils at E2 and E3 cycle modes. The kinetic viscosity of the fuel increased as the sulfur content of the fuel increased, thereby the specific fuel oil consumption (SFC) of the engine improved. This result is considered to be due to improved combustion conditions due to increased average diameters of sprayed particles and due to increased kinetic viscosity under constant fuel injection pressure in this study. In the case of NOx emission, this study showed no significant change in amount of sulfur content.