• 제목/요약/키워드: SOx Emissions

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선박 기인 대기오염물질 현황 및 저감 기술 소개 (Current Status of Air Pollutants from Ships and Reduction Technologies)

  • 박준성;함승호;강다영;박희연;박종관
    • 대한조선학회논문집
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    • 제61권2호
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    • pp.135-142
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    • 2024
  • There is a lot of concern around the world about air pollution from ships. The majority of air pollution from ships comes from fuel combustion. The combustion process produces various air pollutants such as carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxides (NOx), sulfur oxides (SOx), and particulate matter (PM), each of which has adverse effects on people and is a major environmental problem. To prevent this, the International Maritime Organization (IMO) has strengthened the regulation of pollutant emissions through the Convention for the Prevention of Marine Pollution. This paper discusses the types of air pollutants emitted by ships, their current status, and the latest technologies to reduce emissions of NOx and SOx.

울산항 선박으로부터의 대기오염 배출량 산정에 관한 연구 (A studies on the Air pollutant Emission Rate calculation from vessels in the Ulsan Port)

  • 정광현;김성주;박흥석
    • 해양환경안전학회:학술대회논문집
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    • 해양환경안전학회 2005년도 춘계학술발표회
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    • pp.111-118
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    • 2005
  • 국제해사기구(IMO)에서 1997년 9월 선박으로부터의 대기오염방지를 위한 협약(MARPOL 부속서VI)을 채택하여 U년 5월 19일 협약 발효를 앞두고 있다. 따라서 향후 선박으로부터 배출되는 배기가스 중에 포함된 아황산가스(SOx)와 질소산화물(No%)등 대기오염 물질의 배출 규제와 항만이나 터미널에서 유조선으로부터 휘발성유기화합물(VOCs) 배출금지 등의 규제가 강화될 것으로 예상된다. 본 연구는 이에 대한 대비와 관리방안을 모색하고자 외국에서 이용되는 선박의 배출오염물질 산정 방법을 이용하여 선박에서 배출되는 SOx, NOx의 배출량을 산정하였다. 또한 울산항 특성을 감안하여 액체화물 적$\cdot$양하시 발생되는 휘발성유기화합물(VOCs)의 양을 산정하는 방법에 대해 고찰하고 그 배출량을 산정하였다.

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비열플라즈마와 라디칼을 이용한 디젤엔진의 매연 및 NO 제거 특성 (Removal Characteristics of Soot and NO by Nonthermal Plasma and Radical in a Diesel Engine)

  • 장영준;최승환;김규보;전충환
    • 대한기계학회논문집B
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    • 제26권4호
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    • pp.547-554
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    • 2002
  • We are facing the serious environmental pollution difficulties such as acid rain, green house effects, etc. The gaseous matter NOx, SOx, VOCs which are regarded as main factors for these current pollutions are mainly emitted from power plants and vehicles. Therefore several leading countries are regulating the emissions strictly, especially the exhaust emissions from a Diesel engine without an aftertreatment device. The objective of this study is to find out soot and NO removal characteristics focused on the emissions of a Diesel engine by using nonthermal plasma for each engine speeds and loads. Electrostatic precipitator(wire-to-plate type reactor) is used for soot removal. Radicals generated from outer air and put into a mixing chamber in the end of exhaust line are used for NO removal. Concentration of exhaust emissions is analyzed from the gas analyzer(KaneMay) and FTIR to estimate by-products.

Eco-friendly selection of ship emissions reduction strategies with emphasis on SOx and NOx emissions

  • Seddiek, Ibrahim S.;Elgohary, Mohamed M.
    • International Journal of Naval Architecture and Ocean Engineering
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    • 제6권3호
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    • pp.737-748
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    • 2014
  • Increasing amounts of ships exhaust gases emitted worldwide forced the International Maritime Organization to issue some restricted maritime legislation for reducing the adverse environmental impacts arising from such emissions. Consequently, ships emission reduction became one of the technical and economical challenges that facing the ships, operators. The present paper addresses the different strategies that can be used to reduce those emissions, especially nitrogen oxides and sulfur oxides. The strategies included: applying reduction technologies onboard, using of alternative fuels, and follows one of fuel saving strategies. Using of selective catalytic reduction and sea water scrubbing appeared as the best reduction technologies onboard ships. Moreover, among the various proposed alternative fuels, natural gas, in its liquid state; has the priority to be used instead of conventional fuels. Applying one of those strategies is the matter of ship type and working area. As a numerical example, the proposed methods were investigated at a high-speed craft operating in the Red Sea area between Egypt and the Kingdom of Saudi Arabia. The results obtained are very satisfactory from the point of view of environment and economic issues, and reflected the importance of applying those strategies.

석탄보일러에서 각종 RDF혼소시 다이옥신 농도 조사 (Co-combustion of RPF in the Coal Power plant)

  • 최연석;최항석;김석준;윤균덕
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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    • pp.452-455
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    • 2008
  • The co-combustion of coal and three kinds of RDFs(Refuse Plastic Fuel) mixture has been experimented in a commercially operating CFB coal boiler respectively and the pollutant emissions such as SOx, NOx, TSP and dioxine were measured at the stack. The mixing ratio with coal was 7.5% RPF, 7.5% RDF and 10% SDF respectively. During co-combustion, dioxine emission level was very low and SOx, NOx and TSP were decreased comparing the single coal combustion. Emitting dioxine concentration was proportioned to the chlorine content of RDF. These RPF, SDF and RDF could be determined to be a good alternative fuel of general coal.

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석탄화력발전소에서 폐플라스틱고형연료(RPF)의 혼소 연구 (Co-combustion of RPF in the Coal Power plant)

  • 최연석
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 추계학술대회 논문집
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    • pp.609-612
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    • 2007
  • The co-combustion of coal and RPF(Refuse Plastic Fuel) mixture has been experimented in a commercially operating CFB coal boiler and the emissions such as SOx, NOx, TSP and dioxine were measured at the stack. The experimented RPF was supplied by domestic RPF company that is commercially producing RPF pellet from the wasted plastics. Up to 15% of total coal was substituted to RPF and no trouble was happened during normal boiler operation. SOx and NOx concentration was reduced about $15{\sim}20$% and TSP(Total Suspended Particle) was drastically reduced about 30% during co-combustion. Dioxine concentration at mixing ratio of 7.5% was $0.0487ng{\sim}TEQ/Sm^3$ ($O_2$, 12%) that satisfied governmental emission regulation.

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Evaluation of ammonia (NH3) emissions from soil amended with rice hull biochar

  • Park, Seong-Yong;Choi, Ha-Yeon;Kang, Yun-Gu;Park, Seong-Jin;Luyima, Deogratius;Lee, Jae-Han;Oh, Taek-Keun
    • 농업과학연구
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    • 제47권4호
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    • pp.1049-1056
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    • 2020
  • Ultrafine dust causes asthma and respiratory and cardiovascular diseases when inhaled. Ammonia (NH3) plays a big role in ultrafine dust formation in the atmosphere by reacting with nitrogen oxides (NOx) and sulfur oxides (SOx) emitted from various sources. The agricultural sector is the single largest contributor of NH3, with the vast majority of emissions ensuing from fertilizers and livestock sector. Interest in using biochar to attenuate these NH3 emissions has grown. This experiment was conducted to study the effects of using rice hull biochar pyrolyzed at three different temperatures of 250℃ (BP 4.6, biochar pH 4.6), 350℃ (BP 6.8), and 450℃ (BP 10.3) on the emission of ammonia from soil fertilized with urea. The emissions of NH3 initially increased as the experiment progressed but decreased after peaking at the 84th hour. The amount of emitted NH3 was lower in soil with biochar amendments than in that without biochar. Emissions amongst biochar-amended soils were lowest for the BP 6.8 treatment, followed in an ascending order by BP 10.3 and BP 4.6. Since BP 6.8 biochar with neutral pH resulted in the lowest amount of NH3 emitted, it can be concluded that biochar's pH has an effect on the emissions of NH3. The results of this study, therefore, indicate that biochar can abate NH3 emissions and that a neutral pH biochar is more effective at reducing gaseous emissions than either alkaline or acidic biochar.

폐기물 고형연료(RDF)의 순환유동층 연소 및 증기생산 (Circulting Fluidized Bed Combustion of Refuse Derived Fuel and Steam Production)

  • 선도원;배달희;조성호;이승용
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 추계학술대회 논문집
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    • pp.613-616
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    • 2007
  • A pilot scale circulating fluidized bed for refuse derived fuel is developed and constructed in order to demonstrate efficient and safe utilization of waste fuel. The capacity of the facility is 8 steam tons per hour with the steam quality of $450^{\circ}C$ and 38atm. The quantity and the quality of the produced steam is sufficient to produce 1MWe power capacity. The test operation proved the high combustion efficiency of 99% and up. The emissions of NOx, SOx in flue gas are below 100, 60ppm respectively with out any emission control. HCl emissions were above 400ppm at the combustor exit but reduced below 10ppm after scrubber.

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패널분석을 이용한 6대 권역별 대기오염물질에 대한 환경규제와 경제성장 간의 상호관계분석: EKC(환경쿠즈네츠곡선)가설을 중심으로 (The correlation among the GHG (Greenhouse Gas) emission, energy consumption and economic growth for the 6 specific regions in Korea by using Panel approaches:By Testing of the EKC(Environmental Kuznets Curve))

  • 박추환
    • 환경정책연구
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    • 제12권2호
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    • pp.59-86
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    • 2013
  • 1988년부터 2008년까지의 자료를 바탕으로 우리나라 6개 권역을 대상으로 권역별 소득, 환경규제, 오염유발원이 각 권역별 대기오염 물질(황산화물, 질소산화물, 총먼지, 일산화탄소)에 미치는 영향을 지역적 관점에서 살펴보았다. 즉, 환경 쿠즈네츠 곡선(EKC)가설 검증차원에서 공해배출과 경제성장 간의 관계를 패널회귀분석을 통해 분석하였다. 분석 결과, 산업시설에 영향을 미치고 있는 황산화물(SOx)의 경우 대부분의 권역에서 EKC가설이 성립하는 것으로 나타났지만, 질소산화물(NOx)과 총먼지(TSP)의 경우 6개 권역 중 대경권에서만 EKC가설이 성립하는 것으로 나타났 으며, 일산화탄소(CO)의 경우에도 EKC가설을 충족시키는 권역은 중부권, 호남권, 동남권에 한정되어 있었다. 또한 각 권역별 대기오염 단속규제가 대기오염과 정(+)의 관계를 보임에 따라 환경규제효과가 나타난다고 보기 어려우며, 각 권역별 연료소비와 석유화학제품의 특화 또한 권역별 대기오염을 증가시키는 주요 요인으로 작용하고 있다.

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선박 대기오염물질 배출 현황 및 저감을 위한 국가 관리 대책 연구: 해양경찰 업무를 중심으로 (National Management Measures for Reducing Air Pollutant Emissions from Vessels Focusing on KCG Services)

  • 이승환;강병용;정봉훈;구자영
    • 해양환경안전학회지
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    • 제26권2호
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    • pp.163-174
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    • 2020
  • 미세먼지 등 대기오염이 일상화되고 국민 건강을 위협하면서 육상뿐만 아니라 해상 선박에서 발생하는 대기오염물질에 대한 관리 필요성이 대두되고 있다. 이에 본 연구는 선박 배출량 현황을 바탕으로 해양경찰 업무 중심의 선박 대기오염물질 점검 실태를 진단하고 배출 저감을 위한 국가 관리 대책을 제안한다. 최근 국립환경과학원(NIER, 2018)에 따르면 선박에서 배출된 총량(CO, NOx, SOx, TSP, PM10, PM2.5, VOCs, NH3, BC)은 국내 전체 발생량의 6.4 %로 나타났고, 이 중 NOx는 13.1 %, SOx는 10.9 %, 미세먼지(PM10/PM2.5)는 9.6 %를 차지하고 있다. 선박 발생량 중에서는 국내외 입출항 화물선이 50.6 %로 가장 많은 배출을 보였고, 어선의 배출 비율도 42.6 %로 적지 않음을 알 수 있었다. 지역적으로 해양경찰 관할 5개 권역을 기준으로는 부산항, 울산항을 포함한 남해권 44.1 %와 광양항, 여수항을 포함한 서해권 24.8 % 순으로 배출이 많았다. 해양경찰은 대기오염물질 관리를 위해 승선 점검을 통한 선박 배출 상황을 관리하고 있지만, 각종 배출 장치의 가동이나 연료유 기준 등의 실측에는 많은 시간과 노력이 필요하고, 또한 선박의 바쁜 운항스케줄에 따른 제약으로 대부분 서류상의 점검으로 진행됨으로써 관리에 한계가 있다. 따라서 선박 대기오염물질 관리를 위해서는 대기오염물질 발생을 실측 점검으로 바꾸도록 규제를 강화하고 해경 함정 등을 활용한 해역별 모니터링 시스템을 구축하여 실질적 현장 데이터에 기초한 관리가 이뤄지도록 하는 한편, 장단기적으로 환경친화적 선박 도입을 위한 기술 개발과 법·제도적 지원이 필요하다.