• Title/Summary/Keyword: SOX3

Search Result 266, Processing Time 0.05 seconds

Theoretical Investigation for the Adsorption of Atmospheric Harmful Gases on the Germanene Sheet (게르마닌 시트의 대기오염 기체 흡착에 대한 이론적 연구)

  • Seo, Hyun-Il;Kim, DongHyun;Baek, SooJin;Shin, ChangHo;Kim, SeungJoon
    • Journal of the Korean Chemical Society
    • /
    • v.64 no.6
    • /
    • pp.334-344
    • /
    • 2020
  • The adsorption of various atmospheric harmful gases (COx, NOx, SOx) on graphene-like Germanene 2D sheet was theoretically investigated using density functional theory(DFT) method. The structures were fully optimized at the B3LYP/cc-pvDZ and CAM-B3LYP/cc-pvDZ levels of theory and confirmed to be a local minimum by the calculation of the harmonic vibrational frequencies. The adsorptions of gases on the Germanene sheet were predicted to be a physisorption process for CO, CO2, NO, and SO2 gases but to be a chemisorption process for NO2, SO, and SO2 gases.

A Study on the removal of $NO_x$ by using Non-thermal Plasma Discharge (Non-thermal Plasma Discharge를 이용한 $NO_x$ 제거에 관한 연구)

  • 안정언;이석현;정용원
    • Proceedings of the Korea Air Pollution Research Association Conference
    • /
    • 2001.11a
    • /
    • pp.419-420
    • /
    • 2001
  • 최근 산업설비 및 기타 시설에서 배출되는 유해가스의 배출허용 기준이 계속 강화되고 있으며 그 중에서도 NOx는 SOx와 함께 대기오염의 주된 원인으로 작용하고 있다. 국내에서도 이들 유해가스를 제거하기 위한 플라즈마 적용기술이 활발히 연구되었으며, 일부 기술은 상용화 단계에 있다. NOx 제거에 있어서 펄스 코로나 방전에 의한 전자의 생성은 유입되는 가스 및 공기에 충돌하여 반응성이 큰 다량의 이온, 원자 및 radical(N, O, OH, $O_3$등)을 생성한다. (중략)

  • PDF

Uncertainty Evaluation of NOx Measurement in Ambient Air (환경대기 중 NOx 측정의 불확도 평가)

  • 임종명;이진홍;우진춘
    • Proceedings of the Korea Air Pollution Research Association Conference
    • /
    • 2002.04a
    • /
    • pp.141-142
    • /
    • 2002
  • 대기환경 기준물질(criteria pollutants)은 NOx를 비롯하여 $O_3$, CO, SOx, PM 10, Pb 인데, 이러한 물질은 환경부에서 법적으로 규정한 대기오염공정 시험법에 따라서 분석된다. 대기오염공정 시험법이 충분한 과학적 근거를 갖는 분석법이 되기 위해서는 분석방법, 분석기기, 분석자 등에 의해 발생되는 불확실성을 최소화시키는 체계적인 관리가 필요하고, 분석기술의 발달수준, 측정분석의 요구수준, 새로운 국제 규격 통에 맞게 지속적으로 보완되어야 한다. (중략)

  • PDF

중국의 장기전력 수급전망

  • 가즈야 후지메
    • 에너지협의회보
    • /
    • s.40
    • /
    • pp.63-73
    • /
    • 1996
  • 중국의 전력소비는 1980-92년간 연율 7.9$\%$ 증가했으며, 1992-2010년간 실질 GNP 성장률이 연율 8$\%$라는 전제하에 전력소비는 연률 7.8$\%$증가할 것이다.(1992-2000년간은 연율 9$\%$, 2000-2010년간은 연율 7$\%$ 예상). 가정 및 상업부문 전기소비가 산업부문보다 급속히 증가할 것으로 보이는데, 이것은 소득증가로 가전기기의 보유가 늘어나기 때문이다. 지속적인 GNP서장의 제약요인으로 SOx, NOx, $CO_2$ 배출 등 환경 문제가 될 것이며, 발전 송전 배전인프라 건설에 필요한 자본투자규모가 1조달러에 이른다. 2010년에는 3백만b/d의 석유, 1백만톤의 석탄, 13.5백만톤의LNG 등 에너지수입에 국제수지균형이 애로요인으로 작용할 것으로 보인다.

  • PDF

Phase Equlibrium Analysis of Slagging Propensity of Coal Ash in Combustion/Gasification Environments (상평형도를 이용한 연소/가스화 조건에서의 석탄회분의 슬래깅 성향해석)

  • 최병철;김형택
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
    • /
    • 1999.11a
    • /
    • pp.75-81
    • /
    • 1999
  • 석탄가스화 복합발전기술은 석탄과 산화제의 부분 연소 반응 및 가스화 반응을 통하여 가스 생성 후 불순물을 용이하게 분리할 수 있으므로 기존의 미분탄 발전 방식에 비해 대기 오염물질인 H$_2$S 및 NH$_3$ 등의 SOx, NOx 등의 발생량을 저감시킬 뿐만 아니라 발전 효율이 높아 $CO_2$ 발생량도 줄일 수 있는 장점이 있다.(중략)

  • PDF

Combustion Characteristics of Coal-Fired Boiler Depending on the Variations in Combustion Air Supply Method (미분탄 보일러의 연소용 공기공급 변화에 따른 노내 연소상태 해석)

  • Seo, San-Il;Park, Ho-Young;Kang, Dong-Soo;Jeong, Dong-Hae
    • Journal of Energy Engineering
    • /
    • v.19 no.3
    • /
    • pp.156-162
    • /
    • 2010
  • 3-D CFD(Computational Fluid Dynamics) work were carried out to investigate the combustion characteristics in a boiler depending on the variations in air supply condition. For the gas temperature, $O_2$, NO, SOx at the outlet of economizer, the predicted values were been compared with the measured data. With the verified CFD model, the effects of air flow rates through SOFA(Separated Over Fire Air) and CCOFA(Closed Coupled Over Fire Air) on the combustion behavior in a boiler were simulated, and the distributions of NOx and gas temperature were mainly compared each other. The change in SOFA air flow rate gave the more sensitive effect on NOx than that in CCOFA. The distributions of gas temperature at convection path are differed with the changes in SOFA and CCOFA flow rate, so the combustion modification such as yaw anlge adjustment are required to get an enhanced gas temperature distribution.

The Effect of Spray Flow Rate, Aspect Ratio, and Filling Rate of Wet Scrubber on Smoke Reduction (습식 스크러버의 분무유량, 형상비 및 충진율 변화가 스모크 저감에 미치는 영향)

  • Son, Kwun;Lee, Ju-Yeol;Park, Kweon-Ha
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.39 no.3
    • /
    • pp.217-222
    • /
    • 2015
  • There has been increased amount of atmospheric pollutants including NOx and SOx which cause acid rain and photochemical smog as a result of increased use of fossil fuels. In order to reduce the amount of pollutants produced by fossil fuel, wet scrubber system is introduced in this experiment. Wet scrubber system is applied to a diesel engine (3,298 cc) and the amount of smoke is measured before and after the application in terms of aspect ratio, filling rate, and flow rate. The result showed a lot of smoke reduction when wet scrubber system was applied, and also the aspect ratios and water spray flow rate were the important factors to improve smoke reduction.

Experimental Study of Dohongsamul-tang (Taohongsiwu-tang) on Fracture Healing (도홍사물탕(桃紅四物湯)이 골절 유합에 미치는 실험적 연구)

  • Ha, Hyun Ju;Oh, Min-Seok
    • Journal of Korean Medicine Rehabilitation
    • /
    • v.30 no.2
    • /
    • pp.47-66
    • /
    • 2020
  • Objectives The purpose of this study is to evaluate the bone healing effect of Dohongsamul-tang (Taohongsiwu-tang; DH) on femur fractured mice. Methods Mice were randomly divided into 4 groups (naive, control, positive control and DH). All groups except naive group were subjected to bone fracture on both hind limb femurs. Naive group received no treatment at all. Control group was fed with normal saline, and positive control group was orally medicated with tramadol. DH-treated group was orally medicated with DH. We analysed the levels of BMP2, COX2, Col2a1, Sox9, Runx2, and Osterix genes on 3, 7 and 14 days after fracture. Alkaline phosphatase, aspartate aminotransferase, alanine aminotransferase, blood urea nitrogen, creatinine, total cholesterol, and triglyceride levels were measured for safety assessment. Results In morphological, histological analysis, callus formation process of DH-treated group was faster than the control group. BMP2, Sox9 gene expression were significantly increased at 7 days after fracture compared to the control group. COX2, Col2a1 gene expression were significantly increased at 14 days after fracture compared to the control group. Total cholesterol was significantly increased by DH at 3 days. Triglyceride was significantly decreased by DH at 3, 7 days after fracture compared to the control group. Conclusions Dohongsamul-tang promoted bone healing process after fracture by stimulating the bone regeneration factors. And DH shows no hepatotoxicity, nephrotoxicity and serum lipid abnormality. In conclusion, it seems that DH helps to promote fracture regeneration after bone fracture by regulating gene expressions related to bone repair.

Application of Gas to Particle Conversion Reaction to increase the DeSOx/DeNOx Efficiency under Pulsed Corona Discharge (DeSOx/DeNOx 효율 개선을 위한 펄스 코로나 방전하에서 기체미립자 전환반응의 적용)

  • Choi, Yu-ri;Kim, Dong-Joo;Kim, Kyo-Seon
    • Journal of Industrial Technology
    • /
    • v.18
    • /
    • pp.249-258
    • /
    • 1998
  • In this paper, we investigated the post-combustion removal of nitrogen oxide($NO_x$) and sulfur oxide($SO_x$) which is based on the gas to particle conversion process by the pulsed corona discharge. Under normal pressure, the pulsed corona discharge produces the energetic free electrons which dissociate gas molecules to form the active radicals. These radicals cause the chemical reactions that convert $SO_x$ and $NO_x$ into acid mists and these mists react with $NH_3$ to form solid particles. Those particles can be removed from the gas stream by conventional devices such as electrostatic precipitator or bag filter. The reactor geometry was coaxial with an inner wire discharge electrode and an outer ground electrode wrapped on a glass tube. The simulated flue gas with $SO_x$ and $NO_x$ was used in the experiment. The corona discharge reactor was more efficient in removing $SO_x$ and $NO_x$ by adding $NH_3$ and $H_2O$ in the gas stream. We also measured the removal efficiency of $SO_x$ and $NO_x$ in a cylinder type corona discharge reactor and obtained more than 90 % of removal efficiency in these experimental conditions. The effects of process variables such as the inlet concentrations of $SO_x$, $NH_3$ and $H_2O$, residence time, pulse frequencies and applied voltages were investigated.

  • PDF

Acceleration of Mesenchymal-to-Epithelial Transition (MET) during Direct Reprogramming Using Natural Compounds

  • Seo, Ji-Hye;Jang, Si Won;Jeon, Young-Joo;Eun, So Young;Hong, Yean Ju;Do, Jeong Tae;Chae, Jung-il;Choi, Hyun Woo
    • Journal of Microbiology and Biotechnology
    • /
    • v.32 no.10
    • /
    • pp.1245-1252
    • /
    • 2022
  • Induced pluripotent stem cells (iPSCs) can be generated from somatic cells using Oct4, Sox2, Klf4, and c-Myc (OSKM). Small molecules can enhance reprogramming. Licochalcone D (LCD), a flavonoid compound present mainly in the roots of Glycyrrhiza inflata, acts on known signaling pathways involved in transcriptional activity and signal transduction, including the PGC1-α and MAPK families. In this study, we demonstrated that LCD improved reprogramming efficiency. LCD-treated iPSCs (LCD-iPSCs) expressed pluripotency-related genes Oct4, Sox2, Nanog, and Prdm14. Moreover, LCD-iPSCs differentiated into all three germ layers in vitro and formed chimeras. The mesenchymal-to-epithelial transition (MET) is critical for somatic cell reprogramming. We found that the expression levels of mesenchymal genes (Snail2 and Twist) decreased and those of epithelial genes (DSP, Cldn3, Crb3, and Ocln) dramatically increased in OR-MEF (OG2+/+/ROSA26+/+) cells treated with LCD for 3 days, indicating that MET effectively occurred in LCD-treated OR-MEF cells. Thus, LCD enhanced the generation of iPSCs from somatic cells by promoting MET at the early stages of reprogramming.