• Title/Summary/Keyword: SO2

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Studies on the Preparation for the Simultaneous Removal of NO and $SO_2$ from Stationary Sources I.Surface properties and reactivity of $V_2O_5-MoO_3/TiO_2$ catalysts (고정원에서 배출되는 $NO_x/SO_x$의 동시제거를 위한 SCR 촉매의 제조법에 관한 연구: I. $V_2O_5-MoO_3/TiO_2$ 촉매들의 표면특성과 반응성)

  • 구미화;정석진
    • Journal of Korean Society for Atmospheric Environment
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    • v.8 no.1
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    • pp.58-67
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    • 1992
  • For removing $NO_x$ and $SO_x$ from the flue gases emitted from stationary sources, $V_2O_5-MoO_3/TiO_2$ catalysts were prepared by the conventional impregnation method (aqueous solution) and a sort of surface fixation method(nonaqueous solution) as reported excellent reproducibility catalysts. And these catalysts observed their catalytic activities as well as their surface properties. V-Mo-O oxide, prepared from nonaqueous solution of $VOCl_3$ and $Mo(CO)_6$ and aqeous solution method, was supported as amorphous state by XRD and SEM measurements. The infrared spectra of fresh and used catalysts showed that in used catalysts, V=O bands decreased and new bands of vanadium oxysulfate bands were very sensitive. So the catalysts prepared from nonaqueous solution may bring about the high activity. Results from catalytic activity measurements at 350$^\circ$C, in the presence of $SO_2, NO$ conversion was more increased than in absence of $SO_2$. As the $MoO_3$ was added to $V_2O_5/TiO_2 system, SO_2$ conversion increased. It found that from the results, $V_2O-5-MoO_3/TiO_2$ catalysts prepared from an nonaqueous solution may bring about the high activity for both the reaction of NO and $SO_2$ removal.

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Studies on the Acceleration of Germination in Carrot Seed (3) Effect of some Inorganic Compounds on the Germination of Carrot Seed (당근 종자 발아 촉진에 관한 연구 (3) 당근 종자의 발아에 있어서 몇가지 무기염류의 영향)

  • 권오용
    • Journal of Plant Biology
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    • v.14 no.2
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    • pp.1-6
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    • 1971
  • When germination beds of carrot seeds were treated with either 0.01M or 0.05M concentrations of Ca(NO3)2, CaSO4, MgSO4, K2SO4 and KH2PO4, an acceleration in the germination rate was observed in the groups treated with 0.01M KH2PO4 and 0.05M MgSO4 and 0.05M Ca(NO2)3. In earlier work by the author with acetone a similar result was observed and reported. The pH range in these experiments was maintained between 5.0 and 6.0. It was found that the groups treated with 0.05M K2SO4, 0.05M Ca(NO3)2, 0.05M Ca(NO3)2, 0.05M MgSO4, 0.01M KH2PO4, 0.01M Ca(NO3)2 germinated earlier than the control group. The acceleration of the germintion rate varied with the inorganic compounds used in the following descending order; 0.01M KH2PO4, 0.05M Ca(NO3)2, 0.05M K2SO4, 0.05M CaSO4 and 0.05M KH2PO4. As a result of these expriments, it occurs to the author that in the germination of carrot seeds some inorganic compounds appear to activate the osmotic function of carrot seeds causing acceleration in the germination rate.

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$CaSO_4$ Decomposition and Desulfurization in In-Furnace Desulfurization for Oxy-Fuel Combustion Using DTF (DTF를 이용한 순산소연소 조건에서 탈황반응과 $CaSO_4$ 분해 특성)

  • Choi, Wook;Jo, Hang-Dae;Choi, Won-Kil;Park, Yeong-Sung;Keel, Sang-In;Lee, Hyung-Keun
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.6
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    • pp.420-425
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    • 2011
  • In general, the decomposition of $CaSO_4$ formed by sulfation reaction in the in-furnace desulfurization process using limestone has strong effect on the desulfurization reaction under the oxy-fuel combustion condition. In this study, the conversion rates were measured and reaction rates were calculated in order to investigate the effects of the experimental variables such as temperature and the concentrations of $CO_2$, $O_2$, $SO_2$, on the $CaSO_4$ decomposition reaction using DTF (Drop Tube Furnace) in the desulfurization reaction. The conversion rate and the reaction rate of $CaSO_4$ decomposition reaction were increased with reaction temperature. $CO_2$ concentration has little effect on $CaSO_4$ decomposition reaction in the presence of $O_2$. Under the same experimental conditions, the decomposition rate of $CaSO_4$ was enhanced with the decreasing the $O_2$ concentration, but vice versa with the increasing of $SO_2$ concentration.

Absorption Characteristics of Sulfur Dioxide in Jet Bubbling Reactor (가스분사반응기에서의 SO2 흡수 특성)

  • Choi, Byung-Sun;Park, Seung-Soo;Kim, Yung-whan
    • Applied Chemistry for Engineering
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    • v.5 no.5
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    • pp.836-842
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    • 1994
  • The optimum design conditions of gas sparger pipe and the effects of operating variables on $SO_2$ removal efficiency have been examined in Jet Bubbling Reactor. Geometry of gas sparser pipe of Jet Bubbling Reactor is a very important factor to obtain a effective gas-liquid contact. Test results revealed that Reynolds numbers at sparger and slot have to be kept greater than 12,000 identically at a given gas velocity. $SO_2$ removal efficiency was a function of ${\Delta}P$, pH, inlet $SO_2$ concentration and particle size of limestone and was more sensitive to the change of ${\Delta}P$ than to the changes of others. The ${\Delta}P$ of at least 230mmAq must be maintained to acheive the above 90% $SO_2$ removal at pH of 4.0 which is considered as adequate operating pH. Higher $SO_2$ removal efficiency was obtained even at lower pH ranges, which resulted from the complete oxidation of the absorbed $SO_2$ to sulfates by adding air and consequently from the reduction of $SO_2$ equillibrium partial pressure in the gas-liquid interface The 99.5% of the limestone utilization was attained in pH range from 3.0 to 5.0 with regardless to the particle size of limestone employed.

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Changes of Photosynthetic Pigment Contents and SOD Activity in the Leaves of Four Tree Species Exposed to SO2 (SO2 노출된 4개 수종의 엽내 광색소 함량 및 SOD 활성 변화)

  • 이재천;한심희;권기원;우수영;최정호
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.5 no.1
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    • pp.18-23
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    • 2003
  • This study was conducted to compare physiological responses of Pinus densiflora, Populus ${\times}$ tomentiglandulosa, Quercus acutissima and Eleutherococcus sessiliflorus exposed to SO$_2$, by measuring photosynthetic pigment contents and SOD activity. Four woody plants were exposed to relatively high SO$_2$ concentration (500 ppb, 800 ppb) for 8h day$^{-1}$ for 7 days in a chamber. Photosynthetic pigment contents in the leaves of four species decreased with increase of SO$_2$ concentration; also chlorophyll a, chlorophyll b and total carotenoid content were significantly different among tree species and treatments. The ratio of chlorophyll b to chlorophyll a of E. sessiliflorus and Q. acutissima increased for 500 ppb treatment but decreased at 800 ppb. This result showed that chlorophyll a was destroyed by 500 ppb SO$_2$ and chlorophyll b by 800 ppb SO$_2$. Therefore, the sensitivity of chlorophyll a to SO$_2$ may be higher than that of chlorophyll b. SOD activity differed significantly between species and treatments. SOD activity of E. sessiliflorus and Q. acutissima increased at 500 ppb but decreased at 800 ppb, but P. densiflora and P ${\times}$tomentiglandulosa maintained high SOD activity at both 500 ppb and 800 ppb. Based on the photosynthetic pigment contents and SOD activity in the leaves of four tree species, the tolerance of P. ${\times}$ tomentiglandulosa to SO$_2$ was the highest of four tree species.

Reflectance and Flexural Modulus of ABS/TiO2 Composite Sheets (ABS/TiO2 복합체 쉬트의 반사율과 굴곡 탄성률)

  • Kim, Jun Hong;Yoon, Kwan Han
    • Polymer(Korea)
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    • v.38 no.1
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    • pp.103-107
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    • 2014
  • Poly(acrylonitrile-butadiene-styrene) (ABS) composite sheets containing titanium dioxide ($TiO_2$), barium sulfate ($BaSO_4$), calcium carbonate ($CaCO_3$) were prepared by using a co-rotating twin screw extruder, and the reflectance and flexural modulus of the composite sheets were measured. The fillers were well dispersed in ABS matrix. The reflectance of composite sheet was increased with increasing $TiO_2$ and $BaSO_4$ content. Sheet having $TiO_2$ 20 wt% composition, with 5~20 wt% $BaSO_4$ resulted in more than 95% of reflectance. The flexural modulus of composite sheet was increased from 1864 MPa for $ABS/TiO_2/BaSO_4$ 85/10/5 (w/w/w) to 3134 MPa for $ABS/TiO_2/BaSO_4$ 55/20/25 (w/w/w).

A Study on Consumer Values Clothing Shopping Orientation and Clothing Satisfaction (성인여성의 가치인식과 의복쇼핑성향 및 의복만족에 관한 연구)

  • 구자명;이명희
    • Journal of the Korean Society of Clothing and Textiles
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    • v.23 no.3
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    • pp.459-470
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    • 1999
  • The objectives of this study were to investigate the difference the clothing shopping orientation and clothing satisfaction according to satisfaction·dissatisfaction group to examine how the clothing satisfaction was influenced by consumer values demographic variable clothing shopping orientation. The subject were 457 women in Seoul Korea The results of the study were as follows. 1. five factors of clothing shopping orientation (SO) derived by factor analysis : F.1. conspicious SO : F,2 search SO: F,3 recreational SO : F,4 addictive SO :F,5 independent SO . Two factors of terminal value derived by factor analysis : F,1 responsible : F.2 ambitious. 2. Satisfaction group had high levels of search SO, dissatisfaction group had high levels of addictive SO. Satisfaction group was satisfied with color style appropriateness for wearer in order dissatisfaction group was dissatisfied with care price size in order. 3. Conspicious SO were influenced bysocial stratification social recognition and happiness. Search SO were influenced by dwelling area and age. Recreational SO were influenced by social stratification social recognition and responsible value. Addictive SO influenced by responsible value social recognition and happiness. independent SO were influenced by marital status and ambitious value. 4. Clothing satisfaction was influenced by addictive conspicious SO happiness and recreational SO(R2=24.6)

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Ab initio 양자화학적 계산을 이용한 이온성 액체의 SO2 흡수능 연구

  • Choe, Jeong-Yong;Kim, Seon-Gyeong;Park, Yeong-Geun;Lee, Jin-Yong
    • Proceeding of EDISON Challenge
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    • 2014.03a
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    • pp.39-51
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    • 2014
  • 산성비의 주요 원인인 이산화황($SO_2$)을 배기가스로부터 효과적으로 제거하기 위한 용매 중 이온성 액체(ionic liquid, IL)의 $SO_2$ 흡수능 (absorption capacity)을 양자화학적 방법을 이용하여 평가했다. 이를 위해 hydroxyl ammonium 계열의 양이온 monoethanolammonium, diethanolammonium 2종과 carboxylate 계열의 음이온 acetate, formate 2종을 조합하여 총 4종의 IL을 연구에 적용했다. $SO_2$가 IL의 pair, 양이온 또는 음이온과 complex를 형성할 때로 구분하여 계산 모델을 세웠으며, 열역학적 상태 변화와 오비탈 상호작용 분석을 통해 흡수능을 평가하였다. 계산 결과, 음이온-$SO_2$ complex를 적용했을 때 formate에 비해 acetate가 $SO_2$ 흡수에 유리할 것으로 분석되었으며, 이는 이전의 실험 연구에서 얻어진 흡수능 경향성과도 잘 맞는다.

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Sulfur Dioxide, Mineral Contents and Physicochemical Properties Generated during Manufacture of Bamboo Salt (죽염 제조공정에 따른 이산화황, 미네랄 함량 및 이화학적 특성)

  • Kim, Hag-Lyeol;Lee, Seong-Jae;Lee, Jung-Hee;Kim, In-Cheol
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.43 no.8
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    • pp.1248-1256
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    • 2014
  • The purpose of this study was to investigate the mechanisms of behind $SO_2$ formation and elevated cause of reducing power in purple bamboo salt (PBS) along with an analysis of physicochemical properties, content of sulfur compounds, oxidation reduction potential (ORP), mineral contents of salt type (MSS, mudflat solar salt; BS, bamboo salt), and addition of raw bamboo (RB). $SO_2$ content of 630 ppm was detected in PBS. $SO_2$ was not detected in MSS, BS, or RB, whereas $SO_2$ (782 ppm) from $K_2SO_4$ was detected after heating a NaCl, KCl, $MgCl_2$, $MgSO_4$, MgO, $CaCl_2$, $K_2SO_4$, and $FeSO_4$ with RB. $SO_2$ content of BS increased with baking time, and it originated from BSRB1 (13.88 ppm) to BSRB4 (109.13 ppm). $SO_3{^{2-}}$ originated only from MSSRB4 and BSRB2~BSRB4. Sulfate ion content decreased along with increasing $SO_2$ and sulfite ion contents. ORP increased with baking time of MSS and BS, and it was present at higher levels in BSRB4 (-211.40 mV) of BS than MSS. Insoluble content was higher in BS than MSS. Further, Ca, K, and Mg ion contents decreased in MSS and increased in BS with baking time. BSRB4 had 1.4 fold higher levels of Ca, 1.5 fold higher levels of Mg, and 1.8 fold higher levels of K than BS. Li, Al, Mn, Fe, and Sr in MSS as well as Al, Fe, and Ni in BS increased with baking time. Anions (Cl, $NO_3$, and Br) and heavy metals (Pb, Cd, Hg, and As) between MSS and BS were not significantly different. These results suggest that the reducing power of BS was due to $SO_2$ and sulfite ion. To increase the amounts of these compounds and reducing power, higher melting temperature and longer baking time are necessary along with BS, which is created by the addition of RB to roasted salt.

The Effects of $NO_2$ and $SO_2$ Gas on the Paper and the Textile Cultural Properties (지류.섬유질 유물에 대한 대기유해가스($SO_2$, $NO_2$)의 영향)

  • Lee, Kyu-Shik;Han, Sung-Hee
    • 보존과학연구
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    • s.17
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    • pp.65-99
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    • 1996
  • We exanmined the each effect of $NO_2$ and $SO_2$gas, the maincomponets of air pollutants, on the deterioration of 6 organic materials with Gasexposure cabinet. The organic materials were used 2 kind of papers(Korean paper, Oldbook paper) and 4 kind of textiles (Cotton, Silk, Hemp, ramie) in gas exposure experiments. In order to know how to change of physical conditions, the materials were exposed to 2000, 1000 ppm. h of $SO_2$dose, to 100 ppm. h of $NO_2$ dose at 65% RH. The color difference, tensile strength, elongation coeffient, mass reduction and fabric status of each materials were discussed the following below.1. The color difference of cotton and hemp was larger than that of silk and ramie in the presence of $SO_2$ gas. and the color difference of korean paper was less than that of the textile materials in the presence of $SO_2$ gas.2. The tensile strength of cotton fell suddenly at 100ppm.h of $SO_2$ dose and even became 56% of the unexposed cotton.3. The weight of 6 materials began to decrease in the presence of $SO_2$ gas.4. The tensile strength and elongation of the materials tended to decrease at 12.5ppm.h of $NO_2$ especially silk was the strongest tendency to decrease.5. Cotton, hemp and ramie were influenced by $SO_2$ gas more than by $NO_2$, but silk were influenced by $NO_2$ more thang by $SO_2$ at 10ppm.h of each noxious gas.

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