• Title/Summary/Keyword: SI이론

Search Result 385, Processing Time 0.031 seconds

Theoretical Studies of the Structures and Electronic Properties of CumSiOm+1 Clusters (m = 0 - 7) (CumSiOm+1 클러스터(m = 0 - 7)의 분자구조 그리고 전기적 특성에 관한 이론 연구)

  • Na, Ho-Hyun;Nam, Seong-Hyun;Lee, Gi-Yun;Jang, Ye-Seul;Yoon, Duck-Young;Bae, Gyun-Tack
    • Journal of the Korean Chemical Society
    • /
    • v.60 no.4
    • /
    • pp.239-244
    • /
    • 2016
  • We investigated the structures and electronic properties of CumSiOm+1 clusters with m = 0 - 7. For these clusters, we replaced a Cu atom in the copper oxide clusters with a Si atom. The B3LYP functional and LANL2DZ basis set were used for optimization of the molecular structures of all neutral and charged clusters. The bond distances, bond angles, and Mulliken charges were calculated to study the structural properties. In addition, in order to understand the electronic properties, we examined the ionization energies, electronic affinities, and second differences in energies.

Estimating Tensile Force of Hangers in Suspension Bridges Using Frequency Based SI Technique : III. Experimental Verification (진동기반의 SI 기법을 이용한 현수교 행어의 장력 추정 : III. 실험적 검증)

  • Jang, Han Teak;Kim, Byeong Hwa;Park, Taehyo
    • KSCE Journal of Civil and Environmental Engineering Research
    • /
    • v.28 no.2A
    • /
    • pp.215-222
    • /
    • 2008
  • This paper introduces an experimental verification of a tension estimation method based on system identification approach for a double hanger system on a suspension bridge. A laboratory model of such double hanger system has been made for this study. Total nine cases of the vibration tests have been conducted with respect to three levels of applied tension and three cases of the location of clamp. For a set of the collected acceleration response data, modal analysis has been followed in order to extract the natural frequencies and mode shapes of the selected cable systems. For the extracted modal parameters, the existing tension estimation methods based on the string theory and axially loaded beam theory have been firstly applied to estimate the tensile force on the double hanger cable system. Next, the tensile force on cables has been estimated by the system identification approach. It is seen that the errors in the tension estimation using the frequency-based system identification technique are about 3% for all cases while the estimation error using the existing method is up to 53.1%.

Long-Life Demonstration Housing Infill Construction : Theory and Practical Limits (장수명 실증주택 인필 시공: 이론과 현실적 한계)

  • Kim, Soo-Am;Yang, Hyeon-Jeong
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2019.05a
    • /
    • pp.89-90
    • /
    • 2019
  • The purpose of this study is to clarify the difference between design and construction conditions based on theory for support (S) and infill (I) distinction and separation in long-life housing, and to search for future direction. To do this, the SI theory is summarized and the construction situation is examined in the demonstration house and the differences and limitations are analyzed. In order to realize SI separation in Korea, it is necessary to set the position of pipe shafts for sewage and drainage, buried in the structure and Ondol layer of the private pipes, buried various wires in the inner wall, and fixing the position of the inner wall.

  • PDF

Numerical simulation for ultrafine SiC powder synthesis using the vapor phase reaction (기상반응을 이용한 SiC 초미분말 합성에 관한 수치모사)

  • 유용호;어경훈;송은석;이성철;소명기
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.9 no.6
    • /
    • pp.563-569
    • /
    • 1999
  • The numerical simulation method was utilized to investigate the optimal condition for synthesizing ultrafine SiC powders by using $TMS[Si(CH_3)_4]-H_2$ gaseous mixtures in the horizontal reactor. As a result of the theoretical analysis, the conversion percentage of TMS source was increased with increasing reaction temperature, however, which was decreased with increasing H$_2$flow rate. Though the SiC particles concentration synthesized was decreased with increasing the reaction temperature due to the higher collision rate in the gas phase, they were increased with increasing the H$_2$flow rate and TMS concentration. The SiC particle size showed a tendency to become larger as the reaction temperature and the initial TMS concentration were increased and smaller as the H$_2$ flow rate was increased. The variation of experimental particle size with the reaction temperature, H$_2$flow rate and TMS concentration was agreed with the theoretical results.

  • PDF

Varying Refractive Index of Antireflection Layer for Crystalline Si Solar Cell

  • Yeo, In-Hwan;Park, Ju-Eok;Kim, Jun-Hui;Jo, Hae-Seong;Im, Dong-Geon
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.02a
    • /
    • pp.702-702
    • /
    • 2013
  • 태양전지에서 SiNX층은 반사방지막 역할과 태양전지 소자 보호 역할 2가지를 동시에 하고 있다. 태양전지에서 반사방지막은 굴절률 1.97, 두께 76 nm가 이론적으로 최적의 상태이다. PECVD장비를 이용하여 SiNx 층을 증착하였다. SiNX층 증착 시에 RF 파워와 혼합 가스를 변화한 후 굴절률을 측정하였다. RF 파워는 100~400 W로 변화시켰고 혼합가스 변화는 SiH4가스와 N2, H2, N2+H2 가스 각각을 같이 넣어 주면서 증착하였다. SiNX 가스 자체에 N2가 80%섞여 있는 가스를 사용하기 때문에 SiH4 가스자체 만으로도 SiNx층을 형성 할 수 있다. RF파워 300 W, SiH4 50 sccm, 기판 온도 $300^{\circ}C$, 공정시간 63초에서 굴절률 1.965, 두께 76 nm를 갖는 SiNx층을 형성 할 수 있었고 개방전압: 0.616 V, 전류밀도: 37.78 mA/$cm^2$, 충실도:76.59%, 효율: 17.82%로 가장 높은 효율을 얻을 수 있었다.

  • PDF

Nondestructive Determination of Reinforcement Volume Fractions in Particulate Composites : Ultrasonic Method (비파괴적 방법에 의한 입자 강화 복합재료의 부피분율 평가: 초음파법)

  • Jeong, Hyun-Jo
    • Journal of the Korean Society for Nondestructive Testing
    • /
    • v.18 no.2
    • /
    • pp.103-111
    • /
    • 1998
  • A nondestructive ultrasonic technique is presented for estimating the reinforcement volume fractions of particulate composites. The proposed technique employs a theoretical model which accounts for composite microstructures, together with a measurement of ultrasonic velocity to determine the reinforcement volume fractions. The approach is used for a wide range of SiC particulate reinforced Al matrix ($SiC_p/Al$) composites. The method is considered to be reliable in determining the reinforcement volume fractions. The technique could be adopted in a production unit for the quality assessment of the metal matrix particulate composite extrusions.

  • PDF

The Impact of Ethical Leadership on Unethical Pro-Supervisor Behavior: The Mediating Effect of Supervisor Identification and Affective Commitment (윤리적 리더십이 비윤리적 친상사 행동에 미치는 영향: 상사동일시와 정서적 몰입의 매개효과를 중심으로)

  • Goh, Seung-Suk;Tak, Jinkook
    • The Journal of the Korea Contents Association
    • /
    • v.21 no.9
    • /
    • pp.221-233
    • /
    • 2021
  • This study empirically examined the relationships among ethical leadership, supervisor identification(SI), affective commitment(AC), and unethical pro-supervisor behavior(UPSB) based on social learning theory and social exchange theory. The data were collected by conducting a survey of 339 workers and analyzed using SPSS25 and SPSS Process Macro (v3.5). The results were as follows. First, ethical leadership directly negatively influences UPSB. Ethical leadership indirectly positively influences UPSB mediated by SI. Second, ethical leadership, completely mediated by AC, indirectly positively influences UPSB. Third, ethical leadership has an indirect positive effect on AC mediated by SI. This study showed how ethical leadership works in organizations through social learning theory and social exchange theory. Also, it suggested implications on how to use ethical leadership in field.

A Study on Extrusion Forces in Hot Extursion of Al-Si Alloys (AI-Si 합금의 열간압출에 있어서 압출압력에 관한 연구)

  • Jo, Hyeong-Ho
    • Korean Journal of Materials Research
    • /
    • v.4 no.7
    • /
    • pp.837-844
    • /
    • 1994
  • To investigate that the theoretical formulas for extrusion forces are applicable to the manufacturing plant, the maximum extrusion forces were calculated from Siebel's and Geleji's formulas and also measured using 550 ton extrusion press. Parameters such as flow stress, $K_f$, angle of dead metal zone, $\alpha$ were obtained experimentally in order to calculate the maximum extrusion forces by the the theoretical formulas, and it was showed that the results were reliable as the deformation efficient factor, $\eta _f$ was determined to be less than 0.5. The maximum extrusion forces calculated from Siebel's formula and Geleji's formula for the angle of dead metal zone, $\alpha = 50^{\circ}$ were approached to the experimental results. However, it was found that Siebel's formula is more useful to apply to the manufacturing plant.

  • PDF

Interaction of acetone molecule on Si(001) surface: A theoretical study (Si(001) 표면과 acetone 분자의 상호작용에 대한 이론적 연구)

  • Baek, Seung-Bin;Kim, Dae-Hee;Kim, Yeong-Cheol
    • Journal of the Semiconductor & Display Technology
    • /
    • v.7 no.3
    • /
    • pp.35-39
    • /
    • 2008
  • We study the interaction of acetone molecule $[(CH_3)_2CO]$ on Si(001) surface using density functional theory. An acetone molecule is adsorbed on a Si atom of the Si dimer of the Si(001) surface. The adsorption of the acetone molecule on the Si atom at lower height between the two Si atoms of the dimer is more favorable than that on the Si atoms at upper height. Then we calculate an energy variation of dissociation and four-membered ring structures of the acetone molecule adsorbed on the Si surface. Total energy difference between the two structures is about 0.05 eV, indicating that the two structures are almost equally stable. Energy barrier exists when a hydrogen atom is dissociated and adsorbed on the other Si atom of the dimer, while energy barrier does not exist when the adsorbed acetone molecule changes to four-membered ring structure, except for the rotation of the acetone molecule along z-direction. Therefore, four-membered ring structure is kinetically more favorable than the dissociation structure when the acetone molecule is adsorbed on the Si(001) surface.

  • PDF