• 한국세라믹학회지
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• 제33권2호
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• pp.235-241
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• 1996

Self-Propagating high temperature synthesis(SHS) technique was used to synthesize the spinel phase of MgAl2O from MgO and Al powder. Processing factors such as mixing time preheating temperature and ignition catalyst were varied to determine the optimum condition to form MgAl2O4 phase. The reaction products were heat treated at the temperature range of 120$0^{\circ}C$ and 150$0^{\circ}C$. to observe phase transformation of unreacted materials. Processing factors such as 48 hrs-mixing 80$0^{\circ}C$-preheating and 20wt% KNO3-ignition catalyst were effective of the formation of MgAl2O spinel. An activation energy 49.7kcal/mol. was calculated to form a MaAl2O4 spinel from unreacted materials.

• 한국세라믹학회지
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• 제30권12호
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• pp.1096-1102
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• 1993

Titanium nitride was synthesized by reacting Ti powder with nitrogen gas using SHS method. In this process, the effects of nitrogen pressure, dilution with TiN, or additiion of titanium hydride(TiH1.924) on the conversion of Ti to TiN were investigated. In particular, much effects were given to solve the problem of the conversion drop due to partial melting and subsequent sintering of Ti parciels, by controlling combustion temperature and combustion wave velocity via mixing Ti powder with TiN or/and TiH1.924. For the diluted titanium powders with TiN, the conversion close to 100% was resulted when the nitrogen pressure was over 8atm and with diluent content of 60wt%, and the self-propagating reaction was not sustained when the diluent content was higher than 60wt%. For samples mixed to be 55wt% in Ti component in the mixture of Ti, TiH1.924, and 45% TiN, the conversion was closed to 100% when the amount of titanium hydride added was over 7wt% and the nitrogen pressure was higher than 5atm. The combustion reaction, however, was not sustained when titanium hydride added was more than 10wt%.

• 한국세라믹학회지
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• 제27권1호
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• pp.118-126
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• 1990

Titanium Cabride powders were prepared by the self-propagating high temperature synthesismethod in air from the mixture of metal titanium powder and carbon powder. The result are as follows : 1. The conversion effciency of higher than 95% can be obtained and the lattice constant value of the product was 4.322$\AA$. 2. The combustion mode, velocity and temperature of combustion wave was photographed using high-speed camera, and showed steady-state, velocity of 15.414mm/sec at 250$0^{\circ}C$. 3. The relative density and MOR strength of TiC sintered at 180$0^{\circ}C$ for 90 minutes by hot-pressing under the pressure of 200kg/$\textrm{cm}^2$ were 95% and 395MPa, respectively.

• 한국세라믹학회지
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• 제37권4호
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• pp.332-337
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• 2000

Forming mechanism of fibrous TiC during self-propagating high temperature synthetic reaction was analyzed and suggested. It was revealed that critical temperature for the stable fiber formation was not the melting point of TiC, but the eutectic reaction temperature of TiC and C. Minimum amount of TiC diluent addition required to form fibers was calculated to be 25.6%, which was consistent with the experimental result. Synthesized fibers were found hollow tube-like. The morphology was explained by the diffusion rates of C and Ti in TiC, and by the molar volume chnage of C during the reaction. Expanding shell model was suggested for the hollow fiber formation mechanism.

• 한국결정학회지
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• 제9권1호
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• pp.44-47
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• 1998

가정용 2.45GHz 마이크로파 오븐을 사용하여 A1 금속분말과 SiO2 분말간에 SHS방법에 의하여 산화/환원 반응을 통한 Al2O3 분말과 Si분말간의 복합체를 얻을 수 있었다. 분말간의 반응을 일으키기 위한 온도까지 승온시키기 위하여는 SiC 분말을 susceptor로 이용한 마이크로파 복합가열(Microwave Hybrid Heating)방법을 사용하여 분당 100℃의 승온 속도로 가열하였으며 반응은 850℃ 근처에서 일어났으며 가열 속도는 반응이 시작되면서 분당 200℃ 이상의 온도상승이 일어나면서 원하는 반응을 얻을 수 있었다.

• 한국재료학회지
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• 제24권5호
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• pp.255-258
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• 2014

Zirconium boride is an artificial or which is rarely found in the nature. $ZrB_2$ is popular in the hard material industry because it has a high melting point, excellent mechanical properties and chemical stability. There are two known methods to synthesize $ZrB_2$. The first involves direct reaction between Zr and B, and the second is by reduction of the metal halogen. However, these two methods are known to be unsuitable for mass production. SHS(Self-propagating High-temperature Synthesis) is an efficient and economic method for synthesizing hard materials because it uses exothermic reactions. In this study, $ZrB_2$ was successfully synthesized by subjecting $ZrO_2$, Mg and $B_2O_3$ to SHS. Because of the high combustion temperature and rapid combustion, in conjunction with the stoichiometric ratio of $ZrO_2$, Mg and $B_2O_3$; single phase $ZrB_2$ was not synthesized. In order to solve the temperature problem, Mg and NaCl additives were investigated as diluents. From the experiments it was found that both diluents effectively stabilized the reaction and combustion regime. The final product, made under optimum conditions, was single-phase $ZrB_2$ of $0.1-0.9{\mu}m$ particle size.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 1994년도 추계학술대회 논문집
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• pp.303-308
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• 1994

The finite element method has been used to model and analyze the heat transfer phenomena during manufacturing process of MoSi $_{2}$ by SHS. For this urpose nonlinear transient heat transfer analyses by using ANSYS have been performed to compute the temperature distributiuon and the peak temperature in the test specimen. The effects of manufacturing process parameters such as a pre-heating temperature, the velocity of reaction zone have also been investigated. The results of the analysis have been compared with the experimental results.

• 한국세라믹학회지
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• 제43권9호
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• pp.588-593
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• 2006

Spinel phase $LiMn_2O_4$ is of great interest as cathode materials for lithium-ion batteries. In this study, SHS (Self propagating High-temperature Synthesis) method to synthesize spinel $LiMn_2O_4$ directly from lithium nitrate, manganese oxide, manganese and sodium chloride were investigated. The influence of Li/Mn ratio, the heat-treated condition of product have been explored. The resultant $LiMn_2O_4$ synthesized under the optimum synthesis conditions shows perfect spinel structure, uniform particle size and excellent electrochemical performances.

• 한국세라믹학회지
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• 제31권10호
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• pp.1159-1168
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• 1994

We powders were synthesized from W powders in differnet particle sizes by Self-propagating High-temperature Synthesis process (SHS) using a chemical furnace. The effects of the mole ratio of chemical fuel content, pellet thickness and the mole ratio between carbon and tungsten (C/W Ratio) on synthesis were investigated with the tungsten powders have different particle size each other. Compositional and structural characterization of these powders was carried out by scanning electron microscope (SEM0 and x-ray diffractometer. Powder characterization was carried out by the measurement of particle size distribution with laser-particle size analyzer. The amounts of WC obtained by SHS process depend very much on the particle size of tungsten powder and heat contents given in a product, i.e. as the particle size of W powder is smaller, the amounts of WC produced increase. Also the more heat contents is given, the more amounts of WC increase. By optimizing the synthesis conditions, it is possible to fabricate WC powders which have little secondary phases (W2C, C).

• 한국분말재료학회지
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• 제5권4호
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• pp.250-257
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• 1998

The synthesis of titanium silicides ($Ti_3Si$, $TiSi_2$, $Ti_5Si_4$, $Ti_5Si_3$ and TiSi) by mechanical alloying has been investigated. Rapid, self-propagating high-temperature synthesis (SHS) reactions were observed to produce the last three phases during room-temperature high-energy ball milling of elemental powders. Such reactions appeared to be ignited by mechanical impact in an intimate, fine powder mixture formed after a critical milling period. During the high-energy ball milling, the repeated impact at contact points leads to a local concentration of energy which may ignite a self-propagating reaction. From in-situ thermal analysis, each critical milling period for the formation of $Ti_5Si_4$, $Ti_5Si_3$ and TiSi was observed to be 22, 35.5 and 53.5 min, respectively. $Ti_3Si$ and $TiSi_2$, however, have not been produced even till the milling period of 360 min due to lack of the homogeneity of the powder mixtures. The formation of titanium silicides by mechanical alloying and the relevant reaction rates appeared to depend upon the critical milling period, the homogeneity of the powder mixtures, and the heat of formation of the products involved.