• Title/Summary/Keyword: SEM evaluation

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Characterization of Water Hyacinth (Eichhornia crassipes) Biomass and Evaluation of Applicability as an Organic Filler to Papermaking (부레옥잠 바이오매스의 특성분석과 제지적용성 평가)

  • Kim, Dong Sung;Heo, Yoon Sung;Sung, Yong Joo;Han, Seung-Won;Seo, Cheol Mo
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.5
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    • pp.79-87
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    • 2014
  • The enrichment with nutrients in rivers and lakes becomes serious problems in Korea. As the environmental friendly solution, the phytoremediation are getting more attention and the water hyacinth could be a strong candidate plant for this. Water hyacinth is a free floating freshwater plant proven to be a effective plant used for a purification of a polluted lakes, sewage wastewater, and livestock wastewater. The biggest obstacles for application of water hyacinth in Korea could be the disposal of the water hyacinth before winter, because there is no feasible use for the water hyacinth until now. In this study, the characteristics of water hyacinth were deeply investigated for providing background data to develop appropriate application of the water hyacinth. The water hyacinth was fractioned three parts, leaf, air blader, root of which morphological properties were evaluated with microscope and field emission scanning electron microscope (FE-SEM). The water contents of each parts of the water hyacinth were 87% for leaf, 96.5% for air bladder, 94.6% for root. The chemical compositions of each parts were also measured and showed around 29% of hot water extract in leaf and air bladder, 42% holocellulose for leaf, 47% holocellulose for air bladder. The application of water hyacinth biomass without root parts to papermaking provided bulkier structure, but the tensile strength was decreased.

Development and Evaluation of Non-Hydrous Skin Analogue Liquid Crystal using Thermo-Sensitivity Smart Sensor

  • Yoo, Kwang-Ho;Hong, Jae-Hwa;Eun, So-Hee;Jeong, Tae-Hwa;Jeong, Kwan-Young
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.3
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    • pp.367-374
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    • 2014
  • In this study, skin permeation enhancement was confirmed by designing it to have a structure and composition similarity to the intercellular lipids that improve miscibility with skin by cross-linked lipids poloxamer. The cross-linked lipids poloxamer was synthesized and analyzed by 1H NMR that structure dose had conjugated pluronic with ceramide3. Active component is released by modification of liquid crystal structure because PPO part, large-scale molecule block of pluronic, has hydrophobic nature at skin temperature of $35^{\circ}C$. Conjugated pluronic with ceramide3 was synthesized using Pluronic F127 and p-NPC (4-nitrophenyl chloroformate) at room temperature yielded 89%. Pluronic(Ceramide 3-conjugated Pluronic) was synthesized by reaction of p-NP-Pluronic with Ceramide3 and DMAP. The yield was 51%. This cross-linked lipids poloxamer was blended and dissolved at isotropic state with skin surface lipids, phospholipid, ceramide, cholesterol and anhydrous additive solvent. Next step was preceded by ${\alpha}$-Transition at low temperature for making the structure of Meso-Phase Lamella, and non-hydrous skin analogue liquid crystal using thermo-sensitivity smart sensor, lamellar liquid crystal structure through aging time. For confirmation of conjugation thermo-sensitivity smart sensor and non-hydrous skin analogue liquid crystal, structural observation and stability test were performed using XRD(Xray Diffraction), DSC(Differential Scanning Calorimetry), PM (Polarized Microscope) And C-SEM (Cryo-Scanning Electron Microscope). Thermo-sensitivity observation by Franz cell revealed that synthesized smart sensor shown skin permeation effect over 75% than normal liquid crystal. Furthermore, normal non-hydrous skin analogue liquid crystal that not applied smart sensor shown similar results below $35^{\circ}C$ of skin temperature, but its effects has increased more than 30% above $35^{\circ}C$.

Evaluation of Soil Improvement by Carbonate Precipitation with Urease (요소분해효소에 의한 탄산칼슘 침전을 통한 지반 개량 평가)

  • Song, Jun Young;Sim, Youngjong;Jin, Kyu-Nam;Yun, Tae Sup
    • Journal of the Korean Geotechnical Society
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    • v.33 no.9
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    • pp.61-69
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    • 2017
  • This study presents the experimental results of $CaCO_3$ formation in sand by the Enzyme Induced Carbonate Precipitation (EICP) method. Concentration of $CaCO_3$ with elapsed reaction time is calibrated by standardized procedure by measuring $CO_2$ pressure, and it increases with time towards asymptotic value. Jumunjin sand saturated with EICP solution shows that both shear wave velocity and electrical conductivity sharply increase as the reaction starts to approach to the constant values after 50 hours of reaction time. Urease concentration of 0.5 g/L exhibits 224% higher final shear wave velocity than that of 0.1 g/L. The nucleation models hint that carbonate tends to precipitate not only at grain contacts but also at grain surfaces. Regardless of urease concentration, electrical conductivity and shear wave velocity follow the unique path. The scanning electron microscopic images and X-ray computed tomographic images validate the spatial configuration of produced $CaCO_3$ in soils.

Fabrication and Evaluation Properties of Titanium Sintered-body for a Sputtering Target by Spark Plasma Sintering Process (방전플라즈마 소결 공정을 이용한 스퍼터링 타겟용 타이타늄 소결체 제조 및 특성 평가)

  • Lee, Seung-Min;Park, Hyun-Kuk;Youn, Hee-Jun;Yang, Jun-Mo;Woo, Kee-Do;Oh, Ik-Hyun
    • Korean Journal of Metals and Materials
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    • v.49 no.11
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    • pp.845-852
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    • 2011
  • The Spark Plasma Sintering(SPS) method offers a means of fabricating a sintered-body having high density without grain growth through short sintering time and a one-step process. A titanium compact having high density and purity was fabricated by the SPS process. It can be used to fabricate a Ti sputtering target with controlled parameters such as sintering temperature, heating rate, and pressure to establish the optimized processing conditions. The compact/target(?) has a diameter of ${\Phi}150{\times}6.35mm$. The density, purity, phase transformation, and microstructure of the Ti compact were analyzed by Archimedes, ICP, XRD and FE-SEM. A Ti thin-film fabricated on a $Si/SiO_2$ substrate by a sputtering device (SRN-100) was analyzed by XRD, TEM, and SIMS. Density and grain size were up to 99% and below $40{\mu}m$, respectively. The specific resistivity of the optimized Ti target was $8.63{\times}10^{-6}{\Omega}{\cdot}cm$.

Mechanical Properties and cytotoxicity of nitrided 630 Stainless by ion nitriding (플라즈마 이온질화에 따른 STS 630의 기계적 특성과 세포독성에 관한 융합적 연구)

  • Hwang, Gab-Woon
    • Journal of the Korea Convergence Society
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    • v.10 no.11
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    • pp.241-246
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    • 2019
  • In this study, we have examined the possibility to improve the material properties and biocompatibility of the 630 stainless steel for the application of medical instruments. The evaluation of mechanical properties and biocompatibility of the 630 stainless steel were studied by aging, nitriding, SEM measurement, Vicker's hardness, tensile strength and MTT cytotoxicity using IGF cells, respectively. The results showed that the tensile strength and Vicker's hardness of 630 stainless steel was increased with aging and ion nitriding time. The cytotoxicities of the 630 stainless decreased compared with the 420 stainless on MTT cytotoxicity using IGF cells. Ion nitriding of 630 stainless led to an enhanced application of medical instruments and biocompatibility performance.

Evaluation of Strength and Durability of Mortar using Ferronickel Slag Powder and Admixtures (페로니켈슬래그 미분말 및 혼화재의 복합사용에 따른 모르타르의 강도 및 내구성 평가)

  • Jo, Seol-Ah;Yoo, Jeong-Hwan;Park, Sang-Soon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.3
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    • pp.262-270
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    • 2019
  • Ferronickel slag, which is an industrial byproduct, is activated by mechanochemical reaction as a nonferrous metal and can be used as an admixture. Therefore, ferronickel slag is used as a substitute resource of admixture. In this study, to evaluate the effect of mixed of ferronickel slag powder and admixture, a mortar using a mixture of ferronickel slag powder, quicklime, gypsum and calcium chloride was fabricated by vibrated and rolled manufacturing method. Strength were evaluated by flexural and compressive strength tests, and durability was evaluated by performing chlorine ion penetration resistance and chemical resistance test. When the substitution ratio of ferronickel slag powder is constant, it is considered that the mixed use of quicklime, gypsum and calcium chloride as admixtures increases the performance.

A Study on the Residual Stress Evaluation of Autofrettaged SCM440 High Strength Steel (자긴가공된 SCM440 고강도강의 잔류응력평가에 관한 연구)

  • Kim, Jae-Hoon;Shim, Woo-Sung;Yoon, Young-Kwen;Lee, Young-Shin;Cha, Ki-Up;Hong, Suck-Kyun
    • Journal of the Korean Society of Propulsion Engineers
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    • v.14 no.4
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    • pp.39-45
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    • 2010
  • Thick-walled cylinders, such as a cannon or nuclear reactor, are autofrettaged to induce advantageous residual stresses into pressure vessels and to increase operating pressure and the fatigue lifetimes. As the autofrettage level increases, the magnitude of compressive residual stress at the bore also increases. The purpose of the present paper is to predict the accurate residual stress of SCM440 high strength steel using the Kendall model which was adopted by ASME Code. Hydraulic pressure process was applied in the inner part and thick-walled cylinders were autofrettaged up to 30% overstrain levels. Electro polishing on the surface of autofrettage specimen was performed to get more accurate residual stress. Residual stresses were measured by X-ray diffraction method. The autofrettage surface which was plastically deformed analyzed using a scanning electron microscope(SEM). Although there were some differences in measured residual stress and numerical results, it has a tendency to agree comparatively with each other.

Cost-based design of residential steel roof systems: A case study

  • Rajan, S.D.;Mobasher, B.;Chen, S.Y.;Young, C.
    • Structural Engineering and Mechanics
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    • v.8 no.2
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    • pp.165-180
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    • 1999
  • The cost effectiveness of using steel roof systems for residential buildings is becoming increasingly apparent with the decrease in manufacturing cost of steel components, reliability and efficiency in construction practices, and the economic and environmental concerns. While steel has been one of the primary materials for structural systems, it is only recently that its use for residential buildings is being explored. A comprehensive system for the design of residential steel roof truss systems is presented. In the first stage of the research the design curves obtained from the AISI-LRFD code for the manufactured cross-sections were verified experimentally. Components of the truss systems were tested in order to determine their member properties when subjected to axial force and bending moments. In addition, the experiments were simulated using finite element analysis to provide an additional source of verification. The second stage of the research involved the development of an integrated design approach that would automatically design a lowest cost roof truss given minimal input. A modified genetic algorithm was used to handle sizing, shape and topology variables in the design problem. The developed methodology was implemented in a software system for the purpose of designing the lowest cost truss that would meet the AISI code provisions and construction requirements given the input parameters. The third stage of the research involved full-scale testing of a typical residential steel roof designed using the developed software system. The full scale testing established the factor of safety while validating the analysis and design procedures. Evaluation of the test results indicates that designs using the present approach provide a structure with enough reserve strength to perform as predicted and are very economical.

Evaluation of the efficiency of cleaning method in direct contact membrane distillation of digested livestock wastewater

  • Kim, Sewoon;Park, Ki Young;Cho, Jinwoo
    • Membrane and Water Treatment
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    • v.8 no.2
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    • pp.113-123
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    • 2017
  • This study investigated effects of physical and chemical cleaning methods on the initial flux recovery of fouled membrane in membrane distillation process. A laboratory scale direct contact membrane distillation (DCMD) experiment was performed to treat digested livestock wastewater with 3.89 mg/L suspended solids, 874.7 mg/L COD, 543.7 mg/L nitrogen, 15.6 mg/L total phosphorus, and pH of 8.6. A hydrophobic PVDF membrane with an average pore size of $0.22{\mu}m$ and a porosity of 75 % was installed inside a direct contact type membrane distillation module. The temperature difference between feed and permeate side was maintained at $40^{\circ}C$ with the feed and permeate stream velocity of 0.18 m/s. The results showed that the permeate flux decreased from $22.1L{\cdot}m^{-2}{\cdot}hr^{-1}$ to $19.0L{\cdot}m^{-2}{\cdot}hr^{-1}$ after 75 hours of distillation. The fouled membrane was cleaned first by physical flushing and consecutively by chemicals with NaOCl and citric acid. After the physical cleaning the flux was recovered to 92 % as compared with the initial clean water flux of the virgin membrane. Then 94 % of the flux was recovered after cleaning by 2,000 ppm NaOCl for 90 minutes and finally 97 % of flux recovered after 3 % citric acid for 90 minutes. SEM-EDS and FT-IR analysis results presented that the foulants on the membrane surface were removed effectively after each cleaning step. The contact angle measurement showed that the hydrophobicity of the membrane surface was also restored gradually after each cleaning step to reach nearly the same hydrophobicity level as the virgin membrane.

Synthesis of size-controlled ZnO tetrapods sizes using atmospheric microwave plasma system and evaluation of its photocatalytic property (대기압 마이크로웨이브 플라즈마를 이용한 다양한 크기의 ZnO tetrapod 합성 및 광촉매 특성 평가)

  • Heo, Sung-Gyu;Jeong, Goo-Hwan
    • Journal of the Korean institute of surface engineering
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    • v.54 no.6
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    • pp.340-347
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    • 2021
  • Among various metal oxide semiconductors, ZnO has an excellent electrical, optical properties with a wide bandgap of 3.3 eV. It can be applied as a photocatalytic material due to its high absorption rate along with physical and chemical stability to UV light. In addition, it is important to control the morphology of ZnO because the size and shape of the ZnO make difference in physical properties. In this paper, we demonstrate synthesis of size-controlled ZnO tetrapods using an atmospheric pressure plasma system. A micro-sized Zn spherical powder was continuously introduced in the plume of the atmospheric plasma jet ignited with mixture of oxygen and nitrogen. The effect of plasma power and collection sites on ZnO nanostructure was investigated. After the plasma discharge for 10 min, the produced materials deposited inside the 60-cm-long quartz tube were obtained with respect to the distance from the plume. According to the SEM analysis, all the synthesized nanoparticles were found to be ZnO tetrapods ranging from 100 to 600-nm-diameter depending on both applied power and collection site. The photocatalytic efficiency was evaluated by color change of methylene blue solution using UV-Vis spectroscopy. The photocatalytic activity increased with the increase of (101) and (100) plane in ZnO tetrapods, which is caused by enhanced chemical effects of plasma process.