• Journal of Technologic Dentistry
• /
• v.25 no.1
• /
• pp.21-28
• /
• 2003

The purpose of this study was to process bio-active glass ceramic composite, reinforced with sapphire fibers, by hot press. Also to study the interface of the matrix and the sapphire fiber, and the mechanical properties. Glass raw materials melted in Pt crucible at 1300$^{\circ}C$ during 3.5 hours. The melt was crushed in ball mill and then crushed material, ground and sieved to $<40{\beta}{\mu}m$. Sapphire fibers cut (30mm) and aligned. Powder and fibers hot pressed. The micrographs show good bonding between the matrix and the fiber and no porosity in the glass matrix. This means ideal fracture phenomena. Glass is fractured before the fiber. This is indication of good fracture strength. EDXS showing aluminum rich phase and crystalline phase. Bright field image of the matrix showing crystalline phase. Also diffraction pattern of TEM showing the crystalline phase and more than one phase. Strength of the samples was determined by 3 point bend testing. Strength of the 10vol% sample was approximately 69MPa, while strength of the control sample is 35MPa. Conclusions through this study as follow: 1. Micrographs show no porosity in the glass matrix and the interface. 2. The interface between the fiber and the glass matrix show no gaps. 3. Fracture of the glass indicates characteristic fiber-matrix separation. 4. Presence of crystalline phase at high processing temperature. 5. Sapphire is compatible with bioactive glass.

• International Journal of Control, Automation, and Systems
• /
• v.2 no.2
• /
• pp.256-262
• /
• 2004

Conventionally, profile non-uniformity has been characterized by relying on approximated profile with angle or anisotropy. In this study, a new non-uniformity model for etch profile is presented by applying a discrete wavelet to the image obtained from a scanning electron microscopy (SEM). Prediction models for wavelet-transformed data are then constructed using a back-propagation neural network. The proposed method was applied to the data collected from the etching of tungsten material. Additionally, 7 experiments were conducted to obtain test data. Model performance was evaluated in terms of the average prediction accuracy (APA) and the best prediction accuracy (BPA). To take into account randomness in initial weights, two hundred models were generated for a given set of training factors. Behaviors of the APA and BPA were investigated as a function of training factors, including training tolerance, hidden neuron, initial weight distribution, and two slopes for bipolar sig-moid and linear function. For all variations in training factors, the APA was not consistent with the BPA. The prediction accuracy was optimized using three approaches, the best model based approach, the average model based approach and the combined model based approach. Despite the largest APA of the first approach, its BPA was smallest compared to the other two approaches.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2010.08a
• /
• pp.224-224
• /
• 2010

최근 반도체 나노막대의 구조적, 광학적 특성을 이용한 새로운 개념의 광학 및 전자 소자 개발을 위한 연구가 활발히 진행되고 있다. 기존의 반도체 나노막대는 gold를 촉매로 하여 성장한 것이 대부분이었지만, gold 촉매는 다른 물질에 빠르게 확산되기 때문에 반도체 특성에 좋지 않은 영향을 미친다. 이러한 이유로 aluminum이나 titanium과 같은 물질을 gold 촉매 대신 사용하거나 촉매를 사용하지 않는 성장 방법에 관한 이슈들이 주목받고 있다. 본 연구에서는 금속 촉매 물질을 사용하지 않고 반도체 나노막대 성장을 시도하였다. 금속 촉매 없이 반도체 나노막대를 성장하는 것은 반도체 특성에 악영향을 미치지 않을 뿐더러, 공정 과정이 용이하다는 장점 때문에 최근 많이 시도되고 있다. 본 실험에서는 Molecular Beam Epitaxy (MBE) 방법을 이용하여 (100) GaAs 기판 위에 GaAs 나노막대를 성장하였다. 금속 촉매 없이 반도체 나노막대를 성장하기 위해 에칭된 $SiO_2$ 층을 이용하였다. GaAs 기판 위에 형성된 35nm 두께의 $SiO_2$를 20:1 BOE 용액에서 10초 간 에칭하면 $SiO_2$상에 pinhole을 형성하는데 이것이 gallium과 반응하면 나노막대 성장을 유도하는 seed가 만들어져 촉매를 사용하지 않고도 나노막대 성장이 가능하다. GaAs 나노막대 성장을 위해 BOE 에칭 조건, gallium incubation time 유무, GaAs 나노막대 성장온도, galiium과 arsenic의 성분 비율, GaAs 양 등을 변화시켜 실험하였고 이렇게 성장된 나노막대가 SEM image 상에서 관찰되었다.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2014.02a
• /
• pp.232.2-232.2
• /
• 2014

Since its discovery in 2004, graphene, a sp2-hybridized 2-Dimension carbon material, has drawn enormous attention. A variety of approaches have been attempted, such as epitaxial growth from silicon carbide, chemical reduction of graphene oxide and CVD. Among these approaches, the CVD process takes great attention due to its guarantee of high quality and large scale with high yield on various transition metals. After synthesis of graphene on metal substrate, the subsequent transfer process is needed to transfer graphene onto various target substrates, such as bubbling transfer, renewable epoxy transfer and wet etching transfer. However, those transfer processes are hard to control and inevitably induce defects to graphene film. Especially for wet etching transfer, the metal substrate is totally etched away, which is horrendous resources wasting, time consuming, and unsuitable for industry production. Thus, our group develops one-step process to directly grow graphene on glass substrate in plasma enhanced chemical vapor deposition (PECVD). Copper foil is used as catalyst to enhance the growth of graphene, as well as a temperature shield to provide relatively low temperature to glass substrate. The effect of growth time is reported that longer growth time will provide lower sheet resistance and higher VSG flakes. The VSG with conductivity of $800{\Omega}/sq$ and thickness of 270 nm grown on glass substrate can be obtained under 12 min growing time. The morphology is clearly showed by SEM image and Raman spectra that VSG film is composed of base layer of amorphous carbon and vertically arranged graphene flakes.

• Korean Journal of Materials Research
• /
• v.27 no.10
• /
• pp.530-533
• /
• 2017

ZnO micro/nanocrystals with different morphologies were synthesized by thermal evaporation of various zinc source materials in an air atmosphere. Zinc acetate, zinc carbonate and zinc iodide were used as the source materials. No catalysts or substrates were used in the synthesis of the ZnO crystals. The scanning electron microscope(SEM) image showed that the morphology of ZnO crystals was strongly dependent on the source materials, which suggests that source material is one of the key factors in controlling the morphology of the obtained ZnO crystals. Tetrapods, nanogranular shaped crystals, spherical particles and crayon-shaped crystals were obtained using different source materials. The X-ray diffraction(XRD) pattern revealed that the all the ZnO crystals had hexagonal wurtzite crystalline structures. An ultraviolet emission was observed in the cathodoluminescence spectrum of the ZnO crystals prepared via thermal evaporation of Zn powder. However, a strong green emission centered at around 500 nm was observed in the cathodoluminescence spectra of the ZnO crystals prepared using zinc salts as the source materials.

• Korean Journal of Digital Imaging in Medicine
• /
• v.12 no.2
• /
• pp.145-150
• /
• 2010

Thick films of carbon fiber were prepared by a heating element of plan shape made in Darin co., We have investigated surface morphology of the specimen depending on heat-treatment temperatures. Scanning electron microscope(SEM) image of carbon fiber thick films of the specimen heat treated shows a grain growth at $1200^{\circ}C$ and becomes a poly-crystallization at $1350^{\circ}C$. The variation of resistivity at the thermally annealed specimen above $600^{\circ}C$ depends on type of the substrates. It may be due to a variation of film thickness and a difference of interfacial phenomena. A heating element of features was affected significantly by skin blood and quantity of heat of the body physiological function. After radiation of farinfrared for plate heating element, the function of biometric physiological is considered of skin blood flow and calorie which greatly affects on individuals. Electromagnetic wave was not influence on the body.

• Applied Microscopy
• /
• v.40 no.4
• /
• pp.267-270
• /
• 2010

The skin is the largest organ of the integument system whose surface is closely related with many physiological and pathological conditions. Various methods are used to understand the structural and functional status of human skin. We would like to present usefulness of scanning electron microscopic (SEM) observation of skin replica and its significance of training module for a novice. The silicon replicas from several regions of the body (hand, finger, forearm, lip, and face) were casted by applying Exafine$^{(R)}$ mixture. The positive replicas were prepared by applying EPON 812 mixture on negative silicon replicas. Some of the negative silicon replicas were cut with a razor blade and surface profiles were observed. The negative and positive replicas were coated with platinum and were observed under the scanning electron microscope. We could investigate the detailed structures of the human skin surface without any physical damage to the subject. The positive replicas depicted real surface structure of the human skin vividly. The cross sectional view of the negative silicon replicas provided surface profile clearly. The scanning electron microscopic observation of the human skin replicas would be useful to study skin surface structures and to evaluate medical and esthetical applications.

• Journal of Sensor Science and Technology
• /
• v.23 no.3
• /
• pp.170-172
• /
• 2014

$CO_2$ sensor was used only one solid electrolyte in many cases. To improve the sensing characteristics of $CO_2$ sensors, solid electrolyte $CO_2$ sensor has been developed by bi-electrolyte type sensor using Na-Beta-alumina and YSZ. However, in many further studies, bi-electrolyte type sensor was made by pellet pressed by press machine and additional treatment for formation of interface. In the aspect of mass production, using thick film and additional treatment is not suitable. In this study, $CO_2$ sensor was fabricated by bi-electrolyte structure which was made by an NBA paste layer deposited on YSZ pellet and fired at $1650^{\circ}C$ for 2 hour. The formation of stable interface between YSZ and NBA were confirmed by SEM image. When the type IV electrochemical cell arrangement represented by $CO_2,O_2,Pt{\mid}Li_2CO_3-CaCO_3{\parallel}NBA{\parallel}YSZ{\mid}O_2,Pt$ is used to measure the $CO_2$ concentration in air. This sensor EMF should depend only on the concentration of $CO_2$ by logarithmic. Also, sensor shows $P_{CO_2}$ and EMF relationship like nerstian reaction at a temperature of $450^{\circ}C$.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2010.08a
• /
• pp.195-195
• /
• 2010

In recent years, Anodic aluminum oxide(AAO) has become popular and attractive materials. It can be easily fabricated and self-organized pore structures. It has been widely used as a biosensor membrane, photonic crystal for optical circuit and template for nanotube growth etc. In previous papers, the theory was developed that AAO shows anisotropic optical properties, since it has anisotropic structure with numerous cylindrical pores. It gives rise to the anisotropy of the refractive index called as birefringence. It can be used as conventional polarizing elements with high efficiency and low cost. Therefore, we would like to compare the theory and experimental results in this study. One method which can measure effective refractive index of thin film is the prism coupling technique. It can give accurate results fast and simply. Furthermore, we can also measure separately the refractive index with different polarization using polarization of the laser (TE mode and TM mode). We calculated the effective refractive index with effective medium approximations (EMAs) by pore size in the SEM image. EMAs are physical models that describe the macroscopic system as the homogeneous and typical method of all mean field theories.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2012.02a
• /
• pp.581-581
• /
• 2012

나노스케일에서의 자구체(magnetic domain), 자화벽(magnetic domain wall)에 대한 연구가 활발하게 진행되고 있으며 특히 자화벽의 위치를 임의로 제어할 수 있는 기술을 응용한 메모리 소자에 대한 연구가 활발하다. 반면에 이러한 연구에 필수적인 자구체, 자화벽 이미징 장비는 매우 미비한 상황이다. 이와 같은 자성이미징(magnetic domain image), 자화벽(magnetic domain wall)을 연구하는데 있어 가장 핵심적인 장비가 SEMPA(Scanning Electron Microscopy with Polarization Analysis)이다. 일반적으로 SEM의 경우 고 에너지 빔의 전자 빔을 주사 시키고 이때 발생되는 이차 전자의 수를 2차원상의 영역에 따라 달라지는 비로 형상을 측정하게 된다. 이때 전자의 수 뿐만 아니라 이들의 spin polarization을 측정할 수 있다면 형상뿐 만 아니라 표면에서의 스핀 상태를 동시에 측정할 수 있게 된다. 기 개발된 W-filament source를 이용한 SEMPA는 field emission source에 비하여 전자빔의 세기가 약하며 이차 전자의 수도 적어 spin polarization 감도가 현저히 떨어진다. 또한 초고진공($1{\times}10^{-10}torr$)에서 사용할 수 없어 측정시료의 contamination을 방지할 수 없다. 이러한 문제점들을 보안하기 위하여 field emission source를 이용한 FE-SEMPA를 개발 중이며 2차전자의 spin polarization감도를 증가시키기 위하여 monte carlo simulation과 전산시늉등울 통해 스핀 검출기를 개발 및 연구결과를 발표하고자 한다.