• 제목/요약/키워드: SCN.

검색결과 166건 처리시간 0.027초

Effects of Specific Interaction Altering Reagents on Hardnesses of Succinylated Soy Protein Gel

  • Bae, Dongho;Jung, Hosun;Choi, Yong-Hee
    • Journal of Applied Biological Chemistry
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    • 제42권3호
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    • pp.125-129
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    • 1999
  • The changes in gel characteristics of soy protein and succinylated soy protein due to various specific interaction-altering reagents which affect the formation and textural properties of gels, were studied. The reagents were added to 15% soy protein solutions prior to heat treatment. Succinylated soy protein formed harder gel without the addition of reagents. Hardly no gels were formed with urea, indicating that hydrogen bonds significantly contributed to the formation and hardness of the gel and the effects of urea on the hardness of succinylated soy protein gel were more significant. Disulfide bonds were important in the formation of hard gels whether they were succinylated or not, but the contributions of hydrophobic interactions to gel hardness were relatively insignificant. The hardness reducing effects of NaCl and NaSCN were more significant in succinylated soy protein gel. As such, electrostatic interactions were important for succinylated soy protein to form hard gel but not for unmodified soy protein.

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Polymeric Iodide-ion Selective Electrodes Based on Urea Derivative as an Ionophore

  • Jeong, Dae-Cheol;Lee, Hyo-Kyoung;Jeon, Seung-Won
    • Bulletin of the Korean Chemical Society
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    • 제27권12호
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    • pp.1985-1988
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    • 2006
  • The polymeric membrane electrodes based on urea derivative as an ionophore were prepared and studied for the iodide-ion selective electrode. This membrane exhibits a linear stable response over a wide concentration range ($1.0\;{\times}\;10^{-5}\sim1.0\;{\times}\;10^{-2}$) with a slope of -57.7 mV/decade, a detection limit of log[$I^-$] = -5.63, and a selectivity coefficient for iodide against perchlorate anion (log$K^{pot}_{I^-,j}$ = -1.42). The selectivity series of the membrane gives the follow as $I^-$ > $SCN^-$, $Sal^-$ > $ClO_4^-$ > $NO_3^-$ > $Br^-$ > $NO_2^-$ > $Cl^-$ > $F^-$. The proposed electrode showed good selectivity and response for iodide anion over a wide variety of other anions in pH 5.0 buffer solutions.

작동매체에 따른 2중효용 흡수식 시스템의 성능해석 (Thermodynamic Analysis of Double-effect Absorption Heat Pump System with New Working Pairs)

  • 원승호;이영수
    • 설비공학논문집
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    • 제3권4호
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    • pp.250-255
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    • 1991
  • Performance analysis of double-effect absorption heat pump system has been done to find improved working pairs (or mixture) by computer simulation. Based on the thermodynamic analysis, the coefficient of performance and mass flow ratio are investigated to compare three aqueous solutions [LiCl-water, LiSCN-LiBr-water, LiCl-$CaCl_2$-$Zn(NO_3)_2$-water] which was developed for only cooling, with conventional LiBr-water solution. It is found that the performances of the new aqueous solutions are better than that of LiBr-water solution not only in cooling systems, but also in heating systems. Theoretical thermodynamic performance data can be used in heat recovery systems by basic design data.

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각종자극제가 고로슬래그 미분말 혼입 모르타르의 초기재령 압축강도 발현에 미치는 영향 (Effect of Early Compressive Strength Development with Blast Furnace Slag Using Various stimulants Mortar.)

  • 김진형;이한승
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2011년도 춘계 학술논문 발표대회 1부
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    • pp.57-58
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    • 2011
  • In the experiment, we add to NaOH, Ca(OH)2 and Calcium Hydroxide as the Slag stimulus also mixed the cement stimulus such as NaSCN, TEA and CaCl2 for improving compressive strenth of concrete which added the Blast Furnace Slag Powder at 1 and 3 days. In the result of strength test, It showed that 2percentage of activator 1 and 5percentage Ca(OH)2, 1percentage of activator 3 and 5percentage of Ca(OH)2 are higher than 100 percentage OPC.

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다관능성 에폭사이드 화합물로 처리한 양모섬유의 가교반응

  • 안형진;박영환
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 1996년도 추계 학술발표회
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    • pp.478-483
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    • 1996
  • 다관능성 에폭사이드 PPE(Polyglycerol Polyglycidyl Ether)를 양모섬유에 처리하였을 때 부가반응의 특성을 고찰하였다. 에폭사이드 PPE에 의한 부가반응이 촉매작용을 하는 NaSCN 존재하에서 이관능성 EGDE보다 높은 부가율을 얻을 수 있었다. 에폭사이드 부가반응은 고온에서 반응이 잘 일어나며 에폭사이드 처리욕의 pH는 반응 초기 급격히 상승했다가 이후 점차 초기 값까지 안정화된다. 처리한 양모섬유를 FTIR의 KBr-pellet법과 ATR법에 의해 분석하여 absorbance ratio를 비교하였을 때 부가반응은 표면으로의 그라프트 반응이 우세함을 알 수 있었으며 이러한 결과는 SEM 관측을 통하여 확인할 수 있었다. Performic acid/Ammonia solubility를 에폭사이드 처리 양모섬유에 적용하여 용해도 변화를 보았을 때 부가된 양이 많을수록 용해도 값이 감소하며 특히 15.6%를 중심으로 용해도 변화가 둔화되었다. 아미노산 분석으로 에폭사이드가 반응한 아미노산이 cystine임을 알 수 있었으며 단백질 사슬간에 가교반응이 이루어졌음을 확인할 수 있었다.

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티오시아네이트 및 4-메틸이미다졸 리간드로 구성된 1차원 카드뮴(II) 착물의 합성과 구조 분석 (Synthesis and Structural Characterization of the One-Dimensional Cadmium(II) Complex with Thiocyanate and 4-Methylimidazole Ligands)

  • 문형실;김종혁;이석근
    • 분석과학
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    • 제14권6호
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    • pp.535-539
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    • 2001
  • One-dimensional coordination polymer of cadmium(II) complex, $[Cd(SCN)_2(C_4H_6N_2]_n$, has been prepared and characterized by X-ray single crystallography. Structure analysis reveals that each cadmium(II) atom is six-coordinated in distorted octahedral fashion with $CdS_2N_4$ composition. $CdS_2N_4$ composition contains two S and two N atoms from four thiocyanates and tow N atoms from two 4-methylimidazole ligands. Central cadmium(II) atoms are run in parallel to the a-axis and are doubly bridged with neighboring cadmium(II) atoms by the thiocyanate and isothiocyanate ligands. Thus, this complex has a one-dimensional polymer structure in which the 4-methylimidazole is in the trans conformation.

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X-FTL 을 활용한 SQLite 다중버전 동시성 제어 (SQLite Multi-version Concurrency Control using X-FTL)

  • 이종백;오기환;이상원
    • 한국정보처리학회:학술대회논문집
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    • 한국정보처리학회 2014년도 추계학술발표대회
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    • pp.794-797
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    • 2014
  • 스마트 디바이스의 사용량 증가와 더불어 각종 가전기기의 스마트화로 인하여 임베디드 시스템에서 주로 사용되는 SQLite 데이터베이스에 대한 동시적 접근 제어의 중요성이 증가하였다. 플래시 메모리 저장장치 단계에서 트랜잭션의 원자성올 제공하는 X-FTL 은 SQLite 의 저널링 모드에서 발생하는 쓰기 연산으로 인한 성능 저하를 해결하였다. 또한 페이지 단위로 트랜잭션의 원자성을 관리하는 X-FTL 의 특징을 이용한다면 동시성 제어 측면의 성능 향상을 기대할 수 있다. 본 논문에서는 X-FTL 을 사용할 때 발생할 수 있는 동시성 제어 성능의 한계를 밝히고, X-FTL 의 X-L2P 테이블에 SCN 을 추가하여 SQLite 의 동시성 제어 성능을 향상할 수 있는 새로운 구조를 제안한다.

스테인스강의 표면특성에 미치는 플라즈마질화의 영향 (Effects of Plasma Nitriding on the Surface Charcteristice Of Stainless Steels)

  • 최한철;김관휴
    • 한국표면공학회지
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    • 제30권2호
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    • pp.144-154
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    • 1997
  • Effects of plasma nitriding on the surface charcteristice of stainless steel(SS) were investjgated by utilizing wear tester, micro-hardness tester and potentiostat. The surface and corrosion morphology of plasma nitrided SS were analyzed by utilizing optical microscopy, SEM, XRD and WDX. It was found that plasma nitriding at $550^{\circ}C$, compared with $380^{\circ}C$, prodiced a good wear resistance and hardness as nitriding time increased, whereas Mo addition showd that were resistance and hardness decreased. Intergranular corrosion(IGC) resistance improved significantly in the case of plasma nirtrided SS containing 4.05wt% Mo at $380^{\circ}C$ because that nitrogen and Mo ast syner gidically to form a protective layer on surface which is responsible for the aggresive SCN-ion. Plasma nitrided at $550^{\circ}C$ decreased IGC as Mo content increased. Pitting improved in the plasma nitirided SS at Mo content incresased owing to retard a nucleation and growth of chromium carbide or nitirde in grain boundary.

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Ferricyanide-Sensing Electrodes

  • Ihn, Gwon-Shik
    • Bulletin of the Korean Chemical Society
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    • 제7권1호
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    • pp.36-38
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    • 1986
  • The Ferricyanide-sensing electrodes were prepared with $Ag_2S\;and\;Ag_3Fe(CN)_6$ (mole ratio 3:1-7:1). The 5:1 $(Ag_2S:Ag_3Fe(CN)_6)$ composition is superior to others in terms of potentiometric response, rapidity of response and reproducibility. Testing was done over the concentration range $10^{-1}M{\sim}10^{-6}M\; Fe(CN)_6^{3-}$ at pH 6.8 with constant ionic strength. The concentration-potential curve was linear and coincided with the Nernstian slope (19.7 mV/decade). Interfering ions were $I^-,\;Br^-,\; SCN^-\;and\;Fe(CN)_6^{4-}$ and the life time of this electrode was 3 weeks. This electrode could be used as the indicator electrode for measuring the ferricyanide and ferrocyanide.

Cell Autonomous Circadian Systems and Their Relation to Inflammation

  • Annamneedi, Venkata Prakash;Park, Jun Woo;Lee, Geum Seon;Kang, Tae Jin
    • Biomolecules & Therapeutics
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    • 제29권1호
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    • pp.31-40
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    • 2021
  • All living beings on earth have an important mechanism of 24-h periodicity, which controls their physiology, metabolism, and behavior. In humans, 24-h periodicity is regulated by the superchiasmatic nucleus (SCN) through external and environmental cues. Peripheral organs demonstrate circadian rhythms and circadian clock functions, and these are also observed in cultured cell lines. Every cell contains a CLOCK: BMAL1 loop for the generation of circadian rhythms. In this review, we focused on cell autonomous circadian rhythms in immune cells, the inflammatory diseases caused by disruption of circadian rhythms in hormones, and the role of clock genes in inflammatory diseases.