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Hot wall Epitaxy(HWE)법에 의한 $AgInS_2$단결정 박막 성장과 열처리 효과 (The effect of thermal annealing and growth of $AgInS_2$/GaAs single crystal thin film by hot wal epitaxy)

  • Hong, Kwang-Joon
    • 한국결정성장학회지
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    • 제11권6호
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    • pp.274-284
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    • 2001
  • A stoichimetric mixture of evaporating materials for $AgInS_2$ single crystal thin films was prepared from horizontal furnace. To obtain the single crystal thin films. $AgInS_2$mixed crystal was deposited on thorughly etched semi-insulating GaAs(100) substrate by the Hot wall Epitaxy (HWE) system. The source and substrate temperatures were $680^{\circ}C$ and $410^{\circ}C$, respectively. The crystalline structure of the single thin films was investigated by the photoluminescence and double crystal X-ray diffraction(DCXD). The carrier density and mobility of $AgInS_2$ single crystal the films measured from Hall effect by van der Pauw method are $9.35\times 10^{16}/\terxtm{cm}^3$ and $294\terxtm{cm}^2$/V.s at 293 K, respectively. From the optical absorption measurement the temperature dependence of the energy band gap on AgInS$_2$ single crystal thin film was found to be $E_g$(T)= 2.1365eV-($9.89\times 10^{-3}eV/T^2$/(2930+T). After the as-grown $AgInS_2$ single crystal thin films was annealed in $Ag^-S^-$ and In-atmospheres, the origin of point defects of AgInS$_2$ single crystal the films has been investigated by using the photoluminescence(PL) at 10K. The native defects of $V_{Ag},V_s, Ag_{int}$ and $S_{int}$ int/ obtained from PL measurements were classified as a donors or acceptors type. And we concluded that the heat-treatment in the S-atmosphere converted $AgInS_2$ single crystal thin films to an optical p-type. Also, we confirmed that In in $AgInS_2$ /GaAs did not form the native defects because In is $AgInS_2$ single crystal thin films did exist in the form of stable bonds.

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회전하는 거친금속표면에서 후방산란되어 형성된 레이저 스펙클의 세기의 시간상관함수 $g_s^{(2)}({\tau})$의 측정 (Measurement of the degree of second order temporal coherence $g_s^{(2)}({\tau})$ of a laser speckle backscattered from a rotating randomly rough metal surface)

  • 안성준;이상수
    • 한국광학회지
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    • 제3권3호
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    • pp.161-166
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    • 1992
  • 회전하는 거친금속표면에 s-편극된 레이저광을 $-30^{\circ}$로 입시시켜 생긴 후방산란파중 입사광과 동일한 편극을 가지는 후방산란파에 대하여 세기의 시간상관함수 $g_{s}^{(2)}(\tau)$를 측정하였다. 이 과정에서 광전신호로부터 $g_{s}^{(2)}(0)$의 측정을 할 때 수반되는 shot noise의 영향을 제하여 줌으로써 정확한 $g_{s}^{(2)}(0)$ 값을 얻었다. 각 산란각$\theta_{s}$에서$g_{s}^{(2)}(\tau)$는 {1+exp($-\tau^2/\tau_0^2$)}함수와 거의 일치하였는데, 이는 등속으로 회전하는 간유리를 투과하여 형성된 레이저 스펙클의 경우와 같은 결과이다. 또한, 산란각에 따른 $\tau_0$의 분포에서는 $\theta_s=34^{\circ}$에서 예리하게 최대값을 가지는 것이 관찰되었다. 이 연구에서, 다중산란이 10%를 넘는 금속판산란과 다중산란이 무시될 수 있는 간유리판산란이 같은 함수꼴의 세기의 시간상관함수를 갖는다는 사실이 확인되었다.

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Why Is a b-value Range of 1500-2000 s/mm2 Optimal for Evaluating Prostatic Index Lesions on Synthetic Diffusion-Weighted Imaging?

  • So Yeon Cha;EunJu Kim;Sung Yoon Park
    • Korean Journal of Radiology
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    • 제22권6호
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    • pp.922-930
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    • 2021
  • Objective: It is uncertain why a b-value range of 1500-2000 s/mm2 is optimal. This study was aimed at qualitatively and quantitatively analyzing the optimal b-value range of synthetic diffusion-weighted imaging (sDWI) for evaluating prostatic index lesions. Materials and Methods: This retrospective study included 92 patients who underwent DWI and targeted biopsy for magnetic resonance imaging (MRI)-suggested index lesions. We generated sDWI at a b-value range of 1000-3000 s/mm2 using dedicated software and true DWI data at b-values of 0, 100, and 1000 s/mm2. We hypothesized that lesion conspicuity would be best when the background (i.e., MRI-suggested benign prostatic [bP] and periprostatic [pP] regions) signal intensity (SI) is suppressed and becomes homogeneous. To prove this hypothesis, we performed both qualitative and quantitative analyses. For qualitative analysis, two independent readers analyzed the b-value showing the best visual conspicuity of an MRI-suggested index lesion. For quantitative analysis, the readers assessed the b-value showing the same bP and pP region SI. The 95% confidence interval (CI) or interquartile range of qualitatively and quantitatively selected optimal b-values was assessed, and the mean difference between qualitatively and quantitatively selected b-values was investigated. Results: The 95% CIs of optimal b-values from qualitative and quantitative analyses were 1761-1805 s/mm2 and 1640-1771 s/mm2 (median, 1790 s/mm2 vs. 1705 s/mm2; p = 0.003) for reader 1, and 1835-1895 s/mm2 and 1705-1841 s/mm2 (median, 1872 s/mm2 vs. 1763 s/mm2; p = 0.022) for reader 2, respectively. Interquartile ranges of qualitatively and quantitatively selected optimal b-values were 1735-1873 s/mm2 and 1573-1867 s/mm2 for reader 1, and 1775-1945 s/mm2 and 1591-1955 s/mm2 for reader 2, respectively. Bland-Altman plots consistently demonstrated a mean difference of less than 100 s/mm2 between qualitatively and quantitatively selected optimal b-values. Conclusion: b-value range showing a homogeneous background signal may be optimal for evaluating prostatic index lesions on sDWI. Our qualitative and quantitative data consistently recommend b-values of 1500-2000 s/mm2.

복합재료의 기계적 성질 및 파손과정 평가 (An Experimental Evaluation of Mechanical Properties and Failure Processing in Composite Laminate)

  • 옹장우;송관형;성낙원;심봉식
    • 대한조선학회지
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    • 제25권4호
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    • pp.58-68
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    • 1988
  • $[0^{\circ}]_{8T},\;[90^{\circ}]_{8T},\;[+45^{\circ}]_{8T}$의 단축방향과 $[{\pm}15^{\circ}]_{2S},\;[{\pm}30^{\circ}]_{2S},\;[{\pm}45^{\circ}]2_{2S},\;[{\pm}60^{\circ}]_{2S},\;[{\pm}75^{\circ}]_{2S}$ Angle Ply 그리고 $0^{\circ},\;{\pm}45^{\circ},\;90^{\circ}$로 조합된 다방향 복합적층판의 기계적 성질에 대하여 스트레인 게이지를 이용하여 측정 수록하였다. 메트릭스의 특성이 잘 나타나는 $[10^{\circ}]$ Off-Axis와 $[{\pm}45^{\circ}]$ Angle Ply를 이용하여 전단탄성계수를 측정하였다. 복합재료 인장시험시 발생하는 Acoustic Emission 특성과 파괴거동을 비교 검토하고, 이것을 통하여 Acoustic Emission법의 유용성과 파손 메카니즘을 규명하고자 하였다.

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Role of a PVA layer During lithography of SnS2 thin Films Grown by Atomic layer Deposition

  • Ham, Giyul;Shin, Seokyoon;Lee, Juhyun;Lee, Namgue;Jeon, Hyeongtag
    • 반도체디스플레이기술학회지
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    • 제17권3호
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    • pp.41-45
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    • 2018
  • Two-dimensional (2D) materials have been studied extensively due to their excellent physical, chemical, and electrical properties. Among them, we report the material and device characteristics of tin disulfide ($SnS_2$). To apply $SnS_2$ as a channel layer in a transistor, $SnS_2$ channels were formed by a stripping method and a transfer method. The limitation of this method is that it is difficult to produce uniform device characteristics over a large area. Therefore, we directly deposited $SnS_2$ by atomic layer deposition (ALD) and then performed lithography. This method was able to produce devices with repeatable characteristics over a large area. However, the $SnS_2$ film was damaged by the acetone used as a photoresist (PR) developer during the lithography process, with the electrical properties of mobility of $2.6{\times}10^{-4}cm^2/Vs$, S.S. of 58.1 V/decade, and on/off current ratio of $1.8{\times}10^2$. These results are not suitable for advanced electronic devices. In this study, we analyzed the effect of acetone on $SnS_2$ and studied the device process to prevent such damage. Using polyvinyl alcohol (PVA) as a passivation layer during the lithography process, the electrical characteristics of the $SnS_2$ transistor had $2.11{\times}10^{-3}cm^2/Vs$ of mobility, 11.3 V/decade of S.S, and $2.5{\times}10^3$ of the on/off current ratio, which were 10x improvements to the $SnS_2$ transistor fabricated by the conventional method.

합성 및 원료 조건에 따른 γ-C2S의 순도 (Purity of γ-Dicalcium Silicate with Synthetic and Raw Materials Conditions)

  • 이석희;조형규
    • 한국건축시공학회지
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    • 제20권2호
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    • pp.123-128
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    • 2020
  • γ-C2S(γ-Calcium Silicate)는 벨라이트(belite)의 다형성으로 알려져 있다. γ-C2S는 CO2 고정 능력이 우수하고 제조 시 CO2 배출량이 적은 공정으로 인해 최근 많은 관심을 받고 있는 시멘트계 재료이다. 본 연구에서는 γ-C2S의 건축재료로써 활용하기 위하여 γ-C2S의 고순도 합성을 위한 다양한 합성방법을 조사하고 이를 기반으로 조건별 합성 실험 및 분석을 실시하였으며 γ-C2S의 순도에 대한 다양한 원료와 소성 온도가 미치는 영향도 평가하였다. 여러 종류의 Ca 결합물 재료가 Ca 공급원으로 사용 되었고 Si 소스 공급원으로는 Si가 주성분인 SiO2가 사용되었다. 각각의 원료는 혼합 후 다양한 조건에서 소성시켰다. 그 결과 Ca(OH)2와 SiO2 분말을 원료로 합성하였을 때 최고 높은 γ-C2S 순도를 얻을 수 있었다. 그리고 γ-C2S 제조 실용화를 위해 천연 광물인 석회암 분말과 실리카 모래를 원료로 한 분말을 사용하여 다양한 소성온도에서 합성하였으며 그 결과 합성한 샘플의 γ-C2S의 순도는 77.6%로 나타났다.

2-계층과 3-계층 C/S 시스템의 응답시간 시뮬레이션 (Response Time Simulation for 2-tier and 3-tier C/S System)

  • 김용수
    • 한국컴퓨터정보학회논문지
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    • 제9권3호
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    • pp.45-53
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    • 2004
  • 2-계층 C/S 시스템을 구성하는 경우 사용자의 응답시간이 길어지는 약점이 있다는 것이 기존의 C/S 시스템 개발자들에게는 잘 알려져 있으나 PDA등을 이용하여 모바일 환경을 제공하는 새로운 개발자들은 곧 잘 이러한 사실을 모르고 종래의 2-계층 방식으로 시스템을 구성하여 실패하는 경우가 있다. 2-계층 C/S 시스템은 개발이 용이하다는 장점을 제외하고는 응답시간, 응용프로그램의 설치. 보안, 확정성, 응용 프로그램의 재사용, 이기종 DBMS지원, 가용성 등에 많은 문제가 있다. 본 논문에서는 간단한 트랜잭션이 2-계층과 3-계층 C/S 시스템에서 작동할 때의 응답시간을 시뮬레이션 하여 분석한다. 비록 문제공간을 2-계층과 3-계층에 국한해서 시뮬레이션 했지만 도출된 결과는 다계층 시스템에서도 적용할 수 있을 것이다.

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$Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ 형광체의 합성과 발광 특성 (Synthesis and luminescence properties of $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ phosphors)

  • 성혜진;허영덕
    • 한국결정성장학회지
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    • 제16권6호
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    • pp.267-272
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    • 2006
  • 일련의 $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$ 형광체를 고상법으로 합성하였다. $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$의 구조와 발광 특성을 조사하였다. $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$은 보라색 발광 다이오드의 발광 파장인 400 nm에서 강한 흡수가 있다. $SrGa_2S_4:Ce,Na$의 발광 봉우리는 448 nm와 485 nm에 있다. $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$에서 Sr이 Ca으로 부분 치환되면 발광 파장이 장파장으로 이동된다. 다파장 백색 LED를 제작할 때 $Sr_{1-x}Ca_xGa_2S_4:Ce,Na$은 보라색 LED로 여기하여 청색 발광 형광체로 사용 될 수 있다.

Glyceorl 투여에 따른 Rat의 혈액학 및 혈액생화학치에 관한 기초연구 (A Basic Study on the Hematology and Serum Chemistry in Rat Treated with Glycerol)

  • 윤왕수;소경순;최진용;강임성;정찬길
    • 대한예방한의학회지
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    • 제10권1호
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    • pp.141-153
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    • 2006
  • In order to study the changes in hematology and serum chemistry of rats injected with glycerol, Sprague-Dawley albino rats weighing 240 to 260 gm were injected intramuscularly with a 50% solution of glycerol(8ml/kg). We measured the values of hematology and serum chemistry, and compared the measured values of S1 group(passed for 1day after injection of glycerol), S2 group(passed for 2days after injection of glycerol), S3 group(passed for 3days after injection of glycerol), S4 group(passed for 3days after injection of glycerol) and S5 group(passed for 4days after injection of glycerol) with those of Normal group(non-treated group). The results are summarized as follows : 1. In body temperature, S1, S2, S4 groups showed significantly higher compared with Normal group, especially S2 group was higher than S1 group(p<0.05). But S5 group was lower than Normal group(p<0.05). 2. In RBC, S1 group was lower than Normal group(p<0.05). And in Hct, S1, S2, S3 groups were lower than Normal group(p<0.05), in Hb, S1 and S3 groups were lower than Normal group(p<0.05). 3. In WBC, S1, S2 groups were higher than Normal group(p<0.05). and in WBC differential count, S2, S3, S5 groups were higher than N, S1, S4 groups in monocyte(p<0.05). 4. In GOT, S1 group was higher than Normal group(p<0.05), and S2, S3, S4, S5 groups were lower than S1 group(p<0.05). In GPT, S1 group was higher than Normal group(p<0.05), and S2, S3 groups were lower than S1 group(p<0.05), S4, S5 groups were lower than N, S1, S2, S3 groups(p<0.05). 5. In total cholesterol and creatinine, S4 group was higher than Normal group(p<0.05). According to the above experimental results, we could find the anemia, inflamation, damage of renal function for 4 days by intramuscularly injection with a 50% solution of glycerol(8ml/kg) in rat.

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Synthesis and Crystal Structure of Cobalt(III) Complex with Chiral Pentadentate Bis-Amide Ligand, 1,9-bis(S)-pyrrolidinyl-2,5,8-triazanonane-1,9-dione$(S,S-prodienH_2)$

  • 이배욱;오창언;도명기
    • Bulletin of the Korean Chemical Society
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    • 제19권4호
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    • pp.457-462
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    • 1998
  • A chiral pentadentate bis-amide ligand, 1,9-bis(S)-pyrrolidinyl-2,5,8-triazanonane-1,9-dio ne$(S,S-prodienH_2)$ has been synthesized from the reaction of bis(2-aminoethyl)amine(dien) and S-proline, and the structure of $[Co(S,S-prodien)H_2O]ClO_4$ has be en determined by single crystal X-ray diffraction. The geometrical structure of the Co(III) complex has been an αβ -form, where the dien moiety of ligand chelates to a facial in metal center, and the aqua ligand coordinates a cis site to the secondary nitrogen of dien. The Co-N(1), Co-N(3) distances of two amide moiety in S,S-prodien are shorter than the other Co-N(2), Co-N(4), and Co-N(5) distances because of the increased basicity of nitrogen in amide. The complex crystallizes in the monoclinic space group $P2_1$(#4), with a=7.838(1), b=12.675(1), c=9.710(1) Å, β=100.39(1) and z=2. Refinement gives the final R and $R_w$ values of 0.045 and 0.057, respectively for 2130 observed reflections. Based upon the CD and X-ray data, it is identified that the absolute configuration of the αβ -$[Co(S,S-prodien)H_2O]ClO_4$ has a Λ-form.