• Journal of the Korean institute of surface engineering
• /
• v.47 no.6
• /
• pp.297-302
• /
• 2014

ZnS nanowires were synthesized in order to investigate $NO_2$ gas sensing properties. They were grown on the sapphire substrate using ZnS powders. SEM (scanning electron microscopy) showed the diameter and length of the ZnS nanowires were approximately in the range of 50 - 100 nm and a few $10s\;{\mu}m$, respectively. They were also found to be composed of Wurtzite- structured single crystals from TEM (transmission electron microscopy) analysis. $NO_2$ gas sensing performance of the ZnS nanowire was measured with electrical resistance changes caused by $NO_2$ gas with a concentration of 1-5ppm. The sensor was UV treated with an intensity of $1.2mW/cm^2$ to facilitate charge carrier transfer. The responses of the ZnS nanowires to the $NO_2$ gas at room temperature, treated with UV of two different wavelengths of 365 nm and 254 nm, are measured to be 124.53 - 206.87 % and 233.97 - 554.83%, respectively. In the current work, the effect of UV treatment on the gas sensing performance of the ZnS nanowires was studied. And the underlying mechanism for the electrical resistance changes of the ZnS nanowires by $NO_2$ gas was also discussed.

• Communications of the Korean Mathematical Society
• /
• v.39 no.2
• /
• pp.331-343
• /
• 2024

Let ℜ be a *-algebra with unity I and a nontrivial projection P₁. In this paper, we show that under certain restrictions if a map ψ : ℜ → ℜ satisfies $$\Psi(S_1{\diamond}S_2{\cdot}{\cdot}{\cdot}{\diamond}S_{n-1}{\bullet}S_n)=\sum_{k=1}^nS_1{\diamond}S_2{\diamond}{\cdot}{\cdot}{\cdot}{\diamond}S_{k-1}{\diamond}{\Psi}(S_k){\diamond}S_{k+1}{\diamond}{\cdot}{\cdot}{\cdot}{\diamond}S_{n-1}{\bullet}S_n$$ for all S_n-2, S_n-1, S_n ∈ ℜ and S_i = I for all i ∈ {1, 2, . . . , n - 3}, where n ≥ 3, then ψ is an additive *-derivation.

• Korean Journal of Crystallography
• /
• v.18 no.1_2
• /
• pp.1-6
• /
• 2007

An Organometallic compound, $C_{16}H_{35}B_{10}IrS_2Si$, was synthesized from o-carborane, $Cp^*Ir(S_2C_2B{10}H_{10})$, and $Me_3SiCHN_2$. The molecular structure of this complex has been determined by X-ray diffraction. Crystallographic data : monoclinic, space group $P2_1/n$, $a=10.1986(12)\;{\AA}$, $b=14.834(5)\;{\AA}$, $c=17.139\;{\AA}$, ${\beta}=92.24(2)^{\circ}$, Z=4, $V=2591.0(14)\;{\AA}^3$. The structure was solved by direct methods and refined by full-matrix leat-squares methods to give a model with a reliability factor R=0.053 for 5080 reflections.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2014.02a
• /
• pp.377-377
• /
• 2014

We demonstrate the high temperature-dependent electrical behavior at 2D multilayer MoS2 transistor. Our previous reports explain that the extracted field-effect mobility of good device was inversely proportional to the increase of temperature. Because scattering mechanism is dominated by phonon scattering at a well-designed MoS2 transistor, having, low Schottky barrier. However, mobility at an immature our $MoS_2$ transistor (${\mu}m$ < $10cm^2V^{-1}s^{-1}$) is proportional to the increase temperature. The existence of a big Schottky barrier at $MoS_2-Ti$ junction can reduce carrier transport and lead to lower transistor conductance. At high temperature (380K), the field-effect mobility of multilayer $MoS_2$ transistor increases from 8.93 to $16.9cm^2V^{-1}sec^{-1}$, which is 2 times higher than the value at room temperature. These results demonstrate that carrier transport at an immature $MoS_2$ with a high Schottky barrier is mainly affected by thermionic emission over the energy barrier at high temperature.

• Korean Journal of Food Science and Technology
• /
• v.45 no.2
• /
• pp.213-220
• /
• 2013

Two types of onions cultivated with different methods of sulfur application (designated as S-1 and S-2) were examined for their physicochemical and sensory properties, and then compared with onions without sulfur application as a control. During cultivation, dietary sulfur methylsulfonylmethane (MSM) was sprayed on the leaves twice starting at 2 months before harvest, with one month intervals for S-1. For S-2, the MSM was applied once onto surface soils before sowing, and then once again on the leaves at 2 months before harvest. Thiosulfinate, a major sulfur-containing compound in onions, increased in the order of control, S-1, and S-2, without noticeable differences in the strength of spicy hot taste and flavor. The S-2 onions demonstrated a total reducing capacity three times higher than control and S-1 did. It indicates that the application of sulfur would positively affect the quality of onions under the condition where sufficient time is given for soil mineralization.

• Applied Chemistry for Engineering
• /
• v.25 no.2
• /
• pp.161-166
• /
• 2014

In this study, effects of pyrite ($FeS_2$) particle sizes on the electrochemical characteristics of thermal batteries are investigated using unit cells made of pulverized pyrite by ball-milling. At $450^{\circ}C$ unit cell discharge test, the electrochemical capacity of $1.46{\mu}m$ pyrite-cell largely increases compared to $98.4{\mu}m$ pyrite-cell, and their internal resistances also decrease. These results are attributed to the increase in the active reaction area of pyrite by ball milling. However, at $500^{\circ}C$ unit cell discharge test, a $1.46{\mu}m$ pyrite cell shows lower internal resistance than that of $98.4{\mu}m$ pyrite cell only at Z-phase region ($FeS_2{\rightarrow}Li_3Fe_2S_4$). After that, a $1.46{\mu}m$ pyrite cell shows a decrease in the cell voltage and an rapid increase of the internal resistance in J-phase region ($Li_3Fe_2S_4{\rightarrow}LiFe_2S_4$) is observed compared to those of $98.4{\mu}m$ pyrite cell. It can be concluded that at the higher temperature, the thermally unstable pulverized pyrite is decomposed thermally as well as self discharged, simultaneously, which causes the higher resistance and lower capacity at $500^{\circ}C$ in J-phase than that of $98.4{\mu}m$ pyrite cell.

• Bulletin of the Korean Chemical Society
• /
• v.20 no.6
• /
• pp.648-652
• /
• 1999

Studies have been carried out on the unusual molecular nonrigidity of CoⅢ(PymS)3 and Cp* RhⅢ(PymS)2(PymS:2-mercaptopyrimidine). The crystal structure of CoⅢ(PymS)3 approximates to an octahedral mer isomer with 4-membered N-Schelating fashion. For Cp*RhⅢ(PymS)2, one PymS ligand bonds to the rhodium ion in an S-monodentate mode (Rh-S(2) = 2.366(1)Å) while the other ligand chelates to the metal ion in an N,S-bidentae mode (Rh-S(1)=2.414(1);Rh-N(1)=2.103(3)Å). Even though the conformations and configurations of both complexes are still retained in solution, an unusual nonrigidity for the protons of the PymS region is obsered in the solution. The broad proton signals of CoⅢ(PymS)3 exhibit a temperature-dependence in the range of -40∼40℃ with a free energy of activation ΔG=64.49kJ/mol(40℃). For Cp*RhⅢ(PymS)₂,such a fluxionality has been markedly observed in solution. This fluxional behavior can be explained in terms of "ligand tautomerism" in metal complexes containing potential tautomeric forms.

• YAKHAK HOEJI
• /
• v.38 no.6
• /
• pp.749-755
• /
• 1994

An interspecific fusant strain, Streptomyces MS1 was obtained by protoplast fusion between S. peucetius subsp. caesius and S. platensis. We studied on the fermentation characteristics of the fusant strain. The fermentation products of the fusant MS1 was identical with S. peucetius, but its production of anthracycline was more stable than S. peucetius under various fermentation conditions in regard to acidogenesis of fermentation broth. The optimal medium composition for anthracycline production by fusant MS1 as follows: sucrose 2.0%, glucose 1.0%, soytone 0.7%, $CaCO_3$ 0.2%, $KH_2PO_4$ 0.013%, casamino acids 0.01%, $K_2SO_4$ 0.025%, $MaCl_2\;6H_2O$ 1.024%, 5M $CaCl_2\;5H_2O$ 0.4%, 1N NaOH 0.7%, 20% L-proline 1.5%. In this condition, the productivity of anthracycline was $80{\sim}100\;{\mu}g/ml$.

• Communications of the Korean Mathematical Society
• /
• v.23 no.1
• /
• pp.11-18
• /
• 2008

For a nef and big divisor D on a smooth projective surface S, the inequality $h^{0}$(S;$O_{s}(D)$) ${\leq}\;D^2\;+\;2$ is well known. For a nef and big canonical divisor KS, there is a better inequality $h^{0}$(S;$O_{s}(K_s)$) ${\leq}\;\frac{1}{2}{K_{s}}^{2}\;+\;2$ which is called the Noether inequality. We investigate an inequality $h^{0}$(S;$O_{s}(D)$) ${\leq}\;\frac{1}{2}D^{2}\;+\;2$ like Clifford theorem in the case of a curve. We show that this inequality holds except some cases. We show the existence of a counter example for this inequality. We prove also the base-locus freeness of the linear system in the exceptional cases.

• Journal of Plant Biology
• /
• v.19 no.4
• /
• pp.95-99
• /
• 1976

This work deals with different extraction media and reaction mixtures on photosystem II activity of Spinach chloroplasts. The photoreduction rate of ferricyanide and DPIP by intact chloroplasts which extracted with four kinds of extraction media; S-Tris-N pH 7.2, 8.0, S-Tricine-N pH 7.2, 8.0, was measured in five kinds of reaction mixtures; S-Tris-N pH 7.2, 8.0, S-Tricine-N pH 7.2, 8.0, 0.05 M-Tris pH 7.2. The extraction medium which shows the highest photoreduction rate was S-Tris-N at pH 7.2 and S-Tricine-N at pH 8.0. As to the reaciton mixture, S-Tricine-N pH 8.0 showed the highest rate. On the complex effects of extraction media and reaction mixtures, the highest photordeuction rate of Hill oxidant by intact chloroplasts was obtained by S-Tris-N pH 7.2 extraction medium and S-Tricine-N pH 8.0 reaction mixture. The second highest activity was obtained by S-Tricine-N pH 8.0 extraction medium and reaction mixture.