• Analytical Science and Technology
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• v.23 no.1
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• pp.97-101
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• 2010

(R)-N-3,5-dinitrobenzoyl (DNB) phenylglycinol derived chiral selector was used as a HPLC chiral stationary phase (CSP) for the resolution of racemic N-acylnaphthylalkylamines. In this study, determination of optical purity was performed by both chiral chromatography and NMR spectroscopy by using the (R)-phenylglycinol derived chiral selector. The data of accuracy and precision of each optical purity value are calculated from the results of NMR and HPLC experiments by comparing with true value. Average error of the NMR method was +2.2% with average RSD of 4.54%, while that of HPLC method was -3.5% with average RSD of 3.23%.

• Analytical Science and Technology
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• v.6 no.2
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• pp.207-215
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• 1993

$Si_3N_4$ powders were mixed with sintering additives($3Y_2O_3{\cdot}5Al_2O_3$, YAG) by coprecipitation method. Mixing homogeneity, sintered and mechanical properties of coprecipitation-mixed powder compacts were compared with those of mechanically-mixed ones. SIMS-analysis for composition on the surface and in the matrix of prepared powder mixtures showed that the added YAG exists mainly on the $Si_3N_4$ powder surfaces in a form of coating. From this result it could be concluded that coprecipitation method is superior to mechanical mixing in the mixing homogeneity. This mixing homogeneity can accompany an improvement in sintered density, microstructure and consequently the mechanical properties of sintered bodys.

• Journal of Internet Computing and Services
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• v.9 no.1
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• pp.129-135
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• 2008

This paper presents a methodology to forecast KOSPI index by extracting fuzzy rules based on the neural network with weighted fuzzy membership functions (NEWFM) and the minimized number of input features using the distributed non-overlap area measurement method. NEWFM classifies upward and downward cases of KOSPI using the recent 32 days of CPPn,m (Current Price Position of day n for n-1 to n-m days) of KOSPI. The five most important input features among CPPn,m and 38 wavelet transformed coefficients produced by the recent 32 days of CPPn,m are selected by the non-overlap area distribution measurement method. For the data sets, from 1991 to 1998, the proposed method shows that the average of forecast rate is 67.62%.

• Communications of Mathematical Education
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• v.20 no.3 s.27
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• pp.361-372
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• 2006

This study was extended as one of the properties of isosceles triangles to polygons(n-angles) by conjectures-proofs-reputations-reformations and developed teaching-learning materials which can be used in high-level classes for middle and high school students.

• Journal of the Korean Chemical Society
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• v.17 no.5
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• pp.371-377
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• 1973

The low temperature anionic copolymerization of p-tolylisocyanate ($M_1$) with n-hexylisocyanate ($M_2$) in DMF was carried out with NaCN. Copolymers were characterized by osmometry and I. R. spectrophotometry. Also copolymer composition was analyzed by spectral measurements. The behavior of this copolymerization system was the type of less ideal, that is the $M_2$ prefers to react exclusively with the same kind of species. The stress-strain behavior of the copolymer obtained from equimolar comonomer feed exhibited somewhat brittle or rigid character.

• Proceedings of the International Microelectronics And Packaging Society Conference
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• 2002.05a
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• pp.165-168
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• 2002

본 연구에서는 칩인덕터 코어 소재로 사용되는 (NiCuZn)-ferrite를 습식합성법을 이용하여 나노크기의 초미세 분말을 합성하였으며, 합성된 (ZiCuZn)-ferrite 의 제조공정 및 전파기적 특성에 관하여 고찰하였다. 조성은 (N $i_{0.4-x}$C $u_{x}$Z $n_{0.6}$)$_{1+w}$ (F $e_2$ $O_4$)$_{1-w}$에서 x의 값을 0.05~0.25 범위로 변화시켰으며, w 값은 0.03으로 고정하였다. 소결은 8$50^{\circ}C$에서 9$50^{\circ}C$의 범위에서 진행하였다. 나노크기의(NiCuZn)-ferrite를 사용함으로서 시약급 원료로 제조된 것보다 소결온도를 낮출 수 있었고, 밀도가 높은 페라이트 소결체를 얻을 수 있었다. 또한 초투자율, 품질계수 등 전자기적 특성이 우수하게 나타났다. 그 밖에 습식합성법으로 합성한 (NiCuZn)-ferrite 의 결정성, 미세구조 등을 XRD, SEM 을 이용하여 고찰하였다.하였다.다.

• Journal of the Korean Chemical Society
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• v.35 no.2
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• pp.142-150
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• 1991

The complexation of hydrazide schiff base ligands such as N,N'-oxalylbis(salicylaldehyde hydrazone), N,N'-malonylbis(salicylaldehyde hydrazone), and N,N'-succinylbis(salicylaldehyde hydrazone) with Cd(II) ion was studied by polarographic method in DMSO solution. The order of stability constants was OBSH < MBSH < SBSH, and these ligands formed stable complexes with Cd(II) ion. The stability constants of complexation were measured at various temperatures. As the results, ${\Delta}$H and ${\Delta}$S of the complexation were distributed on the complex stabilities.

• Applied Chemistry for Engineering
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• v.5 no.4
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• pp.706-713
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• 1994

Isothermal vapor-Liquid equilibrium data have been measured for binary systems MTBE-methanol, MTBE-n-heptane, and methanol-n-heptane at $45^{\circ}C$ and $65^{\circ}C$ by using head space gas chromato-graphy (H.S.G.C). Among these systems a minimum azeotrope was observed in both of MTBE-methanol system and n-heptane-methanol system. Particularly n-heptane-methanol system has a heterogeneous minimum azotrope since it has an immisible region. These equilibrium data were correlated with the excess Gibbs energy model, and the thermodynamic consistency test was also carried out by using Redlich-Kister equation.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.438-439
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• 2013

Microelectronic devices의 접촉저항의 향상을 위해 Metal silicides의 형성 mechanism과 전기적 특성에 대한 연구가 많이 이루어지고 있다. 지난 수십년에 걸쳐, Ti silicide, Co silicide, Ni silicide 등에 대한 개발이 이루어져 왔으나, 계속적인 저저항 접촉 소재에 대한 요구에 의해 최근에는 Rare earth silicide에 관한 연구가 시작되고 있다. Rare-earth silicide는 저온에서 silicides를 형성하고, n-type Si과 낮은 schottky barrier contact (~0.3 eV)를 이룬다. 또한, 비교적 낮은 resistivity와 hexagonal AlB2 crystal structure에 의해 Si과 좋은 lattice match를 가져 Si wafer에서 high quality silicide thin film을 성장시킬 수 있다. Rare earth silicides 중에서 ytterbium silicide는 가장 낮은 electric work function을 갖고 있어 낮은 schottky barrier 응용에서 쓰이고 있다. 이로 인해, n-channel schottky barrier MOSFETs의 source/drain으로써 주목받고 있다. 특히 ytterbium과 molybdenum co-deposition을 하여 증착할 경우 thin film 형성에 있어 안정적인 morphology를 나타낸다. 또한, ytterbium silicide와 마찬가지로 낮은 면저항과 electric work function을 갖는다. 그러나 ytterbium silicide에 molybdenum을 화합물로써 높은 농도로 포함할 경우 높은 schottky barrier를 형성하고 epitaxial growth를 방해하여 silicide film의 quality 저하를 야기할 수 있다. 본 연구에서는 ytterbium과 molybdenum의 co-deposition에 따른 silicide 형성과 전기적 특성 변화에 대한 자세한 분석을 TEM, 4-probe point 등의 다양한 분석 도구를 이용하여 진행하였다. Ytterbium과 molybdenum을 co-deposition하기 위하여 기판으로 $1{\sim}0{\Omega}{\cdot}cm$의 비저항을 갖는 low doped n-type Si (100) bulk wafer를 사용하였다. Native oxide layer를 제거하기 위해 1%의 hydrofluoric (HF) acid solution에 wafer를 세정하였다. 그리고 고진공에서 RF sputtering 법을 이용하여 Ytterbium과 molybdenum을 동시에 증착하였다. RE metal의 경우 oxygen과 높은 반응성을 가지므로 oxidation을 막기 위해 그 위에 capping layer로 100 nm 두께의 TiN을 증착하였다. 증착 후, 진공 분위기에서 rapid thermal anneal(RTA)을 이용하여 $300{\sim}700^{\circ}C$에서 각각 1분간 열처리하여 ytterbium silicides를 형성하였다. 전기적 특성 평가를 위한 sheet resistance 측정은 4-point probe를 사용하였고, Mo doped ytterbium silicide와 Si interface의 atomic scale의 미세 구조를 통한 Mo doped ytterbium silicide의 형성 mechanism 분석을 위하여 trasmission electron microscopy (JEM-2100F)를 이용하였다.

• Journal of Sericultural and Entomological Science
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• v.26 no.2
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• pp.1-6
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• 1984

The present study was made to establish the purification method of mature microsporidian spores by iso-density equilibrium technique using percoll and the serological discrimination by an indirect fluorescent antibody technique. The purification of new microsporidian spores took effect in the three steps purification method(precentrifugation-percoll iso-density equilibrium centrifugation-rising). There were clear differences in the size of spores between the new microsporidia and N. bombycis. The spores of N. bombycis is short elliptical of 2.07 in a ratio of length to width in diameter while that of new microsporidia is characterized with long elliptical shape which shows a ratio of 2.76 in length to width in diameter. The specific antigens of new microsporidia K79 spores was showed in the spores wall by the indirect fluorescent antibody reaction, and it was affected by the antibody against N. bombycis which antiserum was diluted in 1:20. It means that the new microsporidia K79 is serologically not identical to N. bombycis.