• Title/Summary/Keyword: S/Z ratio

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Electrical Properties and Temperature Stability of resonant Frequency with Zr/Ti ratio in PSN-PMN-PZT Ceramics (PSN-PMN-PZT 세라믹스의 Zr/Ti 비에 따른 전기적 특성과 공진주파수의 온도안정성)

  • 류주현;윤광희;민석규;이명수;서성재
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.8
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    • pp.675-680
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    • 2000
  • In this study the temperature coefficient of resonant frequency(TC $F_{r}$) dielectric and piezoelectric properties of Pb[(S $b_{1}$2//N $b_{1}$2/)$_{0.065}$)-(Z $r_{x}$, $Ti_{1-x}$ )$_{0.90}$] $O_3$ceramics were investigated with Zr/Ti ratio. The compositions near the morphotropic phase boundary (MPB) appeared when Zr/Ti ratio was 49.5/50.5 The dielectric constant and electromechanical coupling factor( $k_{p}$) also showed the highest values of 1,257, 0.653 respectively when the Zr/Ti ratio was 49.5/50.5 Moreover the mechanical quality factor( $Q_{m}$) showed th lowest value of 713 when the Zr/Ti ratio. The temperature coefficient of resonant frequency(TC $F_{r}$) abruptly change at the morphotropic phase boundary(MPB) which existed between the rhombohedral phase with highly negative TC $F_{r}$ of -106ppm/$^{\circ}C$ and the tetragonal phase with highly positive TC $F_{r}$ of +64pp $m^{\circ}C$ as Zr/Ti ratio varied from 50/50 to 49.5/50.5.50.5..50.5.

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Determination of Isotopic Ratios for Ca in Inductively Coupled Plasma Mass Spectrometry (ICPMS) by Removing Water Related Molecules

  • 박용남;S. R. Koirtyohann
    • Bulletin of the Korean Chemical Society
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    • v.18 no.11
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    • pp.1172-1175
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    • 1997
  • Calcium isotopic ratios are precisely measured by removing isobaric interferences originated from water in the plasma. Liquid Ar cryogenic trap combined with membrane desolvator could eliminate backgrounds at m/z 42 and 44. Slow drift of ICP-MS is corrected by the frequent running of the standards. It is found necessary to separate Ca from the sample matrix using Ca oxalate precipitation technique. Currently, the RSD is 0.5-1.0% for 2 minutes of measurement but is expected to be improved if the measurement time is increased. The technique was applied to 42Ca enriched baby fecal samples and successfully determined 42Ca/44Ca ratio changes.

Dielectric, Piezoelectric Properties and Temperature Stability of Resonant Frequency in PSN-PMN-PZT Ceramics (PSN-PMN-PZT 세라믹스의 유전 및 압전 특성과 공진 주파수의 온도안정성)

  • 윤광희;류주현;민석규;이명수;서성재
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.391-395
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    • 2000
  • In this study, the temperature coefficient of resonant frequency(TC $F_{r}$), dielectric and piezoelectric properties of Pb[(S $b_{1}$2/N $b_{1}$2/)$_{0.0035}$-(M $n_{1}$3/N $b_{2}$3/)$_{0.0065}$-(Z $r_{x}$ $Ti_{1-x}$ )$_{0.90}$] $O_3$ceramics is investigated with Zr/Ti ratio. The dielectric constant and electromechanical coupling factor( $k_{p}$) showed the highest values of 1257, 0.562 respectively when the Zr/Ti ratio is 49.5/50.5. The mechanical quality factor( $Q_{m}$) is the lowest value of 713 when the Zr/Ti ratio is 49.5/50.5, and increased with the decrease of the Zr/Ti ratio. The temperature coefficient of resonant frequency(TC $F_{r}$) change abruptly at the morphotropic phase boundary(MPB), which is between the rhombohedral phase with highly negative TC $F_{r}$ of -106ppm/$^{\circ}C$ and the tetragonal phase with highly positive TC $F_{r}$ of +64pp $m^{\circ}C$ as Zr/Ti ratio changes from 50/50 to 49.5/50.5.50.5..5.50.5.5.

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Parametric modeling and shape optimization design of five extended cylindrical reticulated shells

  • Wu, J.;Lu, X.Y.;Li, S.C.;Xu, Z.H.;Wang, Z.D.;Li, L.P.;Xue, Y.G.
    • Steel and Composite Structures
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    • v.21 no.1
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    • pp.217-247
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    • 2016
  • Five extended cylindrical reticulated shells are proposed by changing distribution rule of diagonal rods based on three fundamental types. Modeling programs for fundamental types and extended types of cylindrical reticulated shell are compiled by using the ANSYS Parametric Design Language (APDL). On this basis, conditional formulas are derived when the grid shape of cylindrical reticulated shells is equilateral triangle. Internal force analysis of cylindrical reticulated shells is carried out. The variation and distribution regularities of maximum displacement and stress are studied. A shape optimization program is proposed by adopting the sequence two-stage algorithm (RDQA) in FORTRAN environment based on the characteristics of cylindrical reticulated shells and the ideas of discrete variable optimization design. Shape optimization is achieved by considering the objective function of the minimum total steel consumption, global and locality constraints. The shape optimization for three fundamental types and five extended types is calculated with the span of 30 m~80 m and rise-span ratio of 1/7~1/3. The variations of the total steel consumption along with the span and rise-span ratio are analyzed with contrast to the results of shape optimization. The optimal combination of main design parameters for five extended cylindrical reticulated shells is investigated. The total steel consumption affected by distribution rule of diagonal rods is discussed. The results show that: (1) Parametric modeling method is simple, efficient and practical, which can quickly generate different types of cylindrical reticulated shells. (2) The mechanical properties of five extended cylindrical reticulated shells are better than their fundamental types. (3) The total steel consumption of cylindrical reticulated shells is optimized to be the least when rise-span ratio is 1/6. (4) The extended type of three-way grid cylindrical reticulated shell should be preferentially adopted in practical engineering. (5) The grid shape of reticulated shells should be designed to equilateral triangle as much as possible because of its reasonable stress and the lowest total steel consumption.

Wind direction field under the influence of topography: part II: CFD investigations

  • Li, S.W.;Hu, Z.Z.;Tse, K.T.;Weerasuriya, A.U.
    • Wind and Structures
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    • v.22 no.4
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    • pp.477-501
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    • 2016
  • Though hilly topography influences both wind speeds and directions aloft, only the influence on wind speeds, i.e. the speed-up effect, has been thoroughly investigated. Due to the importance of a model showing the spatial variations of wind directions above hilly terrains, it is worthwhile to systematically assess the applicability and limitations of the model describing the influence of hilly topographies on wind directions. Based on wind-tunnel test results, a model, which describes the horizontal and vertical variations of the wind directions separately, has been proposed in a companion paper. CFD (Computational Fluid Dynamics) techniques were employed in the present paper to evaluate the applicability of the proposed model. From the investigation, it has been found that the model is acceptable for describing the vertical variation of wind directions by a shallow hill whose primary-to-secondary axis ratio (aspect ratio) is larger than 1. When the overall hill slope exceeds $20^{\circ}$, the proposed model should be used with caution. When the aspect ratio is less than 1, the proposed model is less accurate in predicting the spatial variation of wind directions in the wake zone in a separated flow. In addition, it has been found that local slope of a hill has significant impact on the applicability of the proposed model. Specifically, the proposed model is only applicable when local slope of a hill varies gradually from 0 (at the hill foot) to the maximum value (at the mid-slope point) and then to 0 (at the hill top).

The effect of composition ratio on the surface morphology and superconducting properties of SmBCO films prepared by thermal co-evaporation method (동시 열증발법으로 제조한 SmBCO 고온 초전도에서 박막 조성비가 표면형상 및 초전도 특성에 미치는 영향)

  • Lee, N.J.;Kim, H.S.;Ha, H.S.;Ko, R.K.;Song, K.J.;Ha, D.W.;Yang, J.S.;Kim, T.H.;Jeong, Y.H.;Youm, D.J.;Moon, S.H.;Park, C.;Oh, S.S.
    • Progress in Superconductivity and Cryogenics
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    • v.9 no.1
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    • pp.5-8
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    • 2007
  • We have investigated the superconducting properties and surface morphology of $Sm_xBa_yCu_3O_{6+z}$ thin films deposited on LMO/IBAD-MgO/Hastelloy which prepared with different composition ratio by co-evaporation method(EDDC, Evaporation using Drum in Dual Chambers). We observed the composition ratio of SmBCO thin films by EDS analysis. We fabricated SmBCO thin film with critical current density of $1.5{\times}10^6A/cm^2$ at composition ratio of SM:Ba:Cu=1.10:2.01:3(at 77 K self-field). And, we confirmed that substitution of Sm-Ba did not occur at Cu rich phase by EDS analysis.

Microstructure and Electrical Properties of Pb[(Mg,Mn)Nb]O3-Pb(Zr,Ti)O3 Piezoelectric Ceramics

  • Kim, Jin-Ho;Kim, Jong-Hwa;Baik, Seung-Woo
    • Transactions on Electrical and Electronic Materials
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    • v.6 no.5
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    • pp.202-209
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    • 2005
  • Phase evolution, microstructure and the electrical properties such as $k_p$ and $Q_m$ of $Pb(Mg_{1/3}Nb_{2/3})O_3[PMN]-Pb(Mn_{1/3}Nb_{2/3})O3[PM'N]-PbZrO_3[PZ]-PbTiO_3[PT]$ quaternary system were investigated within the compositional ranges $0{\leq}y{\leq}0.125$, y+z=0.125, and $0.39{\leq}x{\leq}0.54$ of the formula $Pb_{0.97}Sr_{0.03}[Mg_{1/3}Nb_{2/3})_y\;(Mn_{1/3}Nb_{2/3})_z\;(Zr_{x}Ti_{1-x})_{1-(y+z)}]O_3$. In the case of increasing Mn/(Mg+Mn) ratio for a fixed Zr/Ti ratio of 47.5/52.5, phase relation remained unchanged but the grain size drastically decreased, and the electrical properties changed as following: both $k_P$ and $Q_m$ reached the peak values at $Mn/(Mg+Mn)\cong0.3l7$ and gradually decreased; $\varepsilon33^T$ showed a monotonic decrease; P-E hysteresis loop gradually changed to asymmetrical one, and $E_i$ increased in correspondence. With increasing Zr/Ti ratio for a fixed Mn/(Mg+Mn) ratio of 0.317, on the contrary, the cell parameter $(\alpha^2c)^{1/3}$ gradually increased, and tetragonal-rhombohedral morphotropic phase boundary appeared in the range of $51/49{\leq}Zr/Ti{\leq}54/46$. the meantime, the grain size substantially increased, and the electrical properties changed as following: $k_P$ and $\varepsilon33^T$ reached peak values at Zr/Ti=51/49 and 48/52, respectively, and then gradually decreased; change of $Q_m$ was adverse to $k_P$; both $E_C\;and\;E_i$ considerably decreased while $P_S$ moderately increased. For the system 0.125(PMN+PM'N)-0.875PZT studied, the composition Mn/(Mg+Mn)=0.3l7 and Zr/Ti=51/49 revealed some promising electrical properties for piezoelectric transformer application such as $k_P=0.58,\;Q_m\cong1000$, and $\varepsilon^T_{33}=970$, as well as dense and fine-grained microstructure.

Compression Properties of Weft Knitted Fabrics Consisting of Shrinkable and Non-Shrinkable Acrylic Fibers

  • Bakhtiari M.;Najar S. Shaikhzadeh;Etrati S. M.;Toosi Z. Khorram
    • Fibers and Polymers
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    • v.7 no.3
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    • pp.295-304
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    • 2006
  • High-bulk worsted yams with different shrinkable and non-shrinkable acrylic fibers blend ratios are produced and then single jersey weft knitted fabrics with three different structures and loop lengths are constructed. The physical properties of produced yams and compression properties of produced fabrics at eight pressure values (50, 100, 200, 500, 1000, 1500 and $2000 g/cm^2$) were measured using a conventional fabric thickness tester. Then, weft-knitted fabric compression behavior was analyzed using a two parameters model. It is found that at 40 % shrinkable fibre blending ratio the maximum yam bulk, shrinkage, abrasion resistance and minimum yarn strength are obtained. It is also shown that high-bulk acrylic yarn has the highest elongation at 20 % shrinkable fibre blend ratio. The statistical regression analysis revealed that the compression behavior of acrylic weft-knitted fabrics is highly closed to two parameter model proposed for woven fabrics. It is also shown that for weft-knitted structure, there is an incompressible layer (V') which resists against high compression load. Acrylic weft-knitted fabrics with knit-tuck structure exhibit higher compression rigidity and lower softness than the plain and knit-miss structures. In addition, at 20 % shrinkable fibre blend ratio, the high-bulk acrylic weft-knitted fabrics are highly compressible.

A Study on the Influence of Substituting Cu Eine Particle for CuO on NiCuZn Ferrite (CuO 대신 Cu 미분말 치환이 NiCuZn Ferrite에 미치는 영향에 관한 연구)

  • Kim, Jae-Sik;Koh, Jae-Gui
    • Journal of the Korean Magnetics Society
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    • v.13 no.1
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    • pp.15-20
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    • 2003
  • Diffusion speed of Cu metal fine particle is fast better than CuO, so it will promote grain growth in sintering. In this paper, the influence on substituting Cu fine particle for CuO of NiCuZn ferrite with basic composition (N $i_{0.204}$C $u_{0.204}$Z $n_{0.612}$ $O_{1.02}$)F $e_{1.98}$ $O_{2.98}$ has been investigated with varying Cu/CuO ratio. The perfect spinel structure of sintered specimen at 90$0^{\circ}C$ was confirmed by the analysis of XRD patterns. The best condition was obtained when the ratio of Cu/CuO was 60%, and the permeability was 1100 and Ms was 87 emu/g in this condition. Cu has influenced on grain growth in sintering, substituting Cu fine particle for CuO could lower sintering temperature over the 3$0^{\circ}C$. After sintering, substituting Cu performed as good as CuO.s CuO.s CuO.

Carbon and Nitrogen Responses of Litterfall Components by NPK and PK Fertilizers in a Red Pine (Pinus densiflora S. et Z.) Stand

  • Park, Seong-Wan;Baek, Gyeongwon;Kim, Seongjun;Yang, A-Ram;Kim, Choonsig
    • Journal of Korean Society of Forest Science
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    • v.108 no.1
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    • pp.21-28
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    • 2019
  • This study was conducted to determine the carbon (C) and nitrogen (N) response of litterfall components as affected by N addition in compound fertilizer in a Korean red pine (Pinus densiflora S. et Z.) stand in southern Korea. Litterfall in a mature red pine stand was collected for two years following compound fertilizer application ($N_3P_4K_1$; $P_4K_1$) and no fertilization (control). The C concentration of litterfall components was not significantly (P > 0.05) different between the $N_3P_4K_1$ and the control plots, whereas the N concentration of the litterfall components was significantly higher in the $N_3P_4K_1$ plot than in the control plot. The $N_3P_4K_1$ and $P_4K_1$ additions induced a lower C/N ratio of litterfall components compared with the control plot. Annual C and N fluxes via litterfall components were not affected by the $N_3P_4K_1$ addition over the study period, except for reproduction litter. Annual N fluxes via reproduction litter were significantly higher in the $N_3P_4K_1$ plot than in the control plot. Thus, the $N_3P_4K_1$ and $P_4K_1$ additions could modify differently nutrient distribution of the forest floor and mineral soils in a red pine stand. These results indicate that N concentration and C/N ratio in litterfall components are more susceptible to fertilizer application than the C response in litterfall components.