• Title/Summary/Keyword: Rust

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Modeling cover cracking due to rebar corrosion in RC members

  • Allampallewar, Satish B.;Srividya, A.
    • Structural Engineering and Mechanics
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    • v.30 no.6
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    • pp.713-732
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    • 2008
  • Serviceability and durability of the concrete members can be seriously affected by the corrosion of steel rebar. Carbonation front and or chloride ingress can destroy the passive film on rebar and may set the corrosion (oxidation process). Depending on the level of oxidation (expansive corrosion products/rust) damage to the cover concrete takes place in the form of expansion, cracking and spalling or delamination. This makes the concrete unable to develop forces through bond and also become unprotected against further degradation from corrosion; and thus marks the end of service life for corrosion-affected structures. This paper presents an analytical model that predicts the weight loss of steel rebar and the corresponding time from onset of corrosion for the known corrosion rate and thus can be used for the determination of time to cover cracking in corrosion affected RC member. This model uses fully the thick-walled cylinder approach. The gradual crack propagation in radial directions (from inside) is considered when the circumferential tensile stresses at the inner surface of intact concrete have reached the tensile strength of concrete. The analysis is done separately with and without considering the stiffness of reinforcing steel and rust combine along with the assumption of zero residual strength of cracked concrete. The model accounts for the time required for corrosion products to fill a porous zone before they start inducing expansive pressure on the concrete surrounding the steel rebar. The capability of the model to produce the experimental trends is demonstrated by comparing the model's predictions with the results of experimental data published in the literature. The effect of considering the corroded reinforcing steel bar stiffness is demonstrated. A sensitivity analysis has also been carried out to show the influence of the various parameters. It has been found that material properties and their inter-relations significantly influence weight loss of rebar. Time to cover cracking from onset of corrosion for the same weight loss is influenced by corrosion rate and state of oxidation of corrosion product formed. Time to cover cracking from onset of corrosion is useful in making certain decisions pertaining to inspection, repair, rehabilitation, replacement and demolition of RC member/structure in corrosive environment.

Studies on the Eradication of Pedicularis spp., Alternate Host of White Pine Blister Rust with Several Herbicides (제초제처리(除草劑処理)에 의(依)한 잣나무털녹병(病) 중간기주(中間奇主)(송이풀류(類)) 제거시험(除去試験))

  • Yi, Chang Keun;Kim, Hyun Joong;Yeo, Woon Hong
    • Journal of Korean Society of Forest Science
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    • v.51 no.1
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    • pp.51-55
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    • 1981
  • The study was conducted during 1975-1980 to evaluate the performance of several herbicides in controling alternate host, Pedicularis spp., of white pine blister rust disease in forest stands. The results obtained were summarized as follows. 1. It was found that Roundup was effective and most suitable herbicide in the fosest stands except that it accompanied some chemical injuries to neighboring plants. 2. As for the reduction density on the plot treated with Roundup was 100% and 65-91% respectively when investigated one and two years after its treatment on Pedicularis spp. 3. Another four chemicals, 2.4-D, Gramoxone, 2.4. 5-T and Para-col killed stems and leaves of Pedicularis spp. at the year treated, but appeared again next spring. 4. Eradication effectiveness in terms of spraying season was proved to be that late August was better than late May or June.

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Antibiotic and Phytotoxic Activities of Ophiobolins from Helminthosporium Species

  • Kim, Hyun-Ju;Kim, Jin-Cheol;Kim, Byung-Sup;Kim, Hong-Gi;Cho, Kwang-Yun
    • The Plant Pathology Journal
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    • v.15 no.1
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    • pp.14-20
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    • 1999
  • Twenty isolates of Helminthosporium species were obtained from various grass plants and tested for controlling efficacy on the development of plant diseases. An isolate of Helminthosporium sp. TP-4 was chosen and six antibiotic substances were purified from cultures of the fungus by repeated silica gel column chromatography and preparative thin-layer chromatography. They were identified as ophiobolin a, 6-epiophiobolin A, 3-anhydroophiobolin A, 3-anhydro-6-epiophiobolin A, iphiobolin B, and iphiobolin I mainly by mass spectrometry and nuclear magnetic resonance spectrometry. Ophiobolins inhibited the growth of a grampositive bacterium Streptomyces griseus, but were not active against gram-negative bacteria. They also showed an antifungal activity. In in vivo tests, iphiobolin B exhibited potent controlling activities against rice blast, tomato late blight, and wheat leaf rust with control values more than 90% and 70% at concentration of $500\mu\textrm{m}$/ml and 100 ${\mu}{\textrm}{m}$/ml. Ophiobolin A and 6-epiophiobolin A controlled the development of wheat leaf rust more than 80% at concentrations of 100 /ml and $500\mu\textrm{m}$/ml respectively. 3-Anhydro-6-epiophiobolin A was not active against any plant disease. On the other hand, the A-series ophiobolins other than 3-anhydroophiobolin A showed stronger phytotoxic activity in a leaf-wounding assay using 8 plant species than those of 3-anhydroophiobolin A, ophiobolin B, and ophiobolin I. The results indicate that there is little correlation between antifungal activity and phytotoxicity of ophiobolins.

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Investigation of Corrosion Minerals from the Remediation for TCE-Contaminate d Groundwater (TCE로 오염된 지하수 정화시 부식 광물에 대한 연구)

  • Moon, Ji-Won;Moon, Hi-Soo;Yungoo Song;Kang, Jin-Kyoo;Yul Roh
    • Journal of the Mineralogical Society of Korea
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    • v.16 no.1
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    • pp.107-123
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    • 2003
  • The objective of this study was to investigate mineral precipitates, which derived from the zero valent iron (ZVI) corrosion during TCE dechlorination and to find the controlling factors in mineral precipitates. A series of column experiemnts were conducted to evaluate the location of ZVI and the effects of electrode arrangements in electro-enhanced permeable reactive barrier (E2PRB) systems. Based on mineralogical study, ZVI samples near the influent port had more lepidocrocite, ferrihydrite or Fe (oxy)hydroxide, and (phospho)siderite while backward samples had more akaganeite, magnetite/maghemite, and intermediate green rust (GR) I and GR II. A suite of mineral distribution was preferabley related to the dissolved oxygen and the increased pH. Controlling factors of mineral precipitates in an E2PRB system were found to be (1) pH, (2) dissolved oxygen, (3) the types of Fe intermediates, and (4) anionic species to form complex strongly.

Corrosion Resistance of Galvanized Steel by Treating Modified Si Organic/Inorganic Hybrid Coating Solution (Si 변성 유/무기 하이브리드 코팅액에 의한 아연도금강판의 내식특성)

  • Seo, Hyun-Soo;Moon, Hee-Joon;Kim, Jung-Ryang;Kim, Jong-Soon;Ahn, Seok-Hwan;Moon, Chang-Kwon;Nam, Ki-Woo
    • Journal of Ocean Engineering and Technology
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    • v.25 no.1
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    • pp.32-38
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    • 2011
  • Galvanized steel has gone through a chemical process to keep it from corroding. The steel gets coated in layers of zinc because rust will not attack this protective metal. For countless outdoor, marine, or industrial applications, galvanized steel is an essential fabrication component. The reduction of the corrosion rate of zinc is an important topic. In the past, a very popular way to reduce the corrosion rate of zinc was to use chemical conversion layers based on $Cr^{+6}$. However, a significant problem that has arisen is that the use of chromium salts is now restricted because of environmental protection legislation. Therefore, it is very important to develop new zinc surface treatments that are environmentally friendly to improve the corrosion resistance of zinc and adhesion with a final organic protective layer. In this study, a Urethane solution (only Urethane 20 wt.%; S-700) and an organic/inorganic solution with Si (Si polysilicate 10 wt.% + Urethane 10 wt.%; LRO-317) are used. Based on the salt spray test of 72 h, S-700 and LRO-317 had a superior effect for the corrosion resistance on EGI and HDGI, respectively.

A Study on Mitigation of Rail Corrosion using Sacrificial Anode Cathodic Protection Method (희생양극법을 이용한 레일부식 저감 방안에 관한 연구)

  • Choi, Jung-Youl;Kim, Jun-Hyung;Lee, Kyu-Yong;Kim, Young-Ki;Park, Jong-Yoon;Song, Bong-Hwan;Seol, Jin-Woong
    • Journal of the Korean Society of Safety
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    • v.32 no.6
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    • pp.54-60
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    • 2017
  • A railway rail will be corroded by the repetitive sea wind and fog in the splash and tidal zone such as Youngjong grand bridge. And these rusts of rail could be increased by increasing service period, and it frequently occurred the safety accidents or disorders in electrical problem. In this study, the sacrificial anode cathodic protection method was proposed as a measures for reducing the corrosion of the railway rails in the oceanic climate conditions. As the results of immersion test using the salt water during four months, the sacrificial anode cathodic protection method using the aluminum anode(Al-anode) was evaluated that a distinct effect on corrosion reduction in the rails. Therefore the sacrificial anode cathodic protection method was experimentally proven that a disorders in aspects electric and signal of railway operation condition such as direct fixation track system in Youngjong grand bridge could be prevented by reducing rust falling from the rail. In addition, the installation conditions of the anodes directly affect the transmission range of corrosion potential, the sectional loss of anode, and the corrosion reduction effect. Therefore, to expect the corrosion reduction effect of rails under the oceanic climate conditions for railway track, it was important to adopted the appropriate spacing of anode installation by considering the actual field conditions.

Physiologic Races of Puccinia graminis f. tritici in Korea (한국에 분포한 맥류 줄기녹병균(Puccinia graminis f. sp. tritici)의 생리적 품종)

  • Chung Bong Koo;Lee Ji Young
    • Korean journal of applied entomology
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    • v.12 no.2
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    • pp.79-82
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    • 1973
  • 1. In order to investigate Physiologic races of Puccinia gramininis f. sp. tritici as basic materials for tile breeding of resistant varieties to stem rust of wheat, this experiment was carried out during 1971 and 1973. 2. Twenty seven isolates of the fungus were identified as follows: two isolates of race 11, eight . isolates of race 17, and 21, four isolates of race 34, one each of race 37 and 56, respectively The remaining three isolates identified were not identical with the key issued by Stakman, et at in 1962. Therefore, the three new races were tentatively numbered $K_3,\;K_4\; and\; K_4,$ in addition to $K_l\;and\;K_2$ described in 1961. 3. Therefore, attempts to produce resistant varieties to stem rust of wheat should be accompanied by intensive investigation of Physiologic races of p. graminis f. sp. tritici in the future.

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Studies on the Disease of Pear Rust caused by Gymnosporangium haraeanum SYDOW I. Some Ecological Investigation of Inoculum Source (배나무 붉은별무늬병(적성병) 관한 연구 I. 전염원의 몇가지 생태 조사)

  • Kim Seung Chul;Kim Choong Hoe
    • Korean journal of applied entomology
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    • v.19 no.1 s.42
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    • pp.39-44
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    • 1980
  • The outbreak of the pear rust caused by Gymnosporangium haraenum SYDOW has increased gradually since 1973, and amounted to 60.3 percent infection of leaves in 1975. But it has reduced due to regulation of juniper plantings by Plant Protection Law enacted in 1974. The teliospores of C. haraeanum germinated from middle of April to middle of May under natural condition. The germination of teliospores was observed 5 day earlier under laboratory condition with the artificial rainfall than that of natural condition. It was required considerable rainfall and longer than 3hr rainy period to germinate teliospores after being matured. Infection of rear leaves took place in the rain or just after the rain, but not after 24hr. The incubation period of G. haraeanum on the leaf was 9 to 10 days. In case that the distance between orchard and juniper trees was less than loom, almost all of the pears were infected, but the chance oft infection reduced in proportion as the distance increased. No infection occurred at the distance of further than 2000m.

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Biocontrol Activity of Acremonium strictum BCP Against Botrytis Diseases

  • Choi, Gyung-Ja;Kim, Jin-Cheol;Jang, Kyoung-Soo;Nam, Myeong-Hyeon;Lee, Seon-Woo;Kim, Heung-Tae
    • The Plant Pathology Journal
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    • v.25 no.2
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    • pp.165-171
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    • 2009
  • Biological control activity of Acremonium strictum BCP, a mycoparasite on Botrytis cinerea, was examined against six plant diseases such as rice blast, rice sheath blight, cucumber gray mold, tomato late blight, wheat leaf rust, and barley powdery mildew in growth chambers. The spore suspension of strain BCP showed strong control activities against five plant diseases except against wheat leaf rust. On the other hand, the culture filtrate of A. strictum BCP was effective in controlling only cucumber gray mold and barley powdery mildew. Further in vivo biocontrol activities of A. strictum BCP against tomato gray mold were investigated under greenhouse conditions. Control efficacy of the fungus on tomato gray mold increased in a concentration-dependent manner. Treatment of more than $1{\times}10^6$ spores/ml significantly controlled the disease both in tomato seedlings and in adult plants. The high disease control activity was obtained from protective application of the strain BCP, whereas the curative application did not control the disease. Foliar infections of B. cinerea were controlled with $1{\times}10^8$ spores/ml of A. strictum BCP applied up to 7 days before inoculation. In a commercial greenhouse, application of A. strictum BCP exhibited the similar control efficacy with fungicide procymidone (recommended rate, $500{\mu}g/ml$) against strawberry gray mold. These results indicate that A. strictum BCP could be developed as a biofungicide for Botrytis diseases under greenhouse conditions.

Antifungal Activity of the Methanol Extract of Myristica malabarica Fruit Rinds and the Active Ingredients Malabaricones Against Phytopathogenic Fungi

  • Choi, Nam-Hee;Choi, Gyung-Ja;Jang, Kyoung-Soo;Choi, Yong-Ho;Lee, Sun-Og;Choi, Jae-Eul;Kim, Jin-Cheol
    • The Plant Pathology Journal
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    • v.24 no.3
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    • pp.317-321
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    • 2008
  • In a search for plant extracts with in vivo antifungal activity for plant diseases, we found that the methanol extract of Myristica malabarica fruit rinds effectively suppressed the development of several plant diseases. The methanol extract exhibited potent 1-day protective activity against rice blast, tomato late blight, wheat leaf rust and red pepper anthracnose. It also showed 7-day and 4-day protective activities against the plant diseases. Three antifungal resorcinols were isolated from the methanol extract of M. malabarica fruit rinds and identified as malabaricones A(MA), B(MB), and C(MC). Inhibitory activity of the three resorcinols against mycelial growth of plant pathogenic fungi varied according to compound and target species. All three compounds effectively reduced the development of rice blast, wheat leaf rust and red pepper anthracnose. In addition, MC was highly active for reducing the development of tomato late blight. This is the first report on the antifungal activities of malabaricones against filamentous fungi.