• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1991년도 가을 학술발표회 논문집
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• pp.99-106
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• 1991

Result of an experimental study on the manufacture, the mechanical properties and waterightness of pitch-based carbon fiber reinforced fly ash.cement composites are presented in this paper. The carbon fiber reinforced fly ash.cement composites using early strength cement, silica powder and a small amount of stylene butadiene rubber latex are prepared with carbon fiber, foaming agents and mixing conditions. As a result, the mechanical and plysical properties such as compresive, tensile and flectural strengths, watertightness and cement composites are improved by using a small amount of stylene butadiene rubber latex.

• Elastomers and Composites
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• 제6권1호
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• pp.71-81
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• 1971

The intention of this study is to investigate the properties of polymer blend, NBR/PVC vulcanizates and blending procedures such as roll-mixing temperatures and sequences for polymer blending of NBR and PVC(resin type). The results obtained are as follows: 1. The roll temperature applied for polymer blending is around $150^{\circ}C$. At this temperature region, the degradation of rubber stock, which may be caused by heat, can be minimized and mill processing in practical application in industries can also be facilitated. 2. It is obviously necessary that a small amount of plasticizers should be added to the stock for improving processibility of roll mixing and physical properties. 3. On roll-mixing sequence, it is more effective that PVC compounded with plasticizer is added to NBR milled on hot roll. 4. The vulcanizates of the blends with different degree of polymerization of PVC ale similar to one another in properties. 5. NBR/PVC(70/30) blends shows the better physical characters than eve,-made foreign latex blend except abrasion-resistance. 6. As PVC addition ratio is increased, the physical properties such as resistance to ozone, tear, heat and oil and tensile strength, modulus, hardness have also improved, on the other hand, tension set and rebound character decreased. 7. The curve of ultimate elongation have point of inflection at the ratio of $30\sim40$ part of PVC. 8. While CR is blended, the physical properties such as brittle point, rebound and resistance to oil in high temperature have improved. 9. Polymer blend of NBR and domestic PVC is applied for the industrial utility such as rubber sole and heel, electric wire cover and oil-resistant packing, coating and gasket, printing roll, film for food packing etc.

• Elastomers and Composites
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• 제45권1호
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• pp.44-50
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• 2010

기계적 혼련법으로 butadiene rubber(BR)과 대표적인 결정성고무인 chloroprene rubber(CR) 블렌드 혼련물을 제조하여, 이들의 가교 거동, 기계적 성질, 내오존성 및 동적 기계적 성질 등을 검토하였다. 내오존시험에 있어서 50 wt% CR 고무의 첨가에 의하여 크게 개선됨을 확인할 수 있었다. Rheovibron에 의한 동적 계적 특성 측정의 결과로부터 BR/CR 블렌드는 두 개의 전이를 보였으며 $tan{\delta}$ 피이크의 위치는 CR 고무의 함량이 증가함에 따라 고온 쪽으로 이동함을 확인할 수 있었다. 한편 CR 고무량이 증가할수록 최적 가황시간이 증가하는 경향을 보였다.

• Elastomers and Composites
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• 제56권1호
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• pp.6-11
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• 2021

In order to develop an ultra-high-density elastomeric material for substitution of steel dynamic dampers, a new curing system and technique for high-loading of the filler were examined in this study. Mechanochemical modification of chloroprene rubber (MAH-g-CR) using an internal mixer was carried out with maleic anhydride (MAH) as a reactive monomer. The optimum amount of MAH was 10 phr and the efficient grafting of MAH on CR could be achieved at a mixing temperature of 100℃. After preparing MAH-g-CR, 50 mol% epoxidized natural rubber (ENR 50) was blended with MAH-g-CR to develop a "self-curable rubber blend system" via reaction between the functional groups of the elastomeric matrices without the curing agent and additives. The content of ENR 50 was fixed at 30 wt.% throughout evaluation of the curing behavior of the MAH-g-CR/ENR blend. Tungsten powder was added to the MAH-g-CR/ENR matrix up to 60 vol.% to obtain ultra-high-density, and the maximum density obtained was 7.57 g/㎤. Stable ts2 (scorch time) and t90 (90% cure time) could be obtained even when tungsten powder was incorporated up to 60 vol.%. In addition, the tensile strength and damping properties of MAH-g-CR/ENR containing 60 vol.% of tungsten were better than those of CR containing 60 vol.% of tungsten.

• 한국기계가공학회지
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• 제21권8호
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• pp.79-86
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• 2022

With the recent increase in the demand for electric vehicles, it is necessary to identify the high current safety of automobile parts. Among the automobile parts, the EPDM parts required colored parts from the existing black; therefore, it was necessary to change the basic filler from carbon black to silica. The rubber used in automobile parts is flexible and exhibits basic characteristics of high strength and elongation. However, as the filler is changed to silica, its physical properties, such as tensile strength and elongation, are lower than those of the existing carbon black base. Therefore, it is necessary to evaluate the mechanical properties with the addition of the EPDM compound using silica as a base without degrading the physical properties of EPDM. In this study, an experiment based on the additive content was performed using the mixture experimental planning method to analyze the mechanical properties according to the additive type and mixing ratio of silica-based EPDM. The mixing ratio of the four additives was set using a simplex lattice design, and the tensile strength, elongation, modulus 300%, and permanent compression reduction rate were analyzed for mechanical characteristics, and rheometer experiments were performed for vulcanization characteristics. Through statistical analysis of the measured data, the main effects and interactions of the EPDM-blended rubber additives were analyzed. These results can be used to derive a mixing ratio of additives that satisfies the required characteristics of the EPDM compound.

• Elastomers and Composites
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• 제47권3호
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• pp.188-193
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• 2012

고무부품의 신뢰성을 확보하기 위해서는 피로수명예측 및 평가기술 개발이 중요하다 하겠다. 최근에 고무부품에 대한 고 성능, 고 신뢰성을 위해 설계, 해석 및 평가기술이 요구되고 있으나, 지금까지는 경험과 시행착오적인 방법으로 개발되고 있는 실정이다. 따라서, 본 연구에서는 고무소재에 대해 배합조건, 기계적 특성, 열화 및 피로수명 등을 포함하는 고무소재 물성 데이터베이스를 구축하고, 고무부품의 특성해석 결과를 데이터베이스와 연계하여 고무부품의 피로해석 모델을 개발하였으며, 실제 피로시험 결과를 통하여 개발된 모델의 타당성을 검증하였다.

• Elastomers and Composites
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• 제27권4호
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• pp.262-266
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• 1992

A number of tin-containing elastomers are produced commercially by Korea Kumho Petrochemical Co., Ltd. (KKPC) under the Kosyn Sol tradename. The effect of mastication of commercial and laboratory polymerized S-SBR has, been investigated using chemical mixer(ML-500), NMR, GPC and Mooney viscometer. Mastication of polymers containings coupling bonds is affected by the amount of stearic acid, the temperature of mixing and the time length of mixing.

• Journal of the Korean Wood Science and Technology
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• 제42권5호
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• pp.605-614
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• 2014

This study investigated microstructural changes of cured urea-formaldehyde (UF) resins mixed with aqueous rubber latex emulsion after intentional acid etching. Transmission electron microscopy (TEM) was used in order to better understand a hydrolytic degradation process of cured UF resins responsible for the formaldehyde emission from wood-based composite panels. A liquid UF resin with a formaldehyde to urea (F/U) molar ratio 1.0 was mixed with a rubber latex emulsion at three different mixing mass ratios (UF resin to latex = 30:70, 50:50, and 70:30). The rate of curing of the liquid modified UF resins decreased with an increase of the rubber latex proportion as determined by differential scanning calorimetry (DSC) measurement. Ultrathin sections of modified and cured UF resin films were exposed to hydrochloric acid etching in order to mimic a certain hydrolytic degradation. TEM observation showed spherical particles and various cavities in the cured UF resins after the acid etching, indicating that the acid etching had hydrolytically degraded some part of the cured UF resin by acid hydrolysis, also showing spherical particles of cured UF resin dispersed in the latex matrix. These results suggested that spherical structures of cured UF resin might play an important role in hindering the hydrolysis degradation of cured UF resin.

• 폴리머
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• 제36권5호
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• pp.637-642
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• 2012

실리카로 충전된 SBR(styrene butadiene rubber)/BR(butadiene rubber) 합성고무 복합소재에 대해서 가공기기의 구조가 실리카 분산에 미치는 영향을 파악하기 위해 주사전자 현미경(SEM-scanning electron microscope)을 이용하여 컴파운드의 모폴로지를 관찰하였다. Internal mixer 내에서 intermeshing rotor와 tangential rotor에 의해 배합된 컴파운드를 비교한 결과, intermeshing rotor에 의해 가공되었을 경우 실리카 입자가 더 고르게 분산 및 분포되었음을 관찰하였다. Rotor의 geometry 차이에 의해 intermeshing rotor가 tangential rotor보다 더 큰 전단력(shear)을 컴파운드에 전달하여 실리카 입자를 효과적으로 분산 및 분배시킨 것으로 판단된다.

• Elastomers and Composites
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• 제45권4호
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• pp.280-285
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• 2010

CIIR에 BR, SBR 및 NBR을 다양한 조성으로 혼합하여 블렌드물의 마찰계수와 내마모특성 및 물리적 특성 변화 등을 검토하였다. 영구압축줄음율 측정에서 블렌드비율 25%에서 가장 높은 값을 나타내어 변형에 대한 저항 특성이 가장 낮은 것으로 나타났다. SBR, NBR, BR이 CIIR에 블렌딩됨에 따라 블렌드물의 마찰계수는 산술평균적으로 저하하는 경향을 나타내었다. 마찰력 향상을 위하여 BR에 CIIR을 블렌딩하는 경우 마찰계수 증가에 의한 접지력 향상보다는 내마모 성능 저하에 의한 마이너스효과가 더욱 큰 것으로 나타났다.