• Title/Summary/Keyword: Rubber Compound

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Influence of Dicyclopentadiene Resin on Abrasion Behavior of Silica-Filled SBR Compounds Using Different Abrasion Testers

  • Eunji Chae;Seong Ryong Yang;Seok Hyun Cho;Sung-Seen Choi
    • Elastomers and Composites
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    • v.58 no.3
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    • pp.103-111
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    • 2023
  • The abrasion resistances of silica-filled styrene-butadiene rubber (SBR) compounds prepared with and without dicyclopentadiene resin (SBR-R and SBR-0, respectively) were studied using four different abrasion testers, namely cut and chip (CC), Lambourn, DIN, and laboratory abrasion tester (LAT100). The effect of the resin on the abrasion behavior was elucidated by analyzing the morphologies and size distributions of wear particles. All the wear particles had rough surfaces, but those obtained in the Lambourn abrasion test exhibited relatively smooth surfaces. The size distributions of the wear particles showed different trends depending on the abrasion tester and the rubber compound; however, most of the wear particles were larger than 1000 ㎛. The SBR-R sample showed a wide range of particle sizes (from 63 ㎛) in the LAT100 abrasion test and majority of the wear particles were 500-1000 ㎛, whereas the SBR-0 sample had the most distribution of larger than 1000 ㎛. The abrasion rates of SBR-0 sample were lower than those of the SBR-R sample for the CC and LAT100 abrasion tests, but the Lambourn abrasion test result showed the opposite trend. Addition of the resin influenced the abrasion behavior, however the effect varied depending on the type of abrasion tests.

A Study on the Life Time Prediction and Acid-Heat aging Property of NBR Rubber for Fuel Cell Gasket (연료전지 카스켓용 NBR 고무의 산-열 노화 특성과 수명예측에 관한 연구)

  • Kim, Mi-Suk;Kim, Jin-Hak;Kim, Seok-Jin;Kim, Jin-Kuk
    • Elastomers and Composites
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    • v.42 no.1
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    • pp.20-31
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    • 2007
  • Material characteristics and lifetime evaluation are very important in design procedure to assure the safety and reliability of the rubber components. In this paper, the NBR compound was prepared by sulfur-cure system, and was used in predicting the lifetime of rubber gasket made by the compound. The accelerated material aging was investigated at different temperatures at 120, 140 and $160^{\circ}C$ and aging time from 3 hours to 600 hours at 5, 6, 7 vol %. of $H_2SO_4$ concentrations The rubber strips were placed in acid solution using pyrex g1ass tube. Both ends of pyrex g1ass tube were sealed to avoid evaporation of solution during heating at given time. The material test and accelerated acid-heat aging test were carried out to predict the useful life of NBR rubber gasket for a fuel cell stack. In order to investigate the effects of acid-heat aging on the properties of the NBR, tensile strength, elongation at break, hardness and crosslink-density were measured. The tensile strength decreases as the $H_2SO_4$ concentrations and temperature increase. Results were evaluated using Arrhenius equation.

Amino Silane, Vinyl Silane, TESPD, ZS(TESPD/Zinc Complex) Effects on Carbon Black/Clay Filled Chlorobutyl Rubber(CIIR) Compounds Part I: Effects on Hard Clay/Carbon Black Filled Compounds

  • Kim, Kwang-Jea
    • Carbon letters
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    • v.10 no.2
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    • pp.101-108
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    • 2009
  • Various silanes, amino silane, vinyl silane, TESPD, and ZS (TESPD/zinc soap complex), are added into chlorinated isobutylene-isoprene copolymer (CIIR)/hard clay/carbon black (CB) compound and they are investigated with respect to the vulcanization characteristics, the processability, and the mechanical properties. In hard clay/CB filled system, only ZS silane added compound shows both lower Mooney viscosity and extrusion torque while vinyl silane added compound showed only a lower extrusion torque. All the ZS added compounds showed the lowest viscosity among them. The silane added compounds showed an increased modulus. In 'fatigue to failure' count test, the ZS added compound showed superior counts compared to other silane (amino, vinyl, TESPD) added compounds. The mechanical properties were significantly increased when the S2 and ZS were added into CIIR/hard clay/CB compound. The ZS added compounds showed a significant improvement on elongation modulus.

Mathematical Modeling and Analysis on the Behavior of VOC in an Indoor Environment (휘발성 유기화합물의 거동특성 예측을 위한 수학적 모델링 및 실내 환기특성 연구)

  • 이승철;최청렬;김창녕
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.7
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    • pp.627-636
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    • 2001
  • This paper presents a numerical analysis of the emission process of volatile organic compound(VOC) from building material and its diffusion in a room. A polypropylene styrene-butadiene rubber(SBR) floor plate is chosen as the emission source of VOC. This study investigates spatial concentration distributions and time history of room-averaged VOC concentration for both with and without flushing. The results of this study show that for calculation based on ten-days period the room averaged VOC concentrations with and without flushing are quite different. the results thus suggest the need of flushing for new buildings.

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Improvement of Insulation Performance of Vehicle Rubber Hoses (자동차용 고무호스의 진동 절연성능 향상에 관한 연구)

  • Jung, Heon-Seob;Min, Byung-Kwon;Lee, Seong-Hoon;Woo, Hee-Soo;Park, Hyun-Ho
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.22 no.9
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    • pp.837-844
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    • 2012
  • We considered an approach in terms of materials for improvement of insulation performance of vehicle rubber hoses. Ethylene propylene rubber(EPDM) for heater hoses in cooling system and acrylic rubber(AR) for intercooler hose in intake system were chosen for mixing for the vibration and noise performance. We modified EPDM and AR through changing compound of base polymer, reinforcement fillers and additives. Dynamic mechanical analysis(DMA) was used to measure viscoelastic properties such as shear modulus and loss factor($tan{\delta}$). Vehicle acceleration test was also conducted to observe indoor changes in insulation performance of hoses.

Dynamic Mechanical and Morphological Properties of Natural Rubber Vulcanizates Containing Fillers

  • Lee, Hae Gil;Park, Chan Young
    • Elastomers and Composites
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    • v.51 no.3
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    • pp.218-225
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    • 2016
  • In order to examine correlation between silane coupling agent and activator which affects the physical properties of silica filled natural rubber compound, such as heat buildup, rebound property, dynamic mechanical and morphological properties were measured. With incorporation of silane coupling agent, $tan{\delta}$ at $0^{\circ}C$ was increased and at $60^{\circ}C$ was decreased, which resulted in improving of wet grip and rolling resistance. When silane coupling agent which is corresponding to 8~10% of silica was used, most favorable heat build up and $tan{\delta}$ was obtained. And also when activator was used, dispersibility of silica was improved as a result of reduction of reaggregation of silica.

A Study on electrical properties of silicone rubber for ATH of coupling agent (ATH 표면처리에 따른 실리콘 고무의 전기적 특성 연구)

  • Jung, Se-Young;Kim, Byung-Kyu;Park, Choon-Hyun;Yeo, Hak-Gue
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.206-209
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    • 2002
  • The purpose of this research was to find influence of compounding materials on electrical properties of silicone rubber such as tracking characteristic. The tracking characteristic was tested through controlling the ATH, a widely use anti-tracking agent. Regarding the particle size and coupling agent of ATH, compound silicone rubber with ATH of coupling agent and larger diameter showed better anti-tracking properties. It can be included that ATH of coupling agent use vinyl silane, dispose of tracking characteristic was achieve excellant results.

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Effect of Changing of Filling Materials in NR-SBR Type Elastomer Based Rubber Materials on Mechanical Properties (필러재료의 변화에 따른 NR-SBR 타입 엘라스토머 기반 고무재료의 기계적물성)

  • Bulbul, Saban;Yasar, Mustafa;Akcakale, Nuretttin
    • Polymer(Korea)
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    • v.38 no.5
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    • pp.664-670
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    • 2014
  • The effects of different filling materials and stabilizers in polymer based materials that are used as shoe soles in the shoemaking industry on the mechanical properties (strength, failure, tensile, tearing, bending etc.) of the final products have been examined in this study. Natural rubber (NR RSS3) and styrene-butadiene rubber (SBR 1502) were used as the main matrix material. New compounds were formed by replacing the fillings in the general compound of the existing factory ($SiO_2$, $CaCO_3$) with 40% (1200 g) blast furnace flue dust, rice husk, reclaimed rubber (recycled) and wood ash. Comparison of the new compounds with the existing compounds revealed a decrease in hardness, density, dimension stability, bending, tearing, % elongation and failure strength and an increase in wearing.

Dynamically Vulcanized PP/EPDM Blends:Effects of Different Types of Peroxides on the Properties

  • Naskar, K.;Noordermeer, J.W.M.
    • Elastomers and Composites
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    • v.38 no.2
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    • pp.167-174
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    • 2003
  • Thermoplastic vulcanizates (TPV) or dynamic vulcanizates are thermoplastic elastomers produced by simultaneous mixing and crosslinking of a rubber and a thermoplastic. The objective of the present work is to investigate the effects of different types of peroxides as curing agents on the properties of PP/EPDM TPVs. The mechanical properties change significantly with the chemical nature of the peroxides and the extent of crosslinking at a fixed PP/EPDM blend ratio. The tensile strength of the TPVs obtained with the various peroxides can be related to the solubility parameters of the polymers and of the peroxides. The Young's modulus of the peroxide-cured TPVs can be correlated with the delta torque values of equivalent thermoset EPDM vulcanizates, corresponding to the crosslinking efficiencies of the peroxides.

Development of Integrated Design System for Mechanical Rubber Components (고무류 기계부품 통합설계시스템 개발)

  • Woo, Chang-Su;Kim, Wan-Doo;Kim, Young-Gil;Shin, Wae-Gi;Lee, Seong-Hoon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.8
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    • pp.1045-1050
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    • 2010
  • Fatigue analysis and lifetime evaluation are very important in design procedure for assuring the safety and reliability of rubber components for mechanical systems. Till recently, the technology for the design, analysis, and evaluation of rubber products was required to manufacture rubber products with high quality, fidelity, and reliability. However, in the rubber-manufacturing companies in Korea, the processes of compound mixing, manufacturing of rubber products, and improvement of rubber properties are based on the trial-and-error method and experience. The objectives of this study are to establish methods for testing rubber materials, to develop a database of the properties of rubber materials, to evaluate the performance of rubber components, and to develop a system for predicting fatigue life. A method to predict fatigue-life of rubber components was proposed; in this method, the finite-element analysis and fatigue damage parameter as determined from a fatigue test are incorporated.