• Title/Summary/Keyword: Rubber Block

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Synthesis of Copoly(amide-imide)s Based on Silica Nano Particles-polyacrylamide

  • Min, Jun Ho;Park, Chan Young;Min, Seong Kee
    • Elastomers and Composites
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    • v.51 no.2
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    • pp.138-146
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    • 2016
  • It is an inconvenience for silica nano-particles to dry again when using it in that they cohere each other through moisture in the air. Acrylamide groups were introduced to improve such inconvenience and copolymerized with silica nano-particles and then we copolymerized again with polyamic acid in order to increase thermal characteristic. Amide block copolymers were prepared using silica and (3-mercaptopropyl) trimethoxysilane (MPTMS) with a siloxane group, using 2,6-Lutidine as a catalyst. Amide block polymers and copolymers were synthesized via ATRP after brominating pyromellitic dianhydride (PMDA) and polyamic acid of methylene diphenyl diamine (MDA), using ${\alpha}$-bromo isobutyryl bromide. Characteristic peaks of copolymer with amide and imide groups and patterns of amorphous polymers were researched by FT-IR and XRD analyses and the analysis of surface characteristic groups was conducted via XPS. A change in thermal properties was examined through DSC and TGA and solubility for solvents was also researched.

Conductive Carbon Block filled Composite(I): The Effect of Carbon Block on the Conductivity (전도성 카본블랙이 충전된 도전성 고분자 복합재료(I): 카본블랙이 전기전도성에 미치는 영향)

  • Kim, Jin-Kuk
    • Elastomers and Composites
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    • v.33 no.5
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    • pp.355-362
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    • 1998
  • The purpose of this paper is to develop a rational engineering conductive carbon filled composite through understanding of the effect of conductive carbon black. Polycabonate(PC), Acrylonitrile Butadiene Styrene copolymer(ABS) and PC/ABS resin were used as matrix of the conductive polymer composites. From the experimental results, PC filled with the fiber shaped carbon black showed a possibility to be a rational engineering conductive composite.

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Modification of Styrene-Butadiene-Styrene Block Copolymer and the Properties of Graft Products (스티렌-부타디엔-스티렌 블록 공중합체(共重合體)의 개질(改質)과 그 특성(特性))

  • Wang, Eun-Jin;Yoon, Jeong-Sik;Yoo, Chong-Sun;Paik, Nam-Chul
    • Elastomers and Composites
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    • v.25 no.4
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    • pp.273-279
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    • 1990
  • The graft polymerization of 2-hydroxyethylmethacrylate(HEMA) and vinyltriethoxysilane(VTES) onto styrene-butadiene-styrene block copolymer(SBS) was carried out in toluene, with radical initiator such as benzoyl peroxide(BPO) and 2, 2'-azo-bis-isobutyronitrile(AIBIN) under nitrogen atmosphere. The degree of grafting was increased with the increases of the reaction temperature and time. And the effeciency of BPO was superior to that of AIBN. The mechanical properties and molecular weight of graft products were measured and the applicability as adhesive of plasticized PVC leather was examined.

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Dynamic modeling of engine/mount system via experimental modal analysis (실험적 모우드해석을 통한 엔진 마운트계의 동역학적 모델링)

  • 정경렬;조치영;이종원
    • Journal of the korean Society of Automotive Engineers
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    • v.10 no.2
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    • pp.39-45
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    • 1988
  • The analytical model of an engine mount system with six degrees of freedom is identified using the modal parameters obtained from the experimental modal analysis. The structural parameters, mass moment of inertia of the engine block and stiffness of the rubber mounts, of the engine mount system are determined by using the condition that the estimated model parameters should satisfy the corresponding eigenvalue problem. The simulated modal parameters of the identified analytical model are in good agreement with the measured modal parameters.

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Verification of Moving Block for Rubber-Tired AGT System (고무차륜 AGT 시스템의 이동폐색 검증)

  • Jeong, Rag-Gyo;Chung, Sang-Gi;Cho, Hong-Sik;Yoon, Yong-Ki
    • Proceedings of the KIEE Conference
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    • 2005.04a
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    • pp.229-231
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    • 2005
  • 현재 철도 신호시스템 추세는 이동폐색 및 무인운전, 안전에 주안점을 두어 연구개발 되고 있다. 본 논문에서는 철도환경에 적합하고 경제성이 고려된 무선에 의한 새로운 열차검지기법인 토대로 이동폐색을 구현 및 평가하기 위하여 적용한 방법에 대하여 기술하고자 한다. 시험선에서 1편성의 열차 조건으로 이동폐색을 검증하기 위하여 선두열차를 모형열차(Dummy Train)로 시스템을 구성하여 정적인 상태에서 평가를 통해 검증하였다.

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Poly(ether block amide) (PEBA) Based Membranes for Carbon Dioxide Separation (이산화탄소 분리를 위한 PEBA공중합체 기반 분리막)

  • Lee, Jae Hun;Patel, Rajkumar
    • Membrane Journal
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    • v.29 no.1
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    • pp.1-10
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    • 2019
  • Poly(ether block amide) (PEBA) is one of the commercially important class of block copolymer very much suitable specifically for $CO_2$ separation. Gas separation membrane need to have good mechanical strength as well as high gas permeability. The crystalline polyamide (PA) block provides the mechanical strength while the rubbery polyether (PE) group being $CO_2$-philic facilitate $CO_2$ permeation though the membrane. Composition of thermoplastic and rubbery phase in the polymer are changed to fit into suitable gas separation application. Although PEBA has good permeability, the selectivity of the membrane can be enhanced by incorporating molecular sieve without affection much the gas permeability. Mixed matrix membrane (MMM), a class of composite membrane combine the advantage of polymer matrix with the inorganic fillers. However, there are some disadvantages based on the compatibility of the inorganic fillers and polymeric phase. This review covers both the advantage and limitations of PEBA block copolymer based composite membrane.

Study on the controlled preparation of polyolefin based block or graft copolymers (폴리올레핀 기반 블록 또는 그라프트 공중합체의 정밀 제조에 대한 고찰)

  • Lee, Jong Heon;Hong, Sung Chul
    • Elastomers and Composites
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    • v.48 no.1
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    • pp.30-38
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    • 2013
  • Polyolefin is one of the most important commodity polymers having excellent physical properties and cost competitiveness, which has continuously broadened their market in response to a heavy demand from industry. However, the lack of polarity in polyolefin has limited its applications, especially where interactions with other materials are important. In view of the above, the incorporation of polar functional groups in polyolefin has been widely attempted. Especially, the preparations of segmented modified polyolefin copolymers, such as block and graft copolymers have been extensively investigated, since the loss of the original properties of polyolefin can be minimized while the polar segments can endow interactions with other materials. Living radical polymerization (LRP) method can be one of the most attractive synthetic tools for the preparation of the modified polyolefin block or graft copolymers. In this review, progress on the preparation of the polyolefin based block or graft copolymers through LRP technique is briefly summarized.

Synthesis and Tribological Behavior of Nanocomposite Polymer Layers

  • Tsukruk, V.V.;Ahn, Hyo-Sok;Julthongpiput, D.;Kim, Doo-In
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.51-52
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    • 2002
  • We report results on microtribological studies of chemically grafted nanoscale polymer layers of different architecture with thickness below 30 nm. We have fabricated the molecular lubrication coatings from elastomeric tri-block copolymers and tested two different designs of corresponding nanocomposite coatings. We observed a significant reduction of friction forces and an increase of the wear stability when a minute amount of oil was trapped within the grafted polymer layer. These polymer gel layers exhibited a very steady friction response and a small value of the coefficient of friction as compared to the initial polymer coating. A polymer 'triplex' coating has been formed by a multiple grafting technique. The unique design of this layer Includes a hard-soft-hard architecture with a compliant rubber interlayer mediating localized stresses transferred through the topmost hard layer. This architecture provides a non-linear mechanical response under a normal compression stress and allows additional dissipation of mechanical energy via the elastic rubber interlayer.

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Printmaking Style Effect using Image Processing Techniques (영상처리 기법을 이용한 판화 스타일 효과)

  • Kim, Seung-Wan;Gwun, Ou-Bong
    • The Journal of the Korea Contents Association
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    • v.10 no.4
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    • pp.76-83
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    • 2010
  • In this paper, we propose a method that converts a inputted real image to a image feeling like printmaking. That is, this method converts a inputted real image to man made rubber printmaking style image using image processing techniques such as spatial filters, image bit-block transfer, etc. The process is as follows. First, after detecting edges in source image, we get the first image by deleting noise lines and points, then by sharpening. Secondly, we get second image using the similar method to the first image. Finally, we blend the first and the second image by logical AND operation This processing enables us to represent rubber panel and knife effects. Also, the proposed method shows that double edge detecting is effective in enhancing line-width and removing the tiny lines.

Cyclic testing of a new visco-plastic damper subjected to harmonic and quasi-static loading

  • Modhej, Ahmad;Zahrai, Seyed Mehdi
    • Structural Engineering and Mechanics
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    • v.81 no.3
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    • pp.317-333
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    • 2022
  • Visco-Plastic Damper (VPD) as a passive energy dissipation device with dual behavior has been recently numerically studied. It consists of two bent steel plates and segments with a viscoelastic solid material in between, combining and improving characteristics of both displacement-dependent and velocity-dependent devices. In order to trust the performance of VPD, for the 1st time this paper experimentally investigates prototype damper behavior under a wide range of frequency and amplitude of dynamic loading. A high-axial damping rubber is innovatively proposed as the viscoelastic layer designed to withstand large axial strains and dissipate energy accordingly. Test results confirmed all assumptions about VPD. The behavior of VPD subjected to low levels of excitation is elastic while with increasing levels of excitation, a significant source of energy dissipation is provided through the yielding of the steel elements in addition to the viscoelastic energy dissipation. The results showed energy dissipation of 99.35 kN.m under a dynamic displacement with 14.095 mm amplitude and 0.333 Hz frequency. Lateral displacement at the middle of the device was created with an amplification factor obtained ranging from 2.108 to 3.242 in the rubber block. Therefore, the energy dissipation of viscoelastic material of VPD was calculated 18.6 times that of the ordinary viscoelastic damper.