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Time-relationship between Deformation and Growth of Metamorphic Minerals around the Shinbo Mine, Korea: the Relative Mineralization Time of Uranium Mineralized Zone (신보광산 주변지역에서 변성광물의 성장과 변형작용 사이의 상대적인 시간관계: 우라늄 광화대의 상대적인 광화시기)

  • Kang, Ji-Hoon;Lee, Deok-Seon
    • Economic and Environmental Geology
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    • v.45 no.4
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    • pp.385-396
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    • 2012
  • The geochemical high-grade uranium anormal zone has been reported in the Shinbo mine and its eastern areas, Jinan-gun, Jeollabuk-do located in the southwestern part of Ogcheon metamorphic zone, Korea. In this paper is reported the time-relationship between deformation and growth of metamorphic minerals in the eastern area of Shinbo mine, which consists of the Precambrian metasedimentary rocks (quartzite, metapelite, metapsammite) and the age-unknown pegmatite and Cretaceous porphyry which intrude them, and is considered the relative mineralization time on the basis of the previous research's result. The D1 deformation formed the straight-type Si internal foliation which is defined mainly as the arrangement of elongate quartz, biotite, opaque mineral in andalusite porphyroblast. The D2 deformation, which is defined by the microfolding of Si foliation, formed S2 crenulation cleavage. It can be divided into two sub-phases, early crenulation and late crenulation. The former occurs as the curvetype Si foliation in the mantle part of andalusite. The latter occurs as S1-2 composite foliation which warps around the andalusite. The andalusite porphyroblast began to grow under non-deformation condition after the formation of S1 foliation which corresponds to the straight-type Si foliation. It continued to grow before the late crenulation phase. The age-unknown pegmatite intruded after the D2 deformation and grew the fibrous sillimanite which random masks the S1-2 composite foliation. The D3 deformation formed F3 fold which folded the S1-2 composite foliation, D2 crenulation, fibrous sillimanite. It means that the intrusion of pegmatite related to the growth of the fibrous sillimanite took place during the inter-tectonic phase of D2 and D3 deformations. The retrograde metamorphism is recognized by the chloritization of biotite and two-way cleavage lamellae which is parallel to the S1-2 composite foliation and the F3 fold axial surface in the andalusite porphyroblast. It occurred during the D2 late crenulation phase and D3 deformation. In considering of the previous research's result inferring the most likely candidate for the uranium source rock as pegamatite, it indicates that the age-unknown pegmatite intruded during the inter-tectonic phase of D2 and D3 deformations, i.e. during the retrograde metamorphism related to the uplifting of crust, and formed the uranium ore zone around the Shinbo mine.

Geochemical Characterization of Rock-Water Interaction in Groundwater at the KURT Site (물 암석 반응을 고려한 KURT 지하수의 지구화학적 특성)

  • Ryu, Ji-Hun;Kwon, Jang-Soon;Kim, Geon-Young;Koh, Yong-Kwon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.3
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    • pp.189-197
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    • 2012
  • Geochemical composition of fracture filling minerals and groundwater was investigated to characterize geochemical characteristics of groundwater system at the KURT site. Minerals such as calcite, illite, laumontite, chlorite, epidote, montmorillonite, and kaolinite, as well as I/S mixed layer minerals were detected in the minerals extracted from the fracture surfaces of the core samples. The groundwater from the DB-1, YS-1 and YS-4 boreholes showed alkaline conditions with pH of higher than 8. The electrical conductivity (EC) values of the groundwater samples were around $200{\mu}S/cm$, except for the YS-1 borehole. Dissolved oxygen was almost zero in the DB-1 borehole indicating highly reduced conditions. The Cl- concentration was estimated around 5 mg/L and showed homogeneous distribution along depths at the KURT site. It might indicate the mixing between shallow groundwater and deep groundwater. The shallow groundwater from boreholes showed $Ca-HCO_3$ type, whereas deep groundwater below 300 m from the surface indicated $Na-HCO_3$ type. The isotopic values observed in the groundwater ranged from -10.4 to -8.2‰ for ${\delta}^{18}O$ and from -71.3 to -55.0‰for ${\delta}D$. In addition, the isotope-depleted water contained higher fluoride concentration. The oxygen and hydrogen isotopic values of deep groundwater were more depleted compared to the shallow groundwater. The results from age dating analysis using $^{14}C$ indicated relatively younger (2000~6000yr old) groundwater compared to other european granitic groundwaters such as Stripa (Sweden).

Clay Mineralogy of the Soils Derived from Gray Shale (회색혈암(灰色頁岩)에서 유래(由來)된 토양점토(土壤粘土) 광물(鑛物)의 특성(特性))

  • Um, Myung-Ho;Jung, Pil-Kyun;Um, Ki-Tae;Lim, Hyung-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.26 no.1
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    • pp.1-9
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    • 1993
  • A study was carried out to investigate the genesis and mineralogical characteristics of clay minerals in three different types of soil derived from the gray shale distributed in Kyeongbuk Province in Korea. The soils have been developed from parent materials of residuum (Daegu series, Sirye series), colluvium(Banho series), and alluvium (Bigog series) of the same origin of parent rock with a topographical sequence. The investigation mainly focussed on the mineralogical aspects of primary minerals of asnd and silt fractions, identification and quantification of clay minerals, and characterization of hydroxy-interlayered mineral (HIM) along with their chemical composition. The identification was done through analyses of chemical, X-ray diffraction, and thermal methods. The major clay minerals in the soils are illite, vermiculite, kaolin and HIM, while chlorite and mixed layer minerals such as illite/chlorite and illite/vermiculite were coexisted as a subsidiary minerals. The distribution of clay minerals, however, varies according to the location and types of parent material. In the soils derived from the parent material of residuum, the upper soil (Daegu series) shows higher of 2:1 type minerals such as illite, vermiculite, and HIM than 1:1 type mineral rich in the lower soil(Sirye series). Soils developed from the parent material of colluvium and alluvium were high in illlte and mixed layer minerals, but low in HIM compared with the residual soils. The predominant weathering sequence of the clay minerals in each soil could be inferred as follows according to the minerlogical distribution and quantification of clay minerals : Daegu series, illite ${\rightarrow}$ vermiculite ${\rightarrow}$ HIM ; Sirye series, vermiculite ${\rightarrow}$ kaolin minerals ; Banho sereies and Bigog series, illite ${\rightarrow}$ illlte/vermiculite and/or illite/chlorlte mixed layer ${\rightarrow}$ vermiculite.

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Petrography and Geochemistry of the Ultramafic Rocks from the Hongseong and Kwangcheon areas, Chungcheongnam-Do. (충남 홍성 및 광천 지역 초염기성암의 암석 및 지구화학)

  • Song Suckhwan;Choi Seon Gyu;Oh Chang Hwan;Seo Ji Eun;Choi Seongho
    • Economic and Environmental Geology
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    • v.37 no.5
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    • pp.477-497
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    • 2004
  • In the Hongseong and Kwangcheon areas, two ultramafic rocks are exposed as isolated bodies in the Precambrian Kyeonggi gneiss complex. The ultramafic rocks extend for several hundred meters to NNE direction and are contact with adjacent metasediments by steeply dipping faults. The rocks are dunite or harzburgite showing dominantly equigranular-mosaic and protogranular textures with a minor amount of porphyroclastic textures. They contain varying amounts of fosteritic olivine (F$o_{0.91-0.93}$), magnesian pyroxene (E$n_{0.89-0.93}$) and tremolitic to magnesian hornblende with minor amounts of spinel, serpentine, chlorite, magnetite, phlogopite and talc. The rocks are in contrast with adjacent gneiss complex or metabasite (amphibole, biotite, plagioclase, alkali-feldspar and quartz). Geochemically, these ultramafic rocks are characterized by high magnesium number (M$g_#$> 0.88) and transitional element (mainly, Ni>1716 ppm, Cr>1789 ppm), low alkali element (e.g. $K_2$O<0.09 wt.%, Na$_2$O<0.19 wt.%) and depletion of incompatible elements. The calculated correlation coefficients showed good positive correlations among the ferrous (e.g. Sc, V, Zn) elements, incompatible elements (e.g. REE), and among SiO$_2$ or $Al_2$O$_3$ with ferrous elements, whereas negative correlations are appeared between Ni and major elements. These results involve increasing of the ferrous- and $Al_2$O$_3$-bearing minerals(e.g. amphibole and mica) with decreasing of Mg-bearing minerals (e.g. olivine) depending on the degree of alteration. Calculated geothermometries and mineral assemblages suggest that the ultramafic rocks have been metamorphosed through the condition from the greenschist to amphibolite facies. Compared with ultramafic rocks elsewhere, it is thought that those of the Hongseong and Kwangcheon areas are derivatives of the depleted sources since they are depleted in incompatible elements including REE abundances. Moreover overall characteristics of the ultramafic rocks are similar to the those of orogenic related Alpine type ultramafic rocks, especially, shallow mantle slab varieties.

A Case Study of Geometrical Fracture Model for Groundwater Well Placement, Eastern Munsan, Gyeonggido, Korea (지하수개발을 위한 단열모델 연구사례(경기도 문산 동쪽지역))

  • Choi Sung-Ja;Chwae Uee-Chan;Kim Se-Kon;Park Jun-Beom;Sung Ki-Sung;Sung Ik-Whan
    • Economic and Environmental Geology
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    • v.39 no.2 s.177
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    • pp.163-171
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    • 2006
  • This study is the case of groundwater development based on the geometrical fracture model of target area established only through geological fracture mapping technique. A fracture mapping of $9km^2$, eastern Munsan, has been conducted to determine geological and hydrological factors for new water well placement in the Gyeonggi gneiss complex. Geophysical exploration was not applicable because of small restricted area and dense underground utilities at the site. Form line mapping on the basis of foliation orientation and rock type revealed a synform of NS fold axis bearing to the south. An EW geological cross-section passed through the site area shows a F2 synform as a double-wall ice cream spoon shape. Three regional faults of $N20^{\circ}E,\;N30^{\circ}W$, and NS have been dragged into the site to help understand extensional fault paths. The $N20^{\circ}E$ fault with dextral sense is geometrically interpreted as a western fault of two flexural conjugate type-P shear faults in the F2 synformal fold. The NE cross-section reveals that a possible groundwater belt in the western limb of super-posed fold area is formed as a trigonal prism within 100 m depth of the intersectional space between the $N20^{\circ}E$ fault plane and the weakly sheared plane of transposed foliation. Another possible fault for water resource strikes $N40^{\circ}E$. Recommended sites for new water well placement are along the $N20^{\circ}E\;and\;N40^{\circ}E$ faults. As a result of fracture mapping, 145 ton/day of water can be produced at one well along the $N20^{\circ}E$ fault line. Exploration of groundwater in the area is succeeded only using with geological fracture mapping and interpretation of geological cross-section, without any geophysical survey. Intersection of fault generated with the F2 synformal fold and foliation supply space of groundwater reserver.

Characteristics of Groundwater Quality in Bedrock and Tailing Dumps at the Abandoned Dalcheon Mine Area (달천 폐광산 지역에서 광미적재지와 기반암 지하수의 수질특성 연구)

  • Yang, Sung-Il;Kang, Dong-Hwan;Kim, Tae-Yeong;Chung, Sang-Yong;Kim, Min-Chul
    • Economic and Environmental Geology
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    • v.41 no.1
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    • pp.47-56
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    • 2008
  • pH and Eh were measured at 25 points in the abandoned Dalcheon mine. And, major ion components $(Na^+,\;K^+,\;Ca^{2+},\;Mg^{2+},\;Cl^-,\;SO_4^{2-},\;CO_3^{2-},\;HCO_3^-)$ were analyzed through groundwater sampling at 41 points. pH and Eh were measured the highest concentration in serpentinite area. And, pH was between weak alkaline and intermediate values in study area. Groundwater in study area was dominated oxidation-reduction environment caused by reaction with carbonate rock. Because sulfur components contained in carbonate, serpentinite, arsenopyrite and pyrite was dissolved by groundwater, $SO_4^{2-}$ component was high in study area. And $Ca^{2+},\;Mg^{2+}$ of cations were high. Correlation coefficients of ion components in tailing dumps were 0.95 between $Ca^{2+}\;and\;SO_4^{2-}$, 0.86 between $Ca^{2+}\;and\;Mg^{2+}$, 0.85 between $Mg^{2+}\;and\;SO_4^{2-}$. Correlation coefficients of ion components in bedrock were 0.86 between $Mg^{2+}\;and\;SO_4^{2-}$, 0.68 between $Ca^{2+}\;and\;SO_4^{2-}$. Concentration range of $Ca^{2+}$ in tailing dumps was $6.85{\sim}323.58mg/L,\;and\;3.18{\sim}207.20mg/L$ in bedrock. Concentration range of $SO_4^{2-}$ in tailing dumps was $21.54{\sim}1673.17mg/L,\;and\;2.04{\sim}1024.64mg/L$ in bedrock. By the result of Piper diagram analysis with aquifer material, groundwater in tailing dumps was $Ca-SO_4$ type. Groundwater quality types with bedrock material were Mg-$SO_4$ and Mg-$HCO_3$ types in serpentinite area, Ca-$HCO_3$ type in carbonate area, Na-K and $CO_3+HCO_3$ types in hornfels, respectively. As a result of this study, groundwater in tailing dumps were dissolved $Ca^{2+},\;Mg^{2+}\;and\;SO_4^{2-}$ components with high concentration. Also, these ion components were transported into bedrock aquifer.

Studies on the Distribution Characteristics of Body Fat and the Estimation of Genetic Variation of Fat Amount in Broiler Type Chicken (육계의 체지방 분포특성과 유전변이 추정에 관한 연구)

  • 오희정;김재홍;오봉국
    • Korean Journal of Poultry Science
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    • v.15 no.1
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    • pp.21-29
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    • 1988
  • This study was conducted to obtain more detailed information on the characteristics of body fat distribution, genetic variation and correlation of fat amount at different location in broiler type chicken. A total of 429 offsprings, produced by mating 13 sires with 52 dams of WPR, were used for this study. All experimental analyses were made on dressed carcasses of 8 weeks of age. The average live body weight was 1,856g in male and 1,483g in female, the proportions of each part to live body weight were higher in male group except skin and abdominal fat pad. The total body fat was more in male (40.76g), but fat rate of total body, skin, and abdomen to live body weight were significantly higher in female group. The fat percentages in each body location were significantly higher in the fatty group and in each sex. The rates of abdominal fat to total body fat were increased by fattening, while subcutaneous fat percentages were lowered. There were high correlations between body weight and fat deposit in each location. The genetic correlation coefficients of body weight to fat percentages of skinned carcass, skin, abdomen, and total body fat to live body weight were negative in both sexes, but those to total body fat, eviscerated carcass fat, and skin fat were positive. In conclusion, the fat weight and fat percentage in individual chickens became higher by fattening however, genetic correlation between live body weight and percentages total body fat to live body weight were so low(negative) that decreasing body fat could be possible without decreasing body weight.

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Application of the Homogenization Analysis to Calculation of a Permeability Coefficient (투수계수 산정을 위한 균질화 해석법의 적응)

  • 채병곤
    • Journal of Soil and Groundwater Environment
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    • v.9 no.1
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    • pp.79-86
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    • 2004
  • Hydraulic conductivity along rock fracture is mainly dependent on fracture geometries such as orientation, aperture, roughness and connectivity. Therefore, it needs to consider fracture geometries sufficiently on a fracture model for a numerical analysis to calculate permeability coefficient in a fracture. This study performed new type of numerical analysis using a homogenization analysis method to calculate permeability coefficient accurately along single fractures with several fracture models that were considered fracture geometries as much as possible. First of all, fracture roughness and aperture variation due to normal stress applied on a fracture were directly measured under a confocal laser scaning microscope (CLSM). The acquired geometric data were used as input data to construct fracture models for the homogenization analysis (HA). Using the constructed fracture models, the homogenization analysis method can compute permeability coefficient with consideration of material properties both in microscale and in macroscale. The HA is a new type of perturbation theory developed to characterize the behavior of a micro inhomogeneous material with a periodic microstructure. It calculates micro scale permeability coefficient at homogeneous microscale, and then, computes a homogenized permeability coefficient (C-permeability coefficient) at macro scale. Therefore, it is possible to analyze accurate characteristics of permeability reflected with local effect of facture geometry. Several computations of the HA were conducted to prove validity of the HA results compared with the empirical equations of permeability in the previous studies using the constructed 2-D fracture models. The model can be classified into a parallel plate model that has fracture roughness and identical aperture along a fracture. According to the computation results, the conventional C-permeability coefficients have values in the range of the same order or difference of one order from the permeability coefficients calculated by an empirical equation. It means that the HA result is valid to calculate permeability coefficient along a fracture. However, it should be noted that C-permeability coefficient is more accurate result than the preexisting equations of permeability calculation, because the HA considers permeability characteristics of locally inhomogeneous fracture geometries and material properties both in microscale and macroscale.

Seasoning of Commercial Wood Using Solar Energy (태양에너지를 이용한 유용목재의 건조)

  • Jung, Hee-Suk;Lee, Hyoung-Woo;Lee, Nam-Ho;Lee, Sang-Bong
    • Journal of the Korean Wood Science and Technology
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    • v.16 no.4
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    • pp.10-39
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    • 1988
  • This study investigated the temperatures and relative humidities in the semi-greenhouse type solar dryer with a black rock-bed heat storage and without heat storage and outdoor temperature and relative humidity at 9 a.m. and 2 p.m.. A comparison was made of the drying rates, final moisture contents, moisture content distributions, casehardening stresses, drying defects, volumetric shrinkage of dried lumber for solar- and air-drying from the green condition of mixtures of Douglas-fir, lauan, taun, oak and sycamore 25mm- and 50 mm-thick lumber during the same period for four seasons, and heat efficiencies for solar dryer with and without the heat storage for saving of heat energy and the cost of lumber drying using the solar energy. The results from this study were summarized as follows: I. The mean weekly temperatures in the solar dryers were 3 to $6^{\circ}C$ at 9 a.m. and 9 to $13^{\circ}C$ at 2 p.m. higher than mean outdoor temperature during all the drying period. 2. The mean weekly relative humidities in the solar dryers were about 1 to 19% at 9 a.m. higher than the outdoor relative humidity. and the difference between indoor and outdoor relative humidity in the morning was greater than in the afternoon. 3. The temperatures and relative humidities in the solar dryer with and without the heat storage were nearly same. 4. The overall solar insolation during the spring months was highest and then was greater in the order of summer, atumm, and winter month. S. The initial rate of solar drying was more rapid than that of air drying. As moisture content decreased, solar drying rate became more rapid than that of air drying. The rates of solar drying with and without heat storage were nearly same. The drying rate of Douglas-fir was fastest and then faster in the order of sycamore, lauan, taun and oak. and the faster drying rate of species, the smaller differences of drying rates between thicknesses of lumber. The drying rates were fastest in the summer and slowest in the winter. The rates of solar drying during the spring were more slowly in the early stage and faster in the later stage than those during the autumn. 6. The final moisture contents were above 15% for 25mm-thick air dried and about 10% for solar dried lumber, but the mean final MCs for 50mm-thick lumber were much higher than those of thin lumber. The differences of final MC between upper and lower course of pile for solar drying were greater than those of pile for air drying. The differences of moisture content between the shell and the core of air dried lumbers were greater than those of solar dried lumber, smallest in the drying during summer and greatest in the drying during winter among seasons. 7. Casehardening stresses of 25mm- and 50mm-thick dried lumber were slight, casehardening stress of solar dried lumber was severer than that of air dried lumber and was similar between solar dried lumber with and without heat storage, Casehardening stresses of lumber dried during spring were slightest and then slighter in the order of summer, autumn, and winter. Casehardening stresses of Douglas -fir, sycamore and lauan were slight, comparing with those of taun and oak. 8. Maximum initial checks of 25mm-thick lumber occurred above and below fiber saturation point and those of 50mm-thick lumber occurred in the higher moisture content than thin lumber. As the moisture content decreased, most of checks were closed and didn't show distinct difference of the degree of checks among drying methods. The degree of checks were very slight in case of Douglas-fir and lauan, and severe in case of taun and oak. The degree of checks for 50mm-thick lumber were severer than those for 25mm-thick lumber. 9. The degree of warpage showed severe in case of oak and sycamore lumber, but no warping was found in case of Douglas-fir, lauan and taun. 10. The volumetric shrinkages of taun and oak were large and medium in case of Douglas-fir, lauan and sycamore. 11. Heat efficiencies of solar dryer with heat storage were 6.9% during spring, 7.7% during summer, 12.1% during autumn and 4.1% during winter season. Heat efficiency of solar dryer with heat storage was slightly greater than that of without heat storage. As moisture content of lumber decreased, heat efficiency decreased.

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Illite, Reviewed on the Chemical Compositions - The Mixed Phase among Muscovite, Pyrophyllite and Chlorite: EPMA Quantitative Analysis of Shale from the Jigunsan Formation at Seokgaejae in Samchuk-City, Gangwon-do (화학조성으로 다시 보는 일라이트-백운모, 파이로필라이트 및 녹니석의 혼합상: 강원도 삼척시 석개재에 분포하는 직운산층 셰일에 대한 EPMA 정량분석)

  • Choi, Seung-Hyun;Mun, Hyang-Ran;Lee, Young-Boo;Lee, Jung-Hoo
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.3
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    • pp.143-153
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    • 2012
  • Mica-type minerals (illites) in the shales of the Jigunsan formation at Seokgaejae in Samchuk-City, Gangwon-do are studied using electron probe micro analysis (EPMA). The average chemical formula of the mica-type mineral obtained from the quantitative analysis is $(K_{1.17}Na_{0.04}Ca_{0.01})(Al_{2.80}Mg_{1.17}Fe_{0.78})(Si_{6.34}Al_{1.66})O_{20}(OH)_4$, which shows a chemical formula within the range of illite. These illites so called can be considered as mixed-phases among muscovite, pyrophyllite and chlorite due to the low contents of interlayer cations and high Mg, Fe. The formula of illite is separated into those three minerals and the method for the separation is newly formulated and proposed in this study. From the formula of illite, the content of muscovite is estimated from K (Na and Ca included), the content of chlorite by Mg+Fe, and the rest remains as pyrophyllite. The chemical formula of muscovite can be calculated by subtracting the compositions of pyrophyllite and chlorite from the analyzed composition of illite using an ideal formula for pyrophyllite and analyzed average formula for chlorite. The calculated formula of muscovite is supposed to be stoichiometric in principle. The result of the separation of analyzed illite is 61% muscovite, 27.3% chlorite and 11.7% pyrophyllite and the calculated formula of muscovite after separation is $(K,Na,Ca)_{2.00}Al_{3.69}(Si_{6.75}Al_{1.25})O_{20}(OH)_4$. The calculated formula of muscovite slightly low in Al content can be considered to be reasonable in general when the low content of Al in the rock and the uncertainties of chlorite compositions used in the calculation are counted. This supports that the method of separation proposed in this study is also applicable.