The artificial rains having different pH and weathering simulation test were performed for Gyeongju Namsan granite and dacitic tuff to predict the role of acid rain in the deterioration of stone monuments located in Gyeongju area. The pH 4.0 rain reacted with the fresh granite showed near neutral pH at the early stage due to the hydrolysis of minerals in the rock surface. But the pH changed back to the initial pH in the later stage. On the other hand, the pH 5.6 rain showed the neutral pH for a longer time than the experiment with pH 4.0 rain, reflecting slower reaction of minerals due to the weaker acidity. When the pH 5.6 rain reacted with the weathered granite, the water showed neutral pH longer than the case of the fresh granite. The similar tendencies were observed in the experiment of dacitic tuff, except that the pH 4.0 rain reacted with dacitic tuff took a longer time to go back to the initial pH as compared with the case of granite. These results may due to the differences in mineral composition and texture of two rocks. Dacitic tuff contains more fine-grained or glassy groundmass than granite and is more reactive with weaker acid rain. It was predicted that the weight loss and strength decrease rate of dacitic tuff would be approximatetly twice relative to those of granite in the same experimental environment.
Park, Sung Mi;Lee, Myeong Seong;Kim, Jae Hwan;Lee, Chan Hee
Korean Journal of Heritage: History & Science
/
v.45
no.1
/
pp.86-101
/
2012
The constituting rocks of Multi-storied Round shape stone Pagoda of Unjusa Temple are lithic tuff and rhyolite tuff breaccia which show green or grey and also rock fragment with poor roundness are present in the structure. lithic tuff is composed of feldspar and quartz which are glassy texture and cryptocrystalline and also micro crystalline are scattered. phenocryst quartz and feldspar in the substrate composed of feldspar and opaque minerals are found in rhyolite tuff breaccia. dust, exfoliation, cavity, fracture and crack are observed in all the stone of the pagoda and the result of Infrared Thermography shows partial inter cavities have developed severely which may cause further exfoliation. In addition, a great deal of various grey, green, and yellow brown lichen as well as bryophyte are present at the upper part of eastern and western roof stone located above the third floor. Discolors remarkably shown at stereobate and roof stone are identified as inorganic pollutants such as manganese oxide, iron oxide and iron hydroxide. The stone of the pagoda of the Chemical Index of Alteration (CIA) and the Weathering Potential Index (WPI) are 55.69 and 1.12 respectively and this corresponds to a highly weathered stage. The measured values, average ultrasonic velocity 2,892m/s, coefficient of weathering 0.4k and compressive strength $1,096kg/cm^3$, suggest that the rock strength and durability are weakened.
Kim, Man-Il;Bae, Du-Won;Kim, Jong-Tae;Chae, Byung-Gon;Jeong, Gyo-Cheol
The Journal of Engineering Geology
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v.17
no.2
s.52
/
pp.289-297
/
2007
Slope failure that is occurred by rainfall generates a lot of property damages and loss of lives. Slope stability management and reinforcement countermeasure can be attained through continuous monitoring about various slope types that adjoin in human's life for reducing slope failure from natural and artificial cut slope hazards. The study area is rock slope that is consisted of gneiss, and large scale joint set is ranging by fault activity. This rock mass is exposed during long period and has lithological weathering property of weathered rock or soft rock. In-situ investigation carried out after divide by natural slope and cut slope. As a result, the natural slope appeared to high possibility of planar failure and wedge failure in few joint points that main joint set is formed. On the other hand, slope failure conformation in cut slope was superior only wedge failure occurrence possibility in eight joint points. In result of numerical analysis using SLIDE 2D, the minimum safety factor was analyzed slope stability for cut slope relatively low than natural slope in this study.
Most large cut slopes of open pit mines, roadways, and railways are steeply inclined and composed with rocks that do not contain soils. However, these rock slopes suffer both weathering and fragmentation. In the case of steep slopes, falling rock and collapse of a slope may often occur due to surface erosion. Cast-in place concrete and rubble work are the most widely used earth structure-based pressure supports that act as restraints against the collapse of the rock slope. In order to overcome the shortcomings of conventional retaining walls, a segmental grid retaining wall is being used with connects precasted segments to construct the wall. In this study, laboratory model test was conducted to estimate deformation behavior of segmental grid retaining wall with configuration of rear strecher, height and inclination of the wall. In order to examine the behavior characteristics of a segmental grid retaining wall, this research analyzes the aspects of spacial displacement through relative displacement according to change in the inclination of the wall. Also, the walls behavior according to the formation and status of the rear stretcher which serves the role of transferring the load from the header and the stretcher which make up the wall, the displacement of backfill materials in the wall, and the location of the maximum load were surveyed and the characteristics of displacement in the segmental grid retaining wall were observed. The test results of the segmental grid retaining wall showed that there was a sudden increase in failure load according to the decrease in the wall's height and the size of the in was greatly decreased. Furthermore, it revealed that with identical inclination and height, the structure of the rear stitcher did not greatly affect the starting point or size of maximum horizontal displacement, but rather had a stronger effect on the inclination of the wall.
Rock properties and the effects of chemicals that were used for conservation were studied for effective conservation treatment of Seated Buddha rock carving, which is composed of grayish white tuff, at Golguram Hermitage, Gyeongju. The rocks contain 3-5% montmorillonite, a swelling mineral and reacting with water, the d spacing of swelling minerals was increased (1.54-2.69%). On the one hand, the physical properties of the rock samples, such as surface hardness, water absorption rate, and porosity improved after the application of ethyl silicate-based stone strengthener. On the other, the interlayer of swelling minerals decreased and greater the of swelling mineral content, the greater is the extent of swelling (4.23-12.12%). When the ethyl silicate-based stone strengthener was applied after pretreatment with a swelling inhibitor, the physical properties were similar to those of the stone strengthener alone. There was no interlayer spacing change of swelling minerals due to swelling inhibition treatment; however, when the stone strengthener was applied after the swelling inhibitor, interlayer changes were similar to those when only the stone strengthener was treated (4.10-11.85%). Though the peak intensity of swelling minerals in X-ray diffraction pattern decreased, the effect of the swelling inhibitor was almost negligible. Therefore, it is not appropriate to use ethyl silicate-based stone strengthener for Golgulam rock containing swelling minerals and supplementing them with a swelling inhibition system is not effective. Because weathering rapidly progresses when swelling minerals contact moisture, for now, measures to prevent water contact, such as expansion of the canopy, are needed in the lower and side parts of the carving.
Journal of the Korean association of regional geographers
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v.2
no.2
/
pp.173-182
/
1996
The intent of this paper is to examine the talus in Chon-hwang-san in the southern part of Korean Peninsula, and then analyze its geomorphic feature and origin. The research is summarized as follows; (1) The talus is 220m long and the range of the width from 10 to 75m. The mean gradient is $33^{\circ}$ and the mean block size is $110{\times}59cm$(long axis$\times$short axis). The overall appearance of the talus is tongue-shaped and the geology of the constituent blocks is dacite. (2) This talus has two particular geomorphic landscapes. One is that the talus has not free face as source of blocks back of itself; the free face of the talus has been parallel retreated to disappearance by frost attack. The other is that the upper part of the talus is on the ridge. (3) This talus is classified into rock fall talus type, and the shape of rock fragments is angular. When considered in conjunction with face of being mentioned above, the morphology and lithology of the talus are best explained on the basis of origin under periglacial environment during late pleistocene time. (4) Most constituent rock debris are now lichen-covered, or covered with a mantle of weathering. There is no evidence of appreciable movement and for supplying block. Therefore, the talus appears to be relict or fossil form stage, currently.
Lee, Myeong Seong;Lee, Jae Man;Lee, Sun Myung;Kim, Sa Dug;Morii, Masayuki
Korean Journal of Heritage: History & Science
/
v.44
no.3
/
pp.78-91
/
2011
The Usuki Stone Buddha Statues in Japan are carved on mainly dark gray welded lapilli tuff accompanied by lenticular fiamme. This rock is composed of matrix which contains feldspar and opaque minerals with some phenocrysts of quartz and feldspar. The matrix is slight to highly welded. The statues have been weathered and weakened by salt and freezing of water. To enhance the mechanical properties of the rock, consolidants and water repellents were applied. The absorption ratio of the rock was highly decreased after the treatment of the water repellents, the consolidant OH 100, as well. Ultrasonic velocity revealed similarly higher values in the treated rock by KSE 300 and OH 100, compared to non-treated rock. KSE 300, especially, highly increased the Equotip surface hardness. All studied consolidants and water repellents were found to change the original color of the stone. SNL, specifically, resulted the significant change in color. In addition, KSE 300 were observed to improve resistance to weathering such as microcrack and fracture through freezing-thawing test after treatment.
Yeongdong area is located in the contact zone between central southeastern Ogcheon belt and Yeongnam massif, in which Cretaceous Yeongdong basin exists. Therefore, the study area has complex geological environment of various geological age and rock types such as Precambrian metamorphic rocks, age-unknown Ogcheon Supergroup, Paleozoic/Mesozoic sedimentary rocks, Mesozoic igneous rocks and Quaternary alluvial deposits. This study focuses on the link between the various geology and water type, and discussed the source of some major ions and their related water-rock interaction. For this study, the field parameters and ion concentrations for twenty alluvial/weathered and eighty bedrock aquifer wells were used. Statistical analysis indicates that there was no significant differences in groundwater quality between wet and dry seasons. Although various types were observed due to complex geology, 80 to 84 % of samples showed $Ca-HCO_3$ water type. Some wells placed in alluvial/weathered aquifers of Precambrian metamorphic and Jurassic granitic terrains showed somewhat elevated $NO_3$ and Cl concentrations. $Mg-HCO_3$ typed waters prevailed in Cretaceous Yeongdong sedimentary rocks. The deeper wells placed in bedrock aquifers showed complicated water types varying from $Ca-HCO_3$ through $Ca-Cl/SO_4/NO_3$ to $Na-HCO_3$ and Na-Cl type. Groundwater samples with $Na-HCO_3$ or Na-Cl types are generally high in F concentrations, indicating more influences of water-rock interaction within mineralized/hydrothermal alteration zone by Cretaceous porphyry or granites. This study revealed that many deep-seated aquifer had been contaminated by $NO_3$, especially prominent in Jurassic granites area. Based on molar ratios of $HCO_3/Ca$, $HCO_3/Na$, Na/Si, it can be inferred that Ca and $HCO_3$ components of most groundwater in alluvial/weathered aquifer wells were definitely related with dissolution of calcite. On the other hand, Ca and $HCO_3$ in bedrock aquifer seem to be due to dissolution of feldspar besides calcite. However, these molar ratios require other mechanism except simple weathering process causing feldspar to be broken into kaolinite. The origin of $HCO_3$ of some groundwater occurring in Cretaceous Yeongdong sedimentary rock area seems to be from dissolution of dolomite($MgCO_3$) or strontianite($SrCO_3$) as well.
In this study the occurrence and mineralogical characteristics of clay minerals from the Munhyun-dong landslide area in Pusan city were examined by XRD, SEM, and chemical analyses. Several types of clay minerals such as halloysite, vermiculite, mica/vermiculite interstratified mineral, vermiculite/smectite interstratified mineral, kaolinite and illite are found abundantly in the area. The occurrence of clay minerals suggest that they have been formed by weathering of andesite which is the bedrock of the area. It is believed that halloysite was formed in the early stage of weathering, and vermiculite, mica/vermiculite interstratified mineral and mica/vermiculite interstratified mineral were formed in the middle stage, and finally, kaolinite was formed. The clay minerals occurring in the central part of the landsliding area and within the slip surface are dominated by expandable minerals such as halloysite, vermiculite and vermiculite/smectite interstratified mineral. These clay minerals expand by absorbing water and effectively decrease the shear resistance of the rock mass, and therefore, they could be an important factor for the landslide. The analyses of geology and mineralogical characteristics of the area suggest that the landslide was caused by combination of various factors including steep slope, heavy rainfall, abundant joints, alteration of the rocks, and occurrence of expandable clay minerals. The result of this study suggests that the investigation for the prevention of possible landslide must include the examination of clay mineralogy as well as the site geology.
The Mireuksaji stone pagoda in Iksan is the largest stone pagoda existing in Eastern Asia. It was assumed that originally it had been established in the shape of nine-storied pagoda but as time went by only six-storied pagoda remained partially due to collapsing, repair and reconstruction. According to the reference, we can't make sure when its modification happened. The form that the pagoda is having now, was modified with concrete by the Japanese during the 1910s. The materials mixed in concrete were mixture of Portland cement, all sorts of stone, sand, and a little bit of new building stone, additive and compound. And also these materials were applied to cultural assets without any experiment at the time of 1910s as maintenance, which are still used recently. To prevent the change of its shape, the west side, south side and the north side which is partially destructed was rebuilt and reinforced with concrete and some of the deformed parts were also filled. The amounts of concrete used were about 200 tons. Such method had prevented the pagoda from destructing, however, by choosing a wrong repair method, its surface of the stone has secondary contaminants and precipitation caused by concrete. This kind of contamination speeds up the weathering which accelerates the aging mechanism of the stone to make it even harder to revive the absence of historical nature. Therefore, we are to find the best cleaning method to remove the secondary hazard contaminants.
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