• Membrane and Water Treatment
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• v.13 no.5
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• pp.245-257
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• 2022

Water quality characteristics and their spatial variations in the Nakdong River were statistically analyzed by multivariate techniques including correlation analysis, CA, and FA/PCA based on water quality parameters for 17 sites over 2017-2019, yielding PI values for primary factors. Site 10 indicated the highest parameter concentrations, and results of pearson's correlation analysis suggest that non-biodegradable organic matter had been distributed on the site. Five clusters were identified in order of descending pollution levels: I (Ib > Ia) > II (IIa > IIb) > III. Spatial variations started from sub-cluster Ib in which Daegu city and Geumho-river are joined. T-P, PO4-P, SS, COD, and TOC corresponded to VF 1 and 2, which were found to be principal components with strong influence on water quality. Sub-cluster Ib was strongly influenced by NO3-N and T-N compared to other clusters. According to the PIs, water quality pollution deteriorated due to non-biodegradable organic matter, nitrogen- and phosphorus-based nutrient salts in the middle and lower reaches, illustrating worsening water pollution due to inflows of anthropogenic sources on the Geumho-river, i.e., sewage and wastewater, discharged from Site 10, at which there is a concentration of urban, agricultural, and industrial areas.

• Proceedings of the Korea Water Resources Association Conference
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• 2022.05a
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• pp.475-475
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• 2022

The aim of this study is to identify the significant pollutant sources from the tributaries that are affecting the water quality of the study site, the Geum River and provide a solution to enhance the water quality. Multivariate statistical analysis modles such as cluster analysis, Principal component analysis (PCA) and positive matrix factorization (PMF) were applied to identify and prioritize the major pollutant sources of the two major tributaries, Gab-cheon and Miho-cheon, of the Geum River. PCA identifies three major pollutant sources for Gab-cheon and Miho-cheon, respectively. For Gab-cheon, wastewater treatment plant (WWTP), urban, and agricultural pollutions are identified as major pollutant sources. For Miho-cheon, agricultural, urban, and forest land are identified as major pollutant sources. On the contrary, PMF identifies three pollutant sources in Gab-cheon, same as PCA result and two pollutant sources in Miho-cheon. Water quality control scenarios are formulated and improvement of water quality in the river locations are simulated and analyzed with the Environmental Fluid Dynamic Code (EFDC) model. Scenario results were evaluated using a water quality index developed by Canadian Council of Ministers of the Environment. PCA and PMF appears to be effective to identify water pollution sources for the Geum river and also its tributaries in detail and thus can be used for the development of water quality improvement alternative of the above water bodies.

• Water for future
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• v.35 no.5
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• pp.51-59
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• 2002

In recent years the human impact on the environment becomes increasing lift threatening, calls for the better management of resources. In field of water quality of river flow, the best way to conserve water quality is specific efforts to control the pollutant loadings and treat the loadings in the basin to reduce the discharge of pollutant loadings to river. But in general the water quality influenced by the dam discharge. Especially in dry season, it is more dominant way to improve the water quality which contaminated with the pollutant loadings from the basin. The dam discharge amounts of the 2 dams in the Keum River that maintain the down stream water quality were estimated for the year of 1999, 2001, 2006, 2011, in case of irrigation and non-irrigation seasons. The pollutant loadings for the basin are estimated with the planning of treatment plants construction schedule for every sub-basins. The river flow rates were considered low flow as 2.33 year low flow and 10 year low flow. The QUAL2E model was used as a tool of simulation.

• Journal of Korean Society on Water Environment
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• v.37 no.2
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• pp.75-91
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• 2021

Ocean dumping manure was prohibited in Korea until the end of 2012. Undumped manure was treated by resourcification, purification, and public process in a facility. But poor storage of untreated manure and overproduced compost can pollute river water. In this study, linear regression, Mann-Kendall, Seasonal Mann-Kendall, LOWESS trend, and Spearman's correlation analysis were conducted for investigating the changes in the water quality of Bukhan and Imjin river before and after the prohibition of ocean dumping. In 2017, the Imjin Riv er basin had more than 5.7 times liv estock breeding heads than the Bukhan Riv er basin and more than 3.5 times livestock manure. The areas of land, farmland, and nutrient balance were also higher in the Imjin River basin. Since the two basins have different environments, it is expected that the characteristics of changes in water quality due to the increase in livestock manure generation and treatment methods will be different when comparing the water quality trends before and after the ban. The result of the trend analysis revealed a decrease in EC before the ban but an increase afterward. T-N and BOD of Imjin river increased slightly before the ban but demonstrated great enhancement thereafter. Other sites and T-P exhibited no trend. The correlation analysis result showed that the increase in the number of livestock rearing was correlated with the increase in T-P of Bukhan River and BOD of Imjin River. The increase in livestock manure production was not correlated with the Imjin River basin, while a correlation was observed with the Bukhan River with an increase in T-N and EC and the decrease in T-P.

• Journal of Korean Society of Water and Wastewater
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• v.23 no.5
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• pp.609-618
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• 2009

Repeated phenol spill in the Nakdong River has been a big issue in Korea since 1991. In this study, treatment of phenol in each water treatment process and total water treatment system is evaluated. Phenol was highly volatile, easily oxidized by ozone, and readily absorbed onto GAC. When there was phenol of 0.3mg/L in water, by ozonation of 1mg/L or by GAC adsorption with EBCT of 10minutes or longer, it could be treated to lower than 0.005mg/L, the national drinking water standard of phenol. Even when a sufficient contact time(70minutes) was allowed, only 35 to 40% of phenol could be removed by powdered activated carbon(PAC). Based on the test results, it can be concluded that 1.0mg/L or less concentration of phenol can be treated at the plants adopting the combination process of ozone and GAC down to the safe level. In this study, removal characteristics for phenol were evaluated with the existing pilot plant and demo plant in different advanced water treatment processes(AWTPs). In the future, studies on changes in oxidation and adsorption characteristics caused by competitive matters such as DOC and removal characteristics by other various AWTPs including ozone/filter adsorber need to be performed.

• Journal of Korean Society on Water Environment
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• v.18 no.3
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• pp.245-251
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• 2002

Reactive dyes waste water, a toxic and refractory pollutant, was treated by an electrochemical method using $Ti/IrO_2$ as anode and Stainless Steel 316 as cathode. In this technique, sodium chloride as an electrolyte was added. A number of experiments were run in a batch system. Artificial samples (reactive blue 19, red 195, yellow 145) were used. Operation parameters, such as supporting electrolyte concentration, current density, pH and sample concentration have been investigated for their influences on COD and color removal efficiencies during electrolysis. After 5 and 90 minites of eletrolysis, color was reduced by 51.5% and 98.9% respectively. Under the condition of current density $10A/dm^2$, NaCl concentration 12mg/l and pH 3, 62.9% of $COD_{Cr}$ was removed after electrolysis for 90 minites. The optimum condition of color removal and COD reduction in this work was found to be the following : pH 3, sodium chloride concentration 20g/l, current density $10A/dm^2$. As a result, we confirmed to be effective to color removal and reduction of refractory organic material.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1996.11b
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• pp.43-67
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• 1996

• Journal of Korean Society on Water Environment
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• v.35 no.1
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• pp.28-34
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• 2019

This study analyzed the occurrence pattern of Dolichospermum (= Anabaena) in the Bukhan river from March 2012 to December 2014 in order to identify the genotypes of Dolichospermum. Furthermore, 16S rRNA were analyzed to identify the genotypes of Dolichospermum that occurred in 2015 which were then compared to the reference sequence deposited at NCBI. During this period, the occurrence of Dolichospermum was highly correlated to water temperature. In the year 2012 and 2013, Dolichospermum appeared in Lake Cheongpyeong (CP), Sambong (SB), and Lake Paldang (P2) between July and August. However, in 2014, it appeared in SB and P2, but not in CP. This reduction in appearance was attributed to the decreased inflow to Lake Uiam as a result of low rainfall in 2014 as compared to 2012. In July 2015, the Dolichospermum 16S rRNA genotype was confirmed in five locations; Lake Cheongpyeong (CP), Seojong (SJ), Songchon Sewage Treatment Plant (SC), Joan (P4), and Lake Paldang (PD). Anabaena crassa of spiral clone, A. planctonica of linear clone, and A. circinalis of spiral clone exhibited high genetic similarity with the reference sequence. The 16r RNA genotype showed approximately 3 % sequence variation between the locations and were more similar to each other in locations that were closer.

• Journal of Environmental Science International
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• v.17 no.10
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• pp.1121-1127
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• 2008

The free-living amoeba and Acanthamoeba sp. are widely distributed in fresh water, soil, air and dust in the world. We studied distribution of amoeba from low Nakdong River(Mulgum and Maeri) and removal efficiency in water treatment process of Busan metropolitan city. During this investigation, water quality showed pH $7.4{\sim}9.6({\pm}1.1)$, water temperature $2.0{\sim}29.0({\pm}17)^{\circ}C$, turbidity $4.8{\sim}27.4({\pm}11.0)$ NTU, chlorophyll-a $10.3{\sim}109.0({\pm}44.3)\;mg/m^{3}$, BOD $1.7\sim4.9({\pm}2.6)$ mg/L, COD $3.1\sim-6.9({\pm}5.0)$ mg/L and total coliform $17\sim920({\pm}200.5)$ MPN/100 mL. The free-living amoeba were detected highly than Acanthamoeba sp., 11 out of 22 in raw water samples were positive (50%) for Acanthamoeba sp. from February 2005 to December 2005. The seasonal characteristics of tree-living amoeba and Acanthamoeba sp. in raw water were mainly distributed through the spring to the early fall. When tree-living amoeba and Acanthamoeba sp. were passed through the water treatment of pilot-plant, approximately 80% was sure to be removed through pre-ozonation, sedimentation, send filtration. 100% was removed after post-ozonation process. All of the isolated amoebas from Nakdong River were Acanthamoeba sp. AC311 18S ribosomal RNA gene with 98% nucleotide sequence homology.

• Journal of Korean Society on Water Environment
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• v.25 no.5
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• pp.720-726
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• 2009

We investigated the most effective pre-treatment processes and LC/MS/MS condition for microcystins analysis. With a step-by-step pre-treatment, efficiencies of several established methods were compared. At the level of cell burst, sonication method was found to be the most efficient. As a mycrocystins first extraction solvent, 5% acetic acid showed the highest efficiency. An isolation and recovery rate of mycrocystins of ODS Sep-Pak $C_{18}$ cartridge was higher than HLB SPE cartridge. As a final elution solvent from cartridge, 100% MeOH had a better efficiency than others. Using a LC/MS/MS, effective analytical methods were established. C18 reverse column was used and gradient elution was performed with using acetonitrile, 0.1% formic acid as a mobile phase. We analysed to 0.8 mL/min flow rate fit to the $5{\mu}m$ particle size column and $55^{\circ}C$ housing temperature. The validity of established analytical method was evaluated that MDL as average $0.050{\pm}0.014{\mu}g/L$ and LOQ as average $0.160{\pm}0.045{\mu}g/L$ had a good sensitivity over 40 magnification rather than $2{\mu}g/L$ detection limit of HPLC.