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Assessment and spatial variation of water quality using statistical techniques: Case study of Nakdong river, Korea

  • Kim, Shin (Nakdong River Environment Research Center, National Institute of Environmental Research)
  • Received : 2019.09.15
  • Accepted : 2022.08.30
  • Published : 2022.09.25

Abstract

Water quality characteristics and their spatial variations in the Nakdong River were statistically analyzed by multivariate techniques including correlation analysis, CA, and FA/PCA based on water quality parameters for 17 sites over 2017-2019, yielding PI values for primary factors. Site 10 indicated the highest parameter concentrations, and results of pearson's correlation analysis suggest that non-biodegradable organic matter had been distributed on the site. Five clusters were identified in order of descending pollution levels: I (Ib > Ia) > II (IIa > IIb) > III. Spatial variations started from sub-cluster Ib in which Daegu city and Geumho-river are joined. T-P, PO4-P, SS, COD, and TOC corresponded to VF 1 and 2, which were found to be principal components with strong influence on water quality. Sub-cluster Ib was strongly influenced by NO3-N and T-N compared to other clusters. According to the PIs, water quality pollution deteriorated due to non-biodegradable organic matter, nitrogen- and phosphorus-based nutrient salts in the middle and lower reaches, illustrating worsening water pollution due to inflows of anthropogenic sources on the Geumho-river, i.e., sewage and wastewater, discharged from Site 10, at which there is a concentration of urban, agricultural, and industrial areas.

Keywords

Acknowledgement

This research was supported by a grant from the Nakdong River Environment Research Center, National Institute of Environmental Research of Korea (NIER-2021- 01-01-042).

References

  1. Ahn, K. and Yang W.M. (2007), "Water quality characteristics in Geum river watershed", Kor. J. Limnol., 40(1), 110-120.
  2. Alves, D.D., Riegel, R.P., de Quevedo, D.M., Osorio, D.M.M, da Costa, G.M., do Nascimento, C.A. and Teloken, F. (2018), "Seasonal assessment apportionment of surface water pollution using multivariate statistical methods: Sinos river, south Brazil", Environ. Monit. Assess., 190(7), 1-12. https://doi.org/10.10067/s10661-018-6759-3.
  3. Bae, H.K. (2020), "The effect of combined sewer overflow on river's water quality", Membr. Water Treat., 11(1), 49-57. http://doi.org/10.12898/mwt.2020.11.1.049.
  4. Chang, N.B. (2005), "Sustainable water resources management under uncertainty", Stoch. Environ. Res. Risk Assess., 19(2), 97-98. https://doi.org/10.1007/s00477-004-0217-1.
  5. Choi, H.G., Han, G.Y. and Choi, S.Y. (2011), "A stochastic analysis of the quality with discharge variation in upper Nakdong river basin", J. Environ. Imp. Assess., 20(6), 833-843. https://doi.org/10.14249/eia.2011.20.6.833.
  6. Choi, K.Y., Im, T.H., Lee, J.W. and Choi, S.Y. (2012), "Evaluation of water quality characteristics in the Nakdong river using statistical analysis", J. Kor. Soc. Water Environ., 45(11), 1157-1168. https://doi.org/10.3741/JKWRA.2012.45.11.1157.
  7. Dutta, S., Dwivedi, A. and Kumar, M.S. (2018), "Use of water quality index and multivariate statistical techniques for the assessment of spatial variations in water quality of a small river", Environ. Monit. Assess., 190(12), 1-17. https://doi.org/10.1007/s10661-018-7100-x.
  8. Gwak, B.R. and Kim, I.K. (2015), "The evaluation of water quality using a multivariate analysis in Changyeong-Haman weir section", J. Kor. Soc. Water Environ., 29(6), 625-632. https://doi.org/10.11001/jksww.2015.29.6.625.
  9. Fan, X., Cui, B., Zhao, Z. and Zhang, H. (2010), "Assessment of river water quality in Pearl river delta using multivariate statistical techniques", Proc. Environ. Sci., 2, 1220-1234. https://doi.org/10.1016/j.proenv.2010.10.133.
  10. Han, S.H., Kim, E.S. and Kim, S.D. (2009), "The water quality management in the Nakdong river watershed using multivariate statistical techniques", Kor. J. Civil Eng., 13(2), 97-105. https:// doi.org/10.1007/s12205-009-0097-5.
  11. Hussain, M., Ahmed, S.M. and Abderrahman, W. (2008), "Cluster analysis and quality assessment of logged water at an irrigation project, eastern Saudi Arabia", J. Environ. Manage., 86, 279- 307. https://doi.org/10.1016/j.jenvman.2006.12.007.
  12. Imai, A., Fukushima, T., Matsushige, K, Kim, Y.H. and Choi, K. (2002), "Characterization of dissolved organic matter in effluents from wastewater treatment plants", Water Res., 34(6), 859-870. https://doi.org/10.1016/S0043-1354(01)00283-4.
  13. Iscen, C.F., Emiroglu, O., Ilhan, S., Arslan, N., Yilmaz, V. and Ahiska, S. (2008), "Application of multivariate statistical techniques in the assessment of surface water quality in Uluabat lake, Turkey", Environ. Monit. Assess., 144, 269-276. https://doi.org/10.1007/s10661-007-9989-3.
  14. Joung, S.H., Park, H.K., Lee, H.J. and Lee, S.H. (2013), "Effect of climate change for diatom bloom at winter and spring season in Mulgeum station of the Nakdong river", J. Kor. Soc. Water Environ., 29(2), 155-164.
  15. Jung, K.Y., Ahn, J.M., Lee, K.L., Lee, I.J., Yu, J.J., Cheon, S.U., Kim, K.S. and Han, G.Y. (2015), "Temporal and spatial analysis of non-biodegradable organic pollutants in the Geumho river system", J. Environ. Sci. Int., 24(11), 1343-1362. http://doi.org/10.5322.JESI.2015.24.11.1343. https://doi.org/10.5322.JESI.2015.24.11.1343
  16. Jung, K.Y., Lee, K.L., Im, T.H., Lee, I.J., Kim, S., Han, K.Y. and Ahn, J.M. (2016a), "Evaluation of water quality for the Nakdong river watershed using multivariate analysis", Environ. Tech. Inn., 5, 67-82. https://dx.doi.org/10.1016/j.eti.2015.12.001.
  17. Jung, K.Y., Ahn, J.M., Kim, S., Lee, I.J. and Yang, D.S. (2016b), "Evaluation of water quality characteristics and water quality improvement grade classification of Geumho river tributaries", J. Environ. Sci. Int., 25, 767-787. http://doi.org/10.5322/JESI.2016.25.6.767.
  18. Jung, S.Y. and Kim, I.K. (2017), "Analysis of water quality factor and correlation between water quality and Chl-a in middle and downstream weir section of Nakdong river", J. Kor. Soc. Environ. Eng., 39, 89-96. http://doi.org/10.4491/KSEE.2017.39.2.89.
  19. Jung, K.Y., Ahn, J.M., Cho, S.H., Lee, Y.J., Han, K.Y., Shin, D.S. and Kim, K.H. (2019), "Evaluation of long-term water quality management policy effect using nonparametric statistical methods", Membr. Water Treat., 10(5), 339-352. https://doi.org/10.12989/mwt.2019.10.5.339.
  20. Kappers, F.I. (1980), "The cynobaterium Microcystics Aeruginosa kg. and the nitrogen cycle of the hypertrophic lake Brielle (the Netherlands)", Hyper. Eco., 2, 37-43. https://doi.org/10.1007/978-94-009-9203-05.
  21. Kim, G.H., Jung, K.Y., Yoon, J.S. and Cheon, S.U. (2013), "Temporal and spatial analysis of water quality data observed in lower watershed of Nam river Dam", J. Kor. Soc. Hazard Mitig., 13(6), 429-437. http://doi.org/10.9798/KOSHAM.2013.13.6.429.
  22. Kim, J.I., Choi, J.W. and An, K.G. (2014), "Spatial and temporal variations of water quality in an urban Miho stream and some influences of the tributaries on the water quality", J. Environ. Sci. Int., 23(3), 433-455. https://doi.org/10.5322/JESI.2014.23.3.433.
  23. Kim, J.O. and Mueller, C.W. (1978), Introduction to Factor Analysis: What It Is and How Do It, Quantitative Applications in the Social Sciences, Sage University Press, Newbury Park, U.S.A.
  24. Kim, M.S., Chung, Y.R., Suh, E.H. and Song, W.S. (2002), "Eutrophication of Nakdong river and statistical analysis of environmental factors", Algae, 17, 105-115. http://doi.org/10.4490/Algae.2002.17.2.105.
  25. Kim, S.M., Kim, S.M. and Park, T.Y. (2010), "Spatial analysis of BOD data in Namgang-Dam watershed for TMDLs", J. Kor. Soc. Agric. Eng., 52(3), 81-88.
  26. Kim, S.R. and Kim, S.M. (2017), "Spatial water quality analysis of main stream of Nakdong river considering the inflow of tributaries", J. Kor. Soc. Water. Environ., 33(6), 640-649. https://doi.org/10.15681/KSWIE2017.33.6.640.
  27. Kolovos, A., Christakos, G., Serre, M.L. and Miller, C.T. (2002), "Computational Bayesian maximum entropy solution of a stochastic advection reaction equation in the light of site- spectific information", Water Resour. Res., 38(12), 1318-1334. https://doi.org/10.1029/2001WR000743.
  28. Kowalkowski, T., Zbytniewski, R., Szpejna, J. and Buszewski, B. (2006), "Application of chemometrics in river water classification", Water Res., 40, 744-752. http://doi.org/10.1016/j.waters.2005.11.042.
  29. Kuppusamy, M.R. and Giridhar, V.V. (2006), "Factor analysis of water quality characteristics including trace metal speciation in the coastal environmental system of Chennai Ennore", Environ. Int., 32, 174-179. https://doi.org/10.1016/j.envint.2005.08.008.
  30. Kumari, M., Tripathi, S., Pathak, V. and Tripathi, B.D. (2013), "Chemometric characterization of river water quality", Environ. Monit. Assess., 185, 3081-3092. https://doi.org/10.1007/s10661-012-2774-y.
  31. Lee, H.J., Park, H.K., Lee, J.H., Park, A.R. and Cheon, S.U. (2016), "Coliform pollution status of Nakdong river and tributaries", J. Kor. Soc. Water Waste, 32(3), 271-280. https://doi.org/10.15681/KSWE.2016.32.3.271.
  32. Lee, S.M. and Kim, I.K. (2017), "Analysis of correlation between cyanobacterial population and water quality factors in the middle and downstream region of Nakdong river", J. Kor. Soc. Water Waste, 31, 93-101. http://doi.org/10.11001/jksww.2017.31.1.093.
  33. Liu, C.W., Lin. K.H., and Kuo, Y.M. (2003), "Application of factor analysis in the assessment of ground water quality in a blackfoot disease area in Taiwan", Sci. Total Environ., 313(1), 77-89. https://doi.org/10.1016/s0048-9697(02)00683-6.
  34. Mckenna, J.E. (2003), "An enhanced cluster analysis program with bootstrap significance testing for ecological community analysis", Environ. Model Soft., 18(3), 205-220. https://doi.org/10.1016/S1364-8152(02)00094-4.
  35. Ministry of Environment (MOE) (2012), Official Test Methods of Water Quality, MOE, Sejong, Korea.
  36. Ma, X., Wang, L., Yang, H., Li, N. and Gong, C. (2020), "Spatiotemporal analysis of water quality using multivariate statistical techniques and the water quality identification index for the Qinhuai river basin, China", Warter, 12(10), 2764-2783. https://doi.org/10.3390/w12102764.
  37. Na, E.H., Park, S.Y., Kim, J.H., Im, S.S. and Kim, K.H. (2015), "A study on spatial and temporal patterns of water quality the middle area of the Nakdong river", J. Kor. Soc. Water Environ., 31(6), 723-731. http://doi.org/10.15681/KSWE.2015.31.6.723.
  38. Na, S.M., Kwon, H.G., Shin, S.M., Son, Y.G., Shin, D.S. and Im, T.H. (2016), "A study on seasonal pollutant distribution characteristics of contaminated tributaries in Nakdong river basin", J. Wetland Res., 18, 301-312. http://doi.org/10.17663/JWR.2016.18.3.301.
  39. Otto, M. (1998), Multivariate Methods In: Analytical Chemistry. Wiley/VCH, Weinheim, Getmany.
  40. Ouyang, Y., Nkedi-kizza, P., Wu, Q.T., Shinde, D. and Huang, C.H. (2006), "Assessment of seasonal variations in surface water quality", Water Res., 39, 2621-2635. https://doi.org/10.1016/j.water.2006.08.030.
  41. Park, J.H., Jung, J.W., Kim, D.Y., Kim, K.S., Han, S.W., Kim, H.O. and Lim, B.J. (2013), "Water quality characteristics of the major tributaries in Yeongsan and Sumjin river basin using statistical analysis", J. Environ. Imp. Assess., 22(2), 171-181. https://doi.org/10.14249/eja.2013.22.2.171.
  42. Pekey, H., Karakas, D. and Bakoglu, M. (2004), "Source apportionment of trace metals in surface waters of a polluted stream using multivariate statistical analyses", Mar. Pollut. Bull., 49(9-10), 809-818. https://doi.org/10.1016/j.marpolbul.2004.06.029.
  43. Razmkhah, H., Abrishamchi, A., Torkian, A. (2010), "Evaluation of spatial and temporal variation in water quality by pattern recognition techniques: A case study on Jajrood river (Tehran, Iran)", J. Environ. Manage., 91, 852-860. https://doi.org/10.1016/j.jenvman.2009.11.001.
  44. Ren, W., Zhong, Y., Meligrana, L., Anderson, B., Watt, W.E., Chen, J. and Leung, H.L. (2003), "Urbanization, land use, and water quality in Shanghai 1947-1996", Environ. Int., 29(5), 649-659. https://doi.org/S0160-4120(03)00051-5. https://doi.org/10.1016/S0160-4120(03)00051-5
  45. Seo, J.K., Lee, H.K. and Chung, I.K. (2010), "The community dynamics of microbial food web during algal blooms by Stephanodiscus spp. in downstream of Nakdong river", Kor. J. Environ. Bio., 28(3), 172-178.
  46. Seo, M.J., Lee, H.J., and Kim, Y.S. (2019), "Relationship between coliform bacteria and water quality factors at weir stations in the Nakdong river, South Korea", Warter, 11(6), 1171-1187. https://doi.org/10.3390/w11061171.
  47. Shrestha, S. and Kazama, F. (2007), "Assessment of surface water quality using multivariate statistical techniques: A case study of the Fuji river basin, Japan", Environ. Model Soft., 22, 464-475. https://doi.org/10.1016/j.envsoft.2006.02.001.
  48. Simeonov, V., Stratis, J.A., Samara, C., Zachariadis, G., Voutsa, D., Anthemidis, A., Sofoniou, M. and Kouimatzis, T. (2003), "Assessment of the surface water quality in Northern Greece", Water Res., 37, 4119-4124. https://doi.org/10.1016/S0043-1354(03)00398-1.
  49. Singh, K.P., Malik, A., Mohan, D. and Sinha, S. (2005), "Water quality assessment and apportionment of pollution sources of Gomti river (India) using multivariate statistical techniques - a case study", Anal. Chim. Acta., 538, 355-374. https://doi.org/10.1016/j.aca.2005.02.006.
  50. Suh, M.J., Cho, C.D., Im, T.H., Kim, S.H., Yoon, H.J., Kim, Y.S. and Kim, G.H. (2019), "Statistical analysis of the spatio- temporal water quality characteristics of the Nakdong river", J. Environ. Sci. Int., 28(3), 303-320. https://doi.org/10.5322/JESI.2019.258.3.303.
  51. Su, S., Li, D., Zhang, Q., Xia, R., Huang, F. and Wu, J. (2011), "Temporal trend and source apportionment of water pollution in different functional zones of Qiantang river, China", Water Res., 45(4), 1781-1795. https://doi.org/10.1016/j.waters.2010.11.030.
  52. Vega, M., Pardo, R., Barrado, E., Deban, L. (1998), "Assessment of seasonal and polluting effects on the quality of river water by exploratory data analysis", Water Res., 32, 3581-3592. https://doi.org/10.10161/S0043-1354(98)00138-9.
  53. Venkatraman, S., Chung, S.Y., Lee, S.Y. and Park, N. (2014), "Assessment of river water quality via environmentric multivariate statistical tools and water quality index: A case study of Nakdong river basin, Korea", Carpa. J. Ear. Environ. Sci., 9(2), 125-132.
  54. Wang, H.Y. (2002), "Assessment and prediction of overall environmental quality of Zhuzhou city, human province, China", J. Environ. Manag., 66(3), 329-340. https://doi.org/10.1006/jema.2002.0590.
  55. Wang, J., Da, L., Song, K. and Li, B. (2008), "Temporal variations of surface water quality in urban, suburban, and rural areas during rapid urbanization in Shanghai, China", Environ. Poll., 152(2), 387-393. https://doi.org/10.1016/j.envpol.2007.06.050.
  56. Wunderlin, D.A., Daiz, M.P., Ame, M.V., Pesce, S.F., Hued, A.C. and Bistoni, M.A. (2001), "Pattern recognition techniques for the evaluation of spatial and temporal variations in water quality, a case study: Suquira river basin (Cordoba-Argentina)", Water Res., 35, 1894-2881. https://doi.org/10.1016/s0043-1354(00)00592-3.
  57. Xian, G., Crane, M. and Junshan, S. (2007), "An analysis of urban development and its environmental impact on the Tampa bay watershed", J. Environ. Manag., 85(4), 965-976. https://doi.org/10.1016/j.jenvman.2006.11.012.
  58. Yang, L., Mei, K. Liu, X., Wu, L., Zhang, M., Xu, J. and Wang, F. (2013), "Spatial distribution and source apportionment of water pollution in different administrative zones of Wen-Rui-Tang (WRT) river watershed, China", Environ. Sci. Pollut. Res., 20, 5341-5352. https://doi.org/10.1007/s11356-013-1536-x.
  59. Yang, Y.H., Zhou, F. Guo, H.C., Sheng, H., Liu, H., Dao, X. and He, C.J. (2010), "Analysis of spatial and temporal water pollution patterns in lake Dianchi using multivariate statistical methods", J. Environ. Manag., 85(4), 965-976. https://doi.org/10.1016/j.jenvman.2006.11.012.
  60. Yoon, H.Y., Kim, J.H., Chae, M.H., Cho, Y.H. and Cheon, S.U. (2019), "Assessment of water quality in the Miho stream using multivariate statistics", J. Environ. Impact. Assess., 28(4), 373-386 https://doi.org/10.14249/eia.2019.28.4.373.
  61. Zeng, X. and Rasmussen, T.C. (2005), "Multivariate statistical characterization of water quality in lake Lanier, Georgia, USA", J. Environ. Qual., 34, 1980-1991. https://doi.org/10.2134/jeq2004.0337.
  62. Zhang, Y., Guo, F., Meng, W. and Wang, X.Q. (2009), "Water quality assessment and source identification of Daliao river basin using multivariate statistical methods", Environ. Monit. Assess., 170, 407-416. https://doi.org/10.1007/s10661-009-1242-9.
  63. Zhou, F., Liu, Y., Guo, H.C. (2006), "Application of multivariate statistical methods to water quality assessment of the watercourses in Northwestern New Territories, Hong Kong", Environ. Monit. Assess., 132, 1-13. https://doi.org/10.1007/s10661-006-9497-x.