• 폴리머
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• 제33권5호
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• pp.458-462
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• 2009

본 연구에서는 순차적 음이온 및 개환중합반응을 통해 ABC 형태의 폴리스티렌-폴리에틸렌옥사이드-폴리락티드 블록공중합체를 성공적으로 합성하였다. 우선, 첫번째 블록인 폴리스티렌을 합성하기 위해서, 사이클로헥산 용매에서 스티렌/이차-부틸리튬을 각각 단량체/개시제로 사용하여 음이온중합(anionic polymerization)을 수행하였고, 이후 고분자 말단을 수산기로 전환시키기 위해, 에틸렌옥사이드를 첨가하였다. 다음 단계로 포타슘 나프탈레나이드(potassium naphthalenide)를 이용하여 폴리스티렌 말단 수산기의 수소를 제거하여, 거대개시제인 PS-$O^-K^+$를 제조하였다. 준비된 거대 개시제에 정량된 에틸렌옥사이드를 첨가하여, 음이온중합을 수행하였다. 폴리락티드 블록을 도입시키는 개환중합의 경우, THF 용매에서 트리에틸알루미늄(triethylaluminum)/피리딘(pyridine)시스템을 이용하여 PS-b-PEO-$AlEt_2$ 형태의 거대개시제를 형성한 후, $90^{\circ}C$에서 중합을 수행하였다. 합성된 블록공중합체를 수소핵자기공명법 및 겔침투크로마토그래피 방법을 통해 조사한 결과, 잘 정의된 분자량 및 낮은 분자량 분포를 나타냄을 확인할 수 있었다.

• 청정기술
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• 제12권2호
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• pp.62-66
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• 2006

다양한 폴리디메틸실록산계 공중합체를 안정화제로 이용하여 초임계 이산화탄소 내에서의 개환중합을 통해 PLLA를 제조하였다. 초임계 개환중합에 사용된 폴리디메틸실록산 공중합체는 폴리디메틸실록산 거대개시제를 사용하여 그룹전이중합법(GTP법)을 이용하여 제조하였다. $\small{L}$-락타이드의 초임계 현탁중합을 통해 수미크론크기의 입자가 형성되었음을 전자 주사 현미경을 통해 확인하였고, 또한 겔 투과 크로마토 그라피 분석을 통해 상당히 좁은 분자량 분포의 PLLA가 제조되었음을 확인하였다.

• Composites Research
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• 제32권6호
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• pp.375-381
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• 2019

Multiwalled carbon nanotubes (MWCNTs) are covalently functionalized with isocyanates by directly reacting commercial hydroxyl functionalized MWCNTs with excess 4,4'-methylenebis (phenyl isocyanate) (MDI) and hexamethylene diiosocyanate (HDI). HDI-modified MWCNTs results in a higher surface isocyanate density than MDI-modified MWCNTs. Anionic ring-opening polymerization of ε-caprolactam is conducted using a sodium caprolactam initiator in combination with a di-functional hexamethylene-1,6-dicarbamoylcaprolactam activator in the presence of isocyanate functionalized MWCNTs. This polymerization proceeds in a highly efficient manner at relatively low reaction temperature (150℃) and short reaction times (10 min). During the polymerization, the isocyanate functionalized MWCNTs act not only as reinforcing fillers but also as second activators. Nanocomposites with HDI modified MWCNTs exhibit higher reinforcement and faster isothermal crystallization than MDI modified MWCNTs. The results show that PA6 chains grow more effectively from HDI modified MWCNT surface than from MDI modified MWCNT surface, resulting in stronger interaction between PA6 and MWCNTs.

• Bulletin of the Korean Chemical Society
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• 제33권12호
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• pp.4122-4126
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• 2012

Cellulose-graft-poly (L-lactide) (cellulose-g-PLLA) was successfully prepared via ring-opening polymerization (ROP) by using 4-dimethylaminopyridine (DMAP) as an organic catalyst in an ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl). The structure and morphology of the polymer was characterized by nuclear magnetic resonance (NMR) and transmission electron microscope (TEM). From wide-angle X-ray powder diffraction (WAXD) and degradation test (by acid, alkaline, PBS and enzyme solution), changes in the crystalline structure as a result of degradation was also investigated. The results indicated that materials which have low degree of crystallinity showing higher degradability, however, in acid liquor, enzyme solution, alkaline liquor and PBS system, the degradation rate of the polymer decreased by the above sequence. Moreover, with the further increase of graft degree of this material, its degradation degree decreased.

• Macromolecular Research
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• 제16권2호
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• pp.155-162
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• 2008

We report the successful synthesis of poly(NBECOOH-b-NBEPOSS) copolymers, taking advantage of the sequential, living ring opening metathesis polymerization of NBETMS and NBEPOSS using the $RuCl_2(=CHPh)(PCY_3)_2$/$CH_2Cl_2$/$20^{\circ}C$ system, followed by the hydrolysis of trimethylsilyl groups in poly(NBETMS-b-NBEPOSS) copolymers. The living behavior of ROMP of NBETMS was first investigated using two diagnostic plots, a first order kinetic plot and a $\bar{M}_n$ vs. conversion plot. The plots confirmed that no termination and chain transfer reaction had occurred during polymerization. Poly(NBECOOH-b-NBEPOSS) copolymers were prepared using the sequential monomer addition of NBEPOSS to living poly(NBETMS) chain ends, followed by the hydrolysis of trimethylsilyl groups in the poly(NBETMS-b-NBEPOSS) copolymers. The high structural integrity of poly(NBE-COOH-b-NBEPOSS) copolymers was confirmed by $^1H$-NMR, $^{13}C$-NMR spcctroscopy and GPC.

• Bulletin of the Korean Chemical Society
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• 제33권1호
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• pp.76-82
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• 2012

A novel and efficient tetrahydrofuranyl ring opening method was developed using the highly reactive TFAT reagent in the presence of an acid scavenger, 2,6-di-tert-butyl-4-methylpyridine. Various acid sensitive groups are compatible with the reaction condition, making it generally applicable to many tetrahydrofuranyl steroids. Moreover, it is a synthetic equivalent of 'Marker degradation' affording an efficient synthesis of C17-OH rockogenin acetate.

• Bulletin of the Korean Chemical Society
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• 제32권8호
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• pp.2737-2742
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• 2011

Ring-opening metathesis polymerization (ROMP) of an ethyl-substituted tetracyclododecene (8-ethyltetracyclo[$4.4.0.1^{2,5}.1^{7,10}$] dodec-3-ene, Et-TCD) was carried out in the presence of a ternary catalyst system consisting of $WCl_6$, triisobutyl aluminium (iso$Bu_3Al$), and ethanol. The optimal molar ratio of Et-TCD/$WCl_3$/iso-$Bu_3Al$/ethanol was found as 500/1/3/2 at which the yield of ring-opened polymer was 100%. 1-Hexene was shown to be an effective molecular weight controlling agent for ROMP reaction of Et-TCD. The hydrogenation of the ring opened polymer (p-Et-TCD) was conducted successfully using Pd(5 wt %)/${\gamma}$-$Al_2O_3$ at $80^{\circ}C$ for 1 h. Chemical structures of p-Et-TCD and its hydrogenated product($H_2$-p-Et-TCD) were characterized using 2D NMR techniques ($^1H-^1H$ COSY and $^1H-^{13}C$ HSQC). The changes of physical properties such as thermal stability, glass transition temperature and light transmittance after the hydrogenation were also investigated using TGA, DSC, and UV.

• Bulletin of the Korean Chemical Society
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• 제35권8호
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• pp.2573-2576
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• 2014

• Bulletin of the Korean Chemical Society
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• 제29권11호
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• pp.2089-2090
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• 2008

• 멤브레인
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• 제25권4호
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• pp.332-342
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• 2015

본 연구는 역삼투막의 막오염을 해결하기 위하여 실란-에폭시 층을 형성시킨 다층 표면개질법을 이용하여 역삼투막의 내오염성을 향상시키고자 하였다. Sol-gel법을 이용하여 Octyltrimethoxysilane (OcTES)을 막 표면에 가교를 통해 고분자화 하였으며 n = 8인 OcTES의 알킬기가 자발적인 self-assembly를 통하여 막 표면에 가지구조를 형성시켰다. 그 위에 ethylene glycol diglycidyl ether (EGDE)의 ether기를 ring-opening을 통해 막 표면에 친수성을 부여하여 역삼투막의 내오염성을 향상시키고자 하였다. FE-TEM, AFM을 이용하여 막의 단면 및 표면구조 분석을 하였고 막 표면의 ridge and valley 구조와 OcTES, EGDE의 다층 표면개질로 인한 bridge 구조를 확인하였으며, 거칠기의 증가를 통해 막 표면의 가지가 잘 형성되었음을 확인하였다. XPS를 통하여 막 표면의 화학구조에 대한 관찰과 표면개질이 잘 이루어졌음을 확인하였으며, contact angle 분석을 통해 표면개질막의 표면에 친수성이 부여되었음을 확인하였다. EGDE 표면개질 조건 최적화를 진행한 결과 EGDE 농도는 0.5 wt%, ring-opening 온도는 $70^{\circ}C$가 가장 적합하였고, 내오염성 실험 결과 및 막오염지수(MFI)는 SUL-H10, $PA-OcTES_{1.0}$, $PA-OcTES_{1.0}-EGDE_{0.5}$이 68.7, 60.4, 5.4 ($10E-8hr/mL^2$)로 나타나 다층 표면 개질막의 내오염성이 매우 향상되었음을 확인할 수 있었다.