• Title/Summary/Keyword: Rich-lean

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Study of NO Storage and Reduction on LNT by Micro Bench-Flow Reactor (마이크로 벤치-플로우 리액터를 이용한 LNT 촉매의 NO 흡장과 정화성능에 관한 연구)

  • Yoon, Joo-Wung;Hwang, Seung-Kwon;Hwang, In-Goo;Park, Sim-Soo;Lee, Jin-Ha;Yeo, Gwon-Koo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.8
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    • pp.789-798
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    • 2011
  • We carry out an experimental investigation to analyze the basic performance of NO(nitric oxide) storage in a lean phase and also analyze the NO reduction achieved by the spraying of reducing agents in the rich phase of the exhaust gas in an LNT(Lean NOx Trap). This is an after-treatment system used to reduce the NOx emissions from a diesel engine. If the stored NO is reduced, we measure the outlet concentration downstream of the LNT. The test LNT material used in the experiments is commercial LNT. After being canned into stainless-steel(SUS304), it was built in a micro bench-flow reactor. Compositions of feed gases, three heated and three no heated gases were sprayed upstream of the LNT to analyze the characteristics. We use various temperatures and space velocities as response variables.

Characteristics of NOx Reduction on NSR(NOx Storage and Reduction) Catalyst Supported by Ni, Ru-ZSM-5 Additives (Ni, Ru-ZSM-5를 첨가한 NSR 촉매의 NOx 정화 특성)

  • Choi, Byung-Chul;Lee, Choon-Hee;Jeong, Jong-Woo
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.5
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    • pp.105-111
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    • 2007
  • In this study, we investigated the conversion performance of de-NOx catalyst for lean-burn natural gas engine. As a de-NOx catalyst, NOx storage reduction catalyst was composed of Pt, Pd and Rh with washcoat including Ba and Ni, Ru-ZSM-5. Ni, Ru-ZSM-5, which was regarded as a NOx direct decomposition catalyst, was made up of ion exchanged ZSM-5 by 5wt.% Ni or Ru. The performance of de-NOx catalyst was evaluated by NOx storage capacity and catalytic reduction in air/fuel, $\lambda=1.6$. The catalytic reaction was also observed when the added fuel was supplied to fuel rich atmosphere by fuel spike period of 5 seconds. The NOx conversion of the catalysts with Ni-ZSM-5 or Ru-ZSM-5 was mainly caused by the effect of NOx adsorption of Ba rather than the catalytic reduction of Ni, Ru-ZSM-5. Ni, Ru-ZSM-5 catalysts can not use for the NSR catalyst because they have quick process in thermal deactivation.

Feasibility of a methane reduced chemical kinetics mechanism in laminar flame velocity of hydrogen enriched methane flames simulations

  • Ennetta, Ridha;Yahya, Ali;Said, Rachid
    • Advances in Energy Research
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    • v.4 no.3
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    • pp.213-221
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    • 2016
  • The main purpose of this work is to test the validation of use of a four step reaction mechanism to simulate the laminar speed of hydrogen enriched methane flame. The laminar velocities of hydrogen-methane-air mixtures are very important in designing and predicting the progress of combustion and performance of combustion systems where hydrogen is used as fuel. In this work, laminar flame velocities of different composition of hydrogen-methane-air mixtures (from 0% to 40% hydrogen) have been calculated for variable equivalence ratios (from 0.5 to 1.5) using the flame propagation module (FSC) of the chemical kinetics software Chemkin 4.02. Our results were tested against an extended database of laminar flame speed measurements from the literature and good agreements were obtained especially for fuel lean and stoichiometric mixtures for the whole range of hydrogen blends. However, in the case of fuel rich mixtures, a slight overprediction (about 10%) is observed. Note that this overprediction decreases significantly with increasing hydrogen content. This research demonstrates that reduced chemical kinetics mechanisms can well reproduce the laminar burning velocity of methane-hydrogen-air mixtures at lean and stoichiometric mixture flame for hydrogen content in the fuel up to 40%. The use of such reduced mechanisms in complex combustion device can reduce the available computational resources and cost because the number of species is reduced.

Modeling of Laminar Burning Velocities for Hydrocarbon and 7ethanol Fuels by Using Detailed Chemical Reaction Mechanisms (상세화학반응기구를 이용한 탄화 수소 및 메탄을 층류 화염 속도 모델링)

  • Bae, Sang-Su;Min, Gyeong-Deok
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.10
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    • pp.1303-1310
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    • 2001
  • In order to be applicable to the combustion modelling of stratified charged combustion like that of - lean burn and GDI engine, the correlations of laminar burring velocities fur several hydrocarbon fuels and methanol are needed over a wide range of equivalence ratio, pressure and temperature. In this study, these correlations are modeled in the 1311owing form based on the experimental and Muller\`s modeling results for several fuels, where $\alpha$, ξ, and ξ are functions of pressure and temperature, $S_{L}$ =$\alpha$ exp[-ξ($\Phi$-$\Phi$$_{m}$)$^{2}$ -exp {-ζ($\Phi$-$\Phi$$_{m}$)}-ζ($\Phi$-$\Phi$$_{m}$)]. By using the results calculated by PREMIX code with Sloane\`s detailed chemical reaction mechanism for propane, it is verified that the coefficients of the abode modeling can be determined by considering laminar burning velocity data only in a range of equivalence ratio less than $\Phi$$_{m}$. Therefore, Muller\`s modeling results can be adopted leer modeling of the pressure and temperature dependency. Compared with the results of the existing Keck'and Gulder's models, those of the present one showed the good agreement of the recent experimental data, especially in the range of lean and rich sides.s.des.s.

A Study on the Full Load Performance and Emission Characteristics with Turbo-charger Change in a HCNG Engine (HCNG 엔진의 터보차저 변경에 따른 전부하 출력 및 배출가스 특성 연구)

  • Park, Cheolwoong;Kim, Changgi;Lim, Gihun;Lee, Sungwon;Choi, Young;Lee, Sunyoup
    • Journal of the Korean Institute of Gas
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    • v.17 no.5
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    • pp.8-14
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    • 2013
  • Hydrogen-natural gas blends(HCNG) engine is optimizing technology of performance and emission characteristics with use of hydrogen's fast flame speed and wide flammability limit. As lean-burn limit is extended, the improvement in thermal efficiency and harmful emissions can be achieved. However, the extension of lean-burn limit under a wide open throttle operation point could be realized with the increase in boosting capacity in a lean-burn engine with turbo-charging system. In the present study, the power output characteristics of HCNG engine with turbo-charger change is assessed and feasibility of the increase in boosting capacity is evaluated. The turbo-charger design with high efficiency at higher flow rate rather than higher boosting pressure makes efficient operation possible at relatively rich mixture condition.

An Experimental Study of Petroleum Cokes Air Staged Burner (공기다단 적용 석유코크스 연료 전용 연소기에 대한 실험적 연구)

  • Kwon, Minjun;Lee, Changyeop;Kim, Sewon
    • Journal of the Korean Society of Combustion
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    • v.20 no.2
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    • pp.40-45
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    • 2015
  • This study is aimed to study combustion characteristics of low $NO_X$ burner using petroleum cokes as fuel. The petroleum coke, which is produced through the oil refining process, is an attractive fuel in terms of its high heating value and relatively low price. But petroleum coke is a challenging fuel because of its low volatile content, high sulfur and nitrogen content, which give rise to undesirable emission characteristics and low ignitability. The petroleum cokes burner is operated at fuel rich condition, and overfire air are supplied to achieve fuel lean condition. The low $NO_X$ burner is designed to control fuel and air mixing to achieve air staged combustion, in addition secondary and tertiary air are supplied through swirler. Air distribution ratio of triple staged air are optimized experimentally. The result showed that $NO_X$ concentration is lowest when overfire air is used, and the burner function at a fuel rich condition.

A Study on the Emission Characteristics of Syngas(H2/CO)-Air Premixed Flame according to the H2 contents (수소 함유량에 따른 합성가스(H2/CO)-공기 예혼합 화염의 배출특성 연구)

  • Jeong, Byeong;Choi, Jongmin;Lee, Keeman
    • 한국연소학회:학술대회논문집
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    • 2013.06a
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    • pp.9-10
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    • 2013
  • This study reports the results of an experimental investigation of emission and temperatures from the syngas-air premixed flame with a various mixture composition in the region of large equivalence ratios. The effects of hydrogen contents and equivalence ratios on the flame velocity, which reported before, and emission of syngas fuel are examined. In this study, representative syngas mixture compositions ($H_2:CO$) such as $H_2:CO=10:90$, 25:75, 50:50 and 75:25 and equivalence ratios from 0.5 to 5.0 have been conducted. The emissions of syngas fuel were measured by the high precision analyzer with enclosure configuration and the adiabatic temperatures are calculated by used Chemkin basis. The NOx emission level is coincided relatively well with the adiabatic temperature distributions in lean mixture conditions, but for rich mixture conditions NOx level was also increased again even though the adiabatic temperature decreases. Such an increasing characteristics in rich mixture conditions is coincided well with the tendency that rather the flue gas temperature increases.

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Research on the Low-Frequency Combustion Characteristics of an Oxygen-Rich Preburner (산화제 과잉 예연소기 저주파 연소특성 연구)

  • Moon, Insang;Moon, Ilyoon;Ha, Seong-Up
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.1
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    • pp.89-96
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    • 2013
  • Combustion pressures were measured to study combustion stability for an oxygen rich preburner by both of static and dynamic pressure sensors. The resolutions of each static and dynamic pressure sensor are the 1,000 Hz and 25,600 Hz, respectively. The nominal combustion pressure of the preburner was 200 bar but 80 bar was used at the several initial tests for the safety reason. Two stage ignition was applied to reduce the ignition impact for every tests including the tests with 200 bar combustion pressure. The tests lasted for 10 sec. max. and a little fluctuations of pressure was observed during the main mode. The measured pressures were studied by FFT analysis and no noticeable frequency coupling was found. Thus the preburner can be regarded as stable and it can be utilized for further study on staged combustion cycle liquid rocket engine.

Effect of Injection Pressure and Injection Timing on Spray and Flame Characteristics of Spray-Guided Direct-Injection Spark-Ignition Engine under Lean Stratified Combustion Operation (성층희박연소 운전조건에서 분사시기에 따른 분무유도식 직접분사 가솔린엔진의 분무 및 화염특성)

  • Oh, Heechang;Lee, Minsuk;Park, Jungseo;Bae, hoongsik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.3
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    • pp.221-228
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    • 2013
  • An experimental study was carried out to investigate the effects of the injection timing on the spray and combustion characteristics in a spray-guided direct-injection spark-ignition (DISI) engine under lean stratified operation. An in-cylinder pressure analysis, exhaust emissions measurement, and visualization of the spray and combustion were employed in this study. The combustion in a stratified DISI engine was found to have both lean premixed and diffusion controlled flame combustion characteristics. The injection timing condition corresponding to the stratified mixture characteristics was verified to be a dominant factor for these flame characteristics. For the early injection timing, a non-luminous blue flame and low combustion efficiency were observed as a result of the lean homogeneous mixture formation. On the other hand, a luminous sooting flame was shown at the late injection timing because of an under-mixed mixture formation. In addition, the smoke emission and incomplete combustion products were increased at the late injection timing as a result of the increased locally rich area. On the other hand, the NOx emissions decreased and IMEP increased as the injection timing retarded. The combustion phasing produced by the injection timing was verified as the reason for this observation.

Measurement and Analysis of Knock for Rapid Throttle Opening in SI Engines (가솔린 엔진에서 급가속 운전시 노킹 측정 및 분석)

  • 이종화;박경석;김현용
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.9
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    • pp.28-35
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    • 1999
  • In this study, investigation of transient knock characteristics in a spark-ignition engine has been carried out. The universal knock threshold values were found by a DFDD method and a NSDBP method which is a non-dimensional version of the SDBP method. Also modified NSDBP method could be used for transient knock detection. In a commercial ECU , spark timing was retarded from the steady -state spark timing during rapid throttle opening to avoid uncomfortable feeling and knock. Knock usually occurred just after the start of rapid throttle opening when spark timing was set, as values for the steady state condition. We found that air/fuel ratio deeply involved with the knock during transient condition. Due to the difference of initial heat release rate, knock occurred more easily at rich air/fuel ratio than at lean air/fuel ratio.

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