• Title/Summary/Keyword: Rhodamine 6G

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A study on Enhancement Effectiveness of Cyanoacrylate Fumed Fingermark by the Solvent of Rhodamine 6G (Rhodamine 6G 용매에 따른 CA 훈증 지문 증강 효과에 관한 연구)

  • Shim, Yea-Ra;Yu, Je-Seol
    • The Journal of the Korea Contents Association
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    • v.17 no.7
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    • pp.294-302
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    • 2017
  • In this study, latent fingermarks deposited in porous or non-porous surface was developed by cyanoacrylate fuming, and then the developed fingermark is enhanced by using Rhodamine 6G. Between water-based R6G and organic solvent-based R6G, author studied about which material have higher effectiveness in enhancing fingermark. In all seven types of surfaces depositing fingermark, water-based R6G have higher effectiveness in enhancing fingermark and lower surface coloring than organic solvent-based R6G. But because the surfaces found in crime scene have multicolor background and various quality, the additional study about various surfaces is needed.

Output Enhancement of Rhodamine 6G Dye Laser by Rhodamine 560 Energy Transfer Dye (Rhodamine 560을 이용한 rhodamine 6G 색소 레이저의 출력 증가)

  • 장원권;이민희
    • Korean Journal of Optics and Photonics
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    • v.5 no.2
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    • pp.266-271
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    • 1994
  • The output power and the energy of Rh-6G dye laser were enhanced by the mixture of Rh-560 dye whose fluorescence spectrum was coincident with the absorption spectrum of Rh-6G. The argon filled coaxial flashlamp used for pulsed pumping and argon laser for CW pumping. The concentration of Rh-6G dye was optimized in each pumping method before Rh-560 dye was mixed in Rh-6G dye solution. In the coaxial flash lamp pumped Rh-6G laser the output energy was increased about 30% when Rh-560 was mixed at 1% of Rh-6G concentration. In the case of argon laser pumping with multiline, the output power was increased 18% at the concentration of 2.5%. In the single line laser pumping, the output power was enhanced more efficiently. The power enhancements were 72% and 88% when the pumping wavelengths were 488 nm and 514.5 nm respectively. ively.

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Rhodamine 6G Based New Fluorophore Chemosensor Toward Hg2+

  • Son, Young-A;Park, June-Min
    • Textile Coloration and Finishing
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    • v.24 no.3
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    • pp.158-164
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    • 2012
  • Rhodamine dyes belong to xanthene family has excellent photostability and photophysical properties. In rhodamine dyes, Rhodamine 6G and its precursors also have xanthene chromophore and it shows high fluorescent quantum yield. Rhodamine 6G derivates are simple to synthesis and its high sensitivity and water solubility are suitable as good chemosensor. In this regard, Rhodamine 6G derivates which have selectivity to specific metal cation can used to detect various heavy metal ions. In this study, rhodamine 6G derivatives were synthesized by reaction of rhodamine 6G hydrazide and glyoxal and 4-phenyl thiosemicarbazide and it showed colorimetric and fluorescence sensing toward $Hg^{2+}$ ion. This novel chemosensor was analyzed and measured on UV-Vis and fluorescence spectrophotometer. HOMO/LUMO values were also calculated by computational calculation.

Fluorescent Enhancement of Bloody Fingermarks Deposited on Dark non-porous Surfaces (어두운 비다공성 표면에 유류된 혈지문 형광 증강에 관한 연구)

  • Kim, Ji-Yeon;Kim, Chae-Won;Kim, Ju-Eun;Yu, Je-Seol
    • The Journal of the Korea Contents Association
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    • v.18 no.2
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    • pp.124-131
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    • 2018
  • This study aimed to compare effectiveness of fluorescent reagents for enhancing blood such as acid yellow 7, rhodamine 6G, eosin Y. AY7 and eosin Y have been introduced in Korea as fluorescent reagents for enhancing blood, but not rhodamine 6G. In this study, researchers photographed when each reagents gave the most effective results. Consequently, rhodamine 6G was superior to the others. Eosin Y enhanced bloody fingermarks weakly compared to AY7 and rhodamine 6G. Furthermore, the more depletion trials were done, the less effectiveness were shown. Therefore, researchers recommended that crime scene investigators try to use rhodamine 6G fluorescent reagents for enhancing blood.

Study for energy transfer from Rhodamime 6G to Rhodamine B using time correlated single photon counting method (시간 상관 단일 광자 계수법에 의한 Rhodamine 6G에서 Rhodamine B로의 에너지 전달에 관한 연구)

  • 엄효순
    • Proceedings of the Optical Society of Korea Conference
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    • 1991.06a
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    • pp.69-73
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    • 1991
  • 모드 동기된 아르곤 이온 레이저를 여기광원으로 사용한 시간상관 단일 광자 계수장치를 이용하여 에탄올 용액 내에서 Rhodamine 6G에서 Rhodamine B로의 에너지 전달에 관하여 연구하였다. 측정된 형광 소멸 곡선은 본 실험실에서 개발한 full-fit program으로 deconvolution 하여 reduced concentration 과 critical transfer distance를 구했다. donor 의 농도가 acceptor의 농도보다 작을 경우에는 Foster 모델이 클 경우에는 Huber 모델이 잘 맞음을 확인하였다.

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Synthesis and Properties of Novel Rhodamine 6G Fluorescent Dye Compound

  • Kim, Hyung-Joo;Wang, Sheng;Son, Young-A
    • Textile Coloration and Finishing
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    • v.24 no.3
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    • pp.153-157
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    • 2012
  • One of organic dye materials which have been long lasting investigated is rhodamine 6G dye series. This dye has been attracted with considerable interests due to the reason of its promising photochemical properties. In this study, a novel fluorescent dye compound based on rhodamine 6G derivative was synthesized through the reaction of rhodamine 6G hydrazide and indole-3-carboxaldehdyde. Absorption and fluorescent emission spectra of this dye were determined with the properties of solvatofluorochromism. Related electron energy states of the dye compound were also characterized by computational calculations.

Potential of PVA templated Silica Xerogels as Adsorbents for Rhodamine 6G

  • Pirzada, Tahira;Shah, Syed Sakhawat
    • Journal of the Korean Chemical Society
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    • v.55 no.6
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    • pp.1024-1029
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    • 2011
  • PVA/silica hybrid xerogels were synthesized by sonohydrolysis of a mixture of 2-way catalyzed TEOS and water solution of PVA. PVA was successfully removed from the xerogels through calcination and its removal was confirmed through TGA analysis of the calcined gel. Microstructure of the gels was studied through SEM, XRD and FTIR. Nitrogen sorption studies were conducted to find out surface area of different samples. It was found out that the samples having PVA removed through calcinations have higher surface area (411.64 $m^2$/g) than the samples (353.544 $m^2$/g) synthesized without any PVA. Adsorption properties of these xerogels synthesized by using different ratios of components were studied by taking Rhodamine G6 as a model adsorbate. The experiments were conducted at room temperature ($25^{\circ}C$). UV visible spectroscopy was used to measure the concentration of the dye before and after adsorption. The adsorption data of Rhodamine G6 on PVA modified silica is described by the Freundlich's adsorption model.

Detection of Dimer of Rhodamine 6G Perchlorate Doped in Ormosil (Ormosil에 침투된 Rhodamine 6G Perchlorate의 이중합체의 검출)

  • Kim, Goo-Dae;Lee, Dong-A;Moon, Ji-Woong;Park, Kyung-Su
    • Analytical Science and Technology
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    • v.10 no.3
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    • pp.225-229
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    • 1997
  • The stability of Rhodamine 6G Perchlorate(Rh6GP) doped in organically modified silicate(Ormosil) was investigated after the Ormosil was synthesized by sol-gel process. The composition of the Ormosil which makes organic dye molecules stable and dimer-free was decided from comparing absorption peaks of dye molecules in sol state, in wet gel and in completely dried gel. The stable and dimer-free Rh6GP doped in the Ormosil was achieved in the 0.1 molar ratio of HCl/TEOS.

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Adsorption Equilibrium of Rhodamine 6G onto the Conchiolin Layer from Aqueous Solution (수용액중의 Rhodamine 6G 염료의 콘키오린 층에 대한 흡착평형)

  • Shin Choon-Hwan;Song Dong-lk
    • Journal of Environmental Science International
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    • v.14 no.12
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    • pp.1195-1201
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    • 2005
  • In order to develop a dye coloring technology on Conchiolin layer in cultured pearls, appropriate dyes were selected, their solubilities in various solvents were studied, and adsorption and desorption experiments were performed. Solubilities of several basic dyes known to suitable for the pearl coloring, i.e., Rhodamine 6G(R6), Rhodamine B(RB) and Methylene Blue(MB), in several solvents (distilled water, methanol, ethanol, and acetone) were investigated. Among these dyes, R6 was chosen as a dye for single component adsorption and desorption experiment due to the relatively good solubility in various solvents tested. Solubilities of dyes were judged to be enough to color the pearls since dye concentrations in pearl coloring are, in general, not so high. The internal surface area of the pearl layer is believed to be directly related to the dye adsorption, the single-point internal surface area of the pearl layer measured at the nitrogen relative pressure of 0.3 was found to be $0.913m^2/g$, and the BET internal surface area, $1.01m^2/g$ The most probable diameters of micropores and macropores were found to be $40{\AA}$and $5000{\AA}$ respectively, from the pore size distribution data. Adsorption isotherm was well fitted to the Langmuir isotherm model, resulting in q=$\frac{1.62C}{1+1.09C^{.}}$

Synthesis and Fluorescence Properties of New Rhodamine 6G Derivarives Containing Hydroxy Coumarin Moiety (새로운 로다민 6G 하이드록시 쿠마린 유도체의 합성과 형광특성)

  • Park, Seong Ho;Chang, Seung Hyun
    • Journal of Environmental Science International
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    • v.25 no.9
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    • pp.1283-1288
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    • 2016
  • In this study, we synthesized fluorescent sensors from rhodamine 6G derivatives and hydroxy coumarin. The synthetic routes to the rhodamine 6G derivatives containing hydroxy coumarin are shown in Fig. 1. Two derivatives were synthesized through Schiff base reactions. The structures of the new compounds were confirmed by melting point, $^1H$-NMR, and GC-MS analyses. The compounds were found to selectively bind to tin ($Sn^{2+}$) ion by fluorescence titration using various metal cations. Longer carbon chains gave more sensitivity. $Sn^{2+}$ ions exhibited the strongest fluorescence among the nime ions. The binding analysis using Job plots suggested that compounds form 1:1 complexes with the $Sn^{2+}$ ions.