• Textile Coloration and Finishing
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• v.24 no.3
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• pp.158-164
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• 2012

Rhodamine dyes belong to xanthene family has excellent photostability and photophysical properties. In rhodamine dyes, Rhodamine 6G and its precursors also have xanthene chromophore and it shows high fluorescent quantum yield. Rhodamine 6G derivates are simple to synthesis and its high sensitivity and water solubility are suitable as good chemosensor. In this regard, Rhodamine 6G derivates which have selectivity to specific metal cation can used to detect various heavy metal ions. In this study, rhodamine 6G derivatives were synthesized by reaction of rhodamine 6G hydrazide and glyoxal and 4-phenyl thiosemicarbazide and it showed colorimetric and fluorescence sensing toward $Hg^{2+}$ ion. This novel chemosensor was analyzed and measured on UV-Vis and fluorescence spectrophotometer. HOMO/LUMO values were also calculated by computational calculation.

• Korean Journal of Optics and Photonics
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• v.5 no.2
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• pp.266-271
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• 1994

The output power and the energy of Rh-6G dye laser were enhanced by the mixture of Rh-560 dye whose fluorescence spectrum was coincident with the absorption spectrum of Rh-6G. The argon filled coaxial flashlamp used for pulsed pumping and argon laser for CW pumping. The concentration of Rh-6G dye was optimized in each pumping method before Rh-560 dye was mixed in Rh-6G dye solution. In the coaxial flash lamp pumped Rh-6G laser the output energy was increased about 30% when Rh-560 was mixed at 1% of Rh-6G concentration. In the case of argon laser pumping with multiline, the output power was increased 18% at the concentration of 2.5%. In the single line laser pumping, the output power was enhanced more efficiently. The power enhancements were 72% and 88% when the pumping wavelengths were 488 nm and 514.5 nm respectively. ively.

• The Journal of the Korea Contents Association
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• v.17 no.7
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• pp.294-302
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• 2017

In this study, latent fingermarks deposited in porous or non-porous surface was developed by cyanoacrylate fuming, and then the developed fingermark is enhanced by using Rhodamine 6G. Between water-based R6G and organic solvent-based R6G, author studied about which material have higher effectiveness in enhancing fingermark. In all seven types of surfaces depositing fingermark, water-based R6G have higher effectiveness in enhancing fingermark and lower surface coloring than organic solvent-based R6G. But because the surfaces found in crime scene have multicolor background and various quality, the additional study about various surfaces is needed.

• Proceedings of the Optical Society of Korea Conference
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• 1991.06a
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• pp.69-73
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• 1991

모드 동기된 아르곤 이온 레이저를 여기광원으로 사용한 시간상관 단일 광자 계수장치를 이용하여 에탄올 용액 내에서 Rhodamine 6G에서 Rhodamine B로의 에너지 전달에 관하여 연구하였다. 측정된 형광 소멸 곡선은 본 실험실에서 개발한 full-fit program으로 deconvolution 하여 reduced concentration 과 critical transfer distance를 구했다. donor 의 농도가 acceptor의 농도보다 작을 경우에는 Foster 모델이 클 경우에는 Huber 모델이 잘 맞음을 확인하였다.

• Journal of Korean Ophthalmic Optics Society
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• v.16 no.1
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• pp.91-95
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• 2011

Purpose: In this study, we investigated the dye to staining for selective accumulation in rabbit retina. Methods: Rhodamine B was injected into the vitreous body in rabbit. After 24 h, the isolated retina was checked condition of cell staining on the microscope. We used conventional immunocytochemical techniques for recognizing cell type. Results: Well-labeled nuclei were seen in the middle of the inner nuclear layer of the rabbit retina. The number and distrbution of the accumulating cells were similar to those of the m$\ddot{u}$ller glia. To identify m$\ddot{u}$ller cell, we used antibody directed against vimentin. Rhodamine B-immunoreactive nuclei also were labeled with antivimentin antibody. We found that Rhodamine B was accumulated selectively in retinal m$\ddot{u}$ller cell. Conclusions: Specific accumulation in rabbit retinal m$\ddot{u}$ller cell occurred when Rhodamine B was applied to living retina.

• Textile Coloration and Finishing
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• v.26 no.1
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• pp.7-12
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• 2014

Nowdays, fluorescent rhodamine chemosensors have attracted a worldwide interest due to its ability to selectively detect heavy and transition metal cations. Due to the importance in environmental and biological toxic effects, the developments of fluorescent chemosensors have been received considerable attention in recent. Especially, a rhodamine-based chemosensor probes have been proved to be useful by exhibiting the efficient "off-on" fluorescence switching toward selected metal cations. This fluorophore can undergo the transformation from non-fluorescent and colorless spirolactam derivative to fluorescent ring-open form. In this study, a new fluorescent chemosensor was synthesized using rhodamine B through two-step procedures, and its selectivity and related optical property were characterized. Selectivity and sensitivity was found toward $Cu^{2+}$ guest molecules and then related optical properties of rhodamine B based fluorescent chemosensor compound were characterized using discussed. In addition, computational calculation was used to determine the HOMO/LUMO values.

• YAKHAK HOEJI
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• v.49 no.2
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• pp.185-191
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• 2005

The absorption of a P-gp substrate, rhodamine 123, from a liposomal dosage form was investigated across Caco-2 cell monolayers, rat intestines and rat intestinal Peyer's patches in Ussing chamber, Rhodamine 123 was incorporated into liposomes according to the standard evaporation method, which led to a production of liposomes with a mean diameter of 71.3 nm. The permeability (Papp of rhodamine 123 from a water solution across the monolayer was $2.45{\times}10^{-6}$ cm/s for $A{\leftrightarrow}B$ (apical to basal) and $14.0{\times}10^{-6}$ cm/s for $B{\leftrightarrow}A$ (basal to apical) directions, consistent with the fact that rhodamine 123 is one of the P-gp substrates. The transport of rhodamine 123 from the liposomal dosage form was much lower for both directions compared to the solution of rhodamine 123. The transport of rhodamine 123 across the rat intestine was also significantly decreased for both directions, I.e., influx and efflux, by the liposomal incorporation of the compound. The transport of rhodamine 123 across the Peyer's patch was substantially reduced by liposomal incorporation. No difference was found in the transport between the Peyer's patch and non-Peyer's patch. These observations suggest that the contribution of transport via Peyer's patches in the uptake of liposomes may be minimal, especially for rapidly absorbed compounds like rhodamine 123. Therefore, the increased absorption of P-gp substrates does not appear to be feasible by incorporating the compounds in liposomes, due to negligible involvement of Peyer's patches in the uptake of particulate dosage forms like liposomes. Liposomes may rather represent a sustained release dosage form of incorporated compounds.

• The Journal of the Korea Contents Association
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• v.18 no.2
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• pp.124-131
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• 2018

This study aimed to compare effectiveness of fluorescent reagents for enhancing blood such as acid yellow 7, rhodamine 6G, eosin Y. AY7 and eosin Y have been introduced in Korea as fluorescent reagents for enhancing blood, but not rhodamine 6G. In this study, researchers photographed when each reagents gave the most effective results. Consequently, rhodamine 6G was superior to the others. Eosin Y enhanced bloody fingermarks weakly compared to AY7 and rhodamine 6G. Furthermore, the more depletion trials were done, the less effectiveness were shown. Therefore, researchers recommended that crime scene investigators try to use rhodamine 6G fluorescent reagents for enhancing blood.

• Journal of Environmental Health Sciences
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• v.37 no.3
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• pp.218-225
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• 2011

Objectives: In this paper, a dielectric barrier discharge (DBD) plasma reactor was investigated for degrading the dye Rhodamine B (RhB) in aqueous solutions. Methods: The DBD plasma reactor system in this study consisted of a plasma component [titanium discharge (inner), ground (outer) electrode and quartz dielectric tube], power source, and gas supply. The effects of various parameters such as first voltage (input power), gas flow rate, second voltage (output power), conductivity and pH were investigated. Results: Experimental results showed that a 99% aqueous solution of 20 mg/l Rhodamine B is decolorized following an eleven minute plasma treatment. When comparing the performance of electrolysis and plasma treatment, the RhB degradation of the plasma process was higher that of the electrolysis. The optimum first voltage and air flow rate were 160 V (voltage of trans is 15 kV) and 3 l/min, respectively. With increased second voltage (4 kV to 15 kV), RhB degradation was increased. The higher the pH and the lower conductivity, the more Rhodamine B degradation was observed. Conclusions: OH radical generation of dielectric plasma process was identified by degradation of N, N-dimethyl-4-nitrosoaniline (RNO, indicator of OH radical generation). It was observed that the effect of UV light, which was generated as streamer discharge, on Rhodamine B degradation was not high. Rhodamine B removal was influenced by real second voltage regardless of initial first and second voltage. The effects of pH and conductivity were not high on the Rhodamine B degradation.

• Journal of the Korean Chemical Society
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• v.63 no.4
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• pp.307-311
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• 2019