• 한국수산과학회지
• /
• 제26권6호
• /
• pp.580-593
• /
• 1993

대마해류는 큐슈 서쪽해역에서 갈라져 대한해협으로 북상하여 흐르는 것으로 알려져 왔다. 이럴 경우 해류는 등수심선을 가로질러야 하며 이를 위해 어떤 힘이 필요하다. 그러한 힘으로는, 대한해협과 쯔가루해협 사이의 해수면의 차이, Reynolds Stress, 밀도차이 등에 제시되어져 왔다. 이 논문에서는 순압인 경우에 이들의 역할을 수치모델을 사용하여 연구해 보았다. 모델 결과는 대마해류가 위의 어떠한 힘이 없이도 발생한다는 것을 보였다. 해류는 동중국해에서 등수심선을 따라 흐르며, 해류흐름은 외부의 힘에 의해서가 아니라 자신의 역학에 의해 발생하는 것으로 보인다. 그 역학은 육지에 의한 틈새(gap) 사이로 유출되는 흐름에서와 같다. 모델결과는 또한 이 해역의 해류가 Reynolds Stress와 같은 외부의 힘에 의해 영향을 받을 수 있다는 것을 보여 주며, 그럴 경우 실제 해양에서는 해류의 역학과 형태가 복잡하게 나타날 가능성이 있다. 그러나 순압모델 결과는 대마해류가 기본적으로는 지형균형(geostrophic adjustment)에 의한 것임을 보여준다.

• 한국환경농학회지
• /
• 제33권1호
• /
• pp.63-67
• /
• 2014

BACKGROUND: The present study is an exploratory research to establish national biosafety regulation systems through a survey on the recognition of safety regulation systems for the living modified organism(LMO). METHODS AND RESULTS: We have conducted a survey on an awareness of LMO safety regulation systems in scientific working groups. The data of 235 respondents were analyzed using various statistical methods. As a result, 72.8% of the respondents were male; 27.2% were female, and 43.4% of them work in the university. A total of 33.2% of the respondents majored in general biology, and their most common job position was the laboratory safety manager. The difference of an awareness on LMO law and regulatory system was not statistically significant by either work places or job positions. CONCLUSION: For the rapid settlement and the efficient implementation of LMO safety management policy, we conclude that it is required to reduce the gap between the recognition and fulfillment of safety management. Furthermore, the mutual exchanges of information among researchers are needed with the settlement of the safety management system and the harmony of policy with improvement of the absurd regulations. The ongoing and specialized training, inspections, and the strengthening of public relations are also required along with the efforts to improve the absurd regulations.

• 한국철도학회논문집
• /
• 제19권5호
• /
• pp.663-671
• /
• 2016

본 연구에서는 교통카드자료를 기반으로 한 김경민 외[1]의 승객경로추적 방법을 이용하여 서울지하철 9호선 2단계 개통에 따른 급행열차 선택에 대한 변화를 분석하였다. 분석결과 2단계 개통 전과 비교하였을 때, 1단계 구간 기존 승객들의 급행열차 선택 비율은 변하지 않음을 확인하였다. 개통 전 후로 나누어 각각에 대한 다항로짓모형을 개발하였고 개통 전 후 모형의 전이성을 확인하였다. 하지만, 급행열차에 대한 선택이 높은 장거리 승객의 증가로 인해 2단계 개통 후 급행열차의 혼잡도가 약 6.7% 상승하였고 일반열차와의 혼잡도 차이는 증가하였다.

• KSII Transactions on Internet and Information Systems (TIIS)
• /
• 제13권4호
• /
• pp.1961-1974
• /
• 2019

In this letter, a harmonic-mean-based dual-antenna selection scheme at relay node is proposed in two-way relaying networks (TWRNs). With well-designed distributed orthogonal concatenated Alamouti space-time block code (STBC), a dual-antenna selection problem based on the instantaneous achievable sum-rate criterion is formulated. We propose a low-complexity selection algorithm based on the harmonic-mean criterion with linearly complexity $O(N_R)$ rather than the directly exhaustive search with complexity $O(N^2_R)$. From the analysis of network outage performance, we show that the asymptotic diversity gain function of the proposed scheme achieves as $1/{\rho}{^{N_R-1}}$, which demonstrates one degree loss of diversity order compared with the full diversity. This slight performance gap is mainly caused by sacrificing some dual-antenna selection freedom to reduce the algorithm complexity. In addition, our proposed scheme can obtain an extra coding gain because of the combination of the well-designed orthogonal concatenated Alamouti STBC and the corresponding dual-antenna selection algorithm. Compared with the common-used selection algorithms in the state of the art, the proposed scheme can achieve the best performance, which is validated by numerical simulations.

• Restorative Dentistry and Endodontics
• /
• 제27권4호
• /
• pp.403-410
• /
• 2002

Several ways of curing are being tried to improve material's properties and reduce marginal gap. However, all are considering about the pattern of light intensity. It was noted from the preliminary study the change of light wavelength from filter changing may give an impact on material's property and microleakage. The object of this study was to verify the effect of filters with various wavelength width on the microhardness and microleakage of composite resin ; hybrid type of DenFil and submicron hybrid type of Esthet X. Composite resins were cured using 3 kinds of filter; narrow-banded(465-475 nm), mid-banded(430-470 nm), wide-banded(400-500 nm). After the estimation of microhardness. degree of dye penetration and the maximum gap from SEM evaluation were done between 4 groups that showed no difference in microhardness value of the lower surface . The results were as follows : 1 Adequate microhardness could not be gained with a narrow-banded filter irrespective of curing time. At the upper surface, DenFil should be polymerized with middle or wide-banded filter for 20 seconds at least, while Esthet X be col$.$ed with middle or wide-banded filter for 30 seconds at least to get simitar hardness value to control group. 2. There was little dye penetration in enamel margin, but all dentin margins skewed much more dye penetration irrespective of curing conditions. Although there was no statistical difference, groups cured with mid-banded filter for 40 seconds and with wide-width filter for 20 seconds showed relatively less dye penetration. 3. It was revealed from the SEM examination that group cured with wide-banded filter had the smallest gap without statistical significance. Spearman's rho test showed that the correlation between the results of dye penetration and SEM examination was very low. From these results, it could be concluded that curing with wide-width filter would be better than the other techniques, even though the curing technique using mid-width filter seems to have its own unique advantage.

• Restorative Dentistry and Endodontics
• /
• 제28권2호
• /
• pp.134-145
• /
• 2003

Mechanical properties and microleakage of two composites [conventional hybrid type DenFil (VERICOM Co., Anyang, Korea) / micro matrix hybrid type Esthet X (Dentsply Caulk, Milford, DE, U.S.A.)] were evaluated to assess whether variable light intensity curing is better than conventional curing technique. Curing was done for 40 seconds in two ways of 2 step soft-start technique and 5 step ramping technique. Three kinds of light intensities of 50, 100, $200{\;}mW/\textrm{cm}^2$ were initially used for 10, 20, 30 seconds each and the maximum intensity of $600 {\;}mW/\textrm{cm}^2$ was used for the rest of curing time in a soft-start curing tech nique. In a ramping technique, curing was done with the same initial intensities and the light intensity was increased 5 times with the same rate to the maximum intensity of $600{\;}mW/\textrm{cm}^2$. After determining conditions that showed no different mechanical properties with conventional technique, Esthet X composite was filled in a class V cavity, which dimension was $4{\times}3{\times}1.5{\;}mm$ and cured under those conditions. Microleakage was evaluated in two ways of dye penetration and maximum gap estimation through SEM observation. ANOVA and Spearman's rho test were used to confirm any statistical significance among groups. The results were as follows : 1 Several curing conditions of variable light intensities resulted in the similar mechanical properties with a conventional continuous curing technique, except conditions that start curing with an initial light intensity of $50{\;}mW/\textrm{cm}^2$. 2. Conventional and ramping techniques were better than soft-start technique in mechanical properties of microhardness and compressive strength. 3. Soft-start group that started curing with an initial light intensity of $100{\;}mW/\textrm{cm}^2$ for 10 seconds showed the least dye penetration. Soft-start group that started curing with an initial light intensity of $200{\;}mW/\textrm{cm}^2$ for 10 seconds showed the smallest marginal gap, if there was no difference among groups. 4. Soft-start technique resulted in better dye-proof margin than conventional technique(p=0.014) and ramping technique(p = 0.002). 5. There was a very low relationship(p=0.157) between the methods of dye penetration and marginal gap determination through SEM evaluation. From the results of this study, it was revealed that ramping technique would be better than conventional technique in mechanical properties, however, soft-start technique might be better than conventional one in microleakage. It was concluded that much endeavor should be made to find out the curing conditions, which have advantages of both aspects or to solve these kinds of problems through a novel idea of polymerization.

• Restorative Dentistry and Endodontics
• /
• 제29권5호
• /
• pp.413-422
• /
• 2004

Established microleakage tests have their own disadvantages. In this study, 3D reconstruction method was tried to overcome these disadvantages. Four types of microleakage tests were used and relationships among them were estimated: penetrated dye volume: marginal adaptability: degree of dye penetration and relative penetrated length to cavity wall. Twenty-four Class V cavities were bulk filled with composite (Esthet X) following surface treatments: N group (no treatment): E group (etching only): T group (etching + Prime & Bond NT). 50% silver nitrate was used as a dye solution after thermocycling ($5^{\circ}C{\;}&{\;}55^{\circ}C$, 1.000 times). Teeth were serially ground with a thickness of 0.2 mm. Volume of dye penetration was estimated from a three-dimensionally reconstructed image with a software (3D-DOCTOR). Percentage of margin without gap was estimated from SEM and degree of dye penetration and the relative length of dye penetration to overall cavity wall were also estimated. ANOVA and Scheffe test for dye volume, Kruskal-Wallis and Mann-Whitney test for marginal quality, Spearman's rho test for checking of relationships among methods were used. The results were as follows: 1. Dye penetration could be seen from several directions, furthermore, its volumetric estimation was possible. 2. Reverse relationship was found between dye volume and marginal quality (r = -0.881/ p = 0.004). 3. Very low relationship was seen between dye volume and two-dimensional tests (degree of dye penetration and relative length). However, 2D evaluation methods showed high relationship (p = 0.002-0.054) each other. 4. Three times vertical section could be recommended as a 2D test.

• Bulletin of the Korean Chemical Society
• /
• 제23권2호
• /
• pp.201-204
• /
• 2002

The rates of the aminolysis of S-phenyl substituted-acetate series $(RC(=O)SC_6H_4Z$, with R=Me, Et, i-Pr, t-Bu and Bn) with benzylamines $(XC_6H_4CH_2NH_2)$ are not correlated simply with the Taft's polar $({\sigma}^{\ast})$ and/or steric effect constants $(E_s)$ of the substituents due to abnormally enhanced rate of the substrate with R=Et. Furthermore, the cross-interaction constant, ${\rho}x_z$ , is the largest with R=Et. These anomalous behaviors can only be explained by invoking the vicinal bond $({\sigma})$-antibond $({\sigma}^{\ast})$ charge transfer interaction between C-$C{\alpha}$ and C-S bonds. In the tetrahedral zwitterionic intermediate, $T^{\pm}$ , formed with R=Et the vicinal ${\sigma}_{c-c}-{\sigma}^{\ast}_{c-s}$ delocalization is the strongest with an optimum antiperiplanar arrangement and a narrow energy gap, ${\Delta}{\varepsilon}={\varepsilon}_{{\sigma}^{\ast}}-{\varepsilon}_{\sigma}$. Due to this charge transfer interaction, the stability of the intermediate increases (with the concomitant increase in the equilibrium constant K (= $k_a/k_{-a}$)) and also the leaving ability of the thiophenolate leaving group increases (and hence $k_b$ increases) so that the overall rate, $k_n\;=\;Kk_b$, is strongly enhanced. Theoretical support is provided by the natural bond orbital (NBO) analyses at the B3LYP/6-31+$G^{\ast}$ level. The anomaly exhibited by R=Et attests to the stepwise reaction mechanism in which the leaving group departure is rate limiting.

• 대한화학회지
• /
• 제43권1호
• /
• pp.85-91
• /
• 1999

Phenyl N,N-diethyl-P-benzylphonamidate 및 그 유도체들의 염기성 가수분해 반응속도 상수를 분광 광도법으로 측정하였다. 속도 상수로부터 열역학적 파라메타(Ea, ${\Delta}H^{\neq}$,${\Delta}S^{\neq}$)를 구하였고, 이탈기의 치환기 효과는 Hammett 식을 이용하여 얻었다. 이들 실험 자료에 의하면 가수분해 반응은 활성화 엔트로피가 양의 값이나 작은 음의 값을 갖고 카르보음이온 생성이 수반되는 해리반응 보다는 이중피라미드 중간체 또는 전이 상태를 경유하는 회합 메카니즘을 강력히 암시하고 있다. 반응속도론적 연구 결과에 의하면 치환 pheny N,N-diethyl-P-benzylphosphonamidates의 가수분해 반응은 회합성 메카니즘으로 진행됨을 알 수 있었다.

• 한국전기전자재료학회논문지
• /
• 제24권2호
• /
• pp.116-120
• /
• 2011

The 0.98 ($Na_{0.44}K_{0.52})Nb_{0.84}O_3-0.02Li_{0.04}$ ($Sb_{0.06}Ta_{0.1})O_3-0.5$ mol%CuO ceramics have been fabircated by ordinary sintering technique and the effect of various calcination method on the electrical propertis and microstructure have been studied. It was observed that the various calcination method influenced the elelctrical properties and structural properties of the 0.98NKN-0.02LST-0.5 mol%CuO ceramics with the optimum piezoelectric constant ($d_{33}$) and electromechanical coupling factor ($k_p$) at room temperature of about $155{\rho}C/N$ and 0.349, respectively, from 0.98NKN-0.02LST-0.5 mol%CuO ceramics sample. The curie temperature ($T_c$) of this ceramic was found at $440^{\circ}C$. The 0.98NKN-0.02LST-0.5 mol%CuO ceramics are a promising lead-free piezoelectric ceramics.