• 한국소성가공학회:학술대회논문집
• /
• 한국소성가공학회 2005년도 춘계학술대회 논문집
• /
• pp.299-302
• /
• 2005

Semisolid A356 slurries were prepared by electromagnetic stirring casting and by inoculation of Al-5Ti-B master alloy. As stirring time and addition of Al-5Ti-B are different, the grain size of the primary phase is different. Through the experiment of rheocast in a Buhler horizontal die casting machine, it was found that the finer the equiaxed primary dendrites, the smoother the die filling and better cast quality. Small equiaxed primary dendrite also results in less liquid segregation on the surface.

• 한국산학기술학회논문지
• /
• 제12권9호
• /
• pp.4267-4273
• /
• 2011

아스팔트와 PE 혼합물에 사용될 상용화제를 선정하기 위하여 poly(ethylene-co-acrylic acid)와 poly(ethylene-co-methacrylic acid)의 금속염인 이오노머들의 아스팔트에 대한 상용성을 광학 현미경, 열분석 및 유변학 연구를 통하여 관찰하였다. 수분 흡수를 통한 극성 분석, 광학 현미경 관찰 결과와 열분석을 통하여 후보 고분자들의 아스팔트와의 상용성을 관찰한 결과 대체적으로 극성이 높을수록 아스팔트와의 상용성이 높아짐을 알 수 있었다. 또한 유변학 관찰을 통하여 몇몇 고분자들은 아스팔트와 균일 상을 이룬다는 것을 알 수 있었다.

• Korean Chemical Engineering Research
• /
• 제58권2호
• /
• pp.176-183
• /
• 2020

이 연구에서는 작은 유기 분자 말단의 하이드록실기와 전이 금속 사이의 배위 결합을 통해 고분자와 유사하게 연결된 복합체를 제작하고, 점착 부여제를 추가하여 해당 물질의 점착제로의 사용 가능성을 확인하였다. 점착제 합성에 사용한 타닌산(tannic acid, TA)은 하이드록실기를 풍부하게 보유하고 있어 전이 금속과는 배위 결합이 가능하고 친수성 고분자와는 수소 결합이 가능하다. 위의 성질을 이용하여 타닌산과 전이 금속, 고분자 세 가지 성분을 한 번에 간단히 섞어 기판에 잘 펴지며 점착 능력을 보유한 특별한 유변 물성을 가지는 물질을 제작하였다. 합성에 사용한 전이 금속의 종류(Fe³⁺, Ti⁴⁺), 고분자의 종류, 처리 조건 등에 따른 유변 물성의 변화를 확인하는 과정을 통해 점착제로 사용하기에 가장 적합한 성분의 조합을 발견하였으며, 인체에 무해하며 높은 응집력과 접착력을 보유한 다목적 점착제로의 사용 가능성을 확인하였다.

• 유변학
• /
• 제11권1호
• /
• pp.18-27
• /
• 1999

본 연구에서는 3차원 열성형 공정 알고리듬과 이에 membrane approximation을 도입한 근사적인 알고리듬을 개발하였고, 이 알고리듬을 이용하여 몇몇 열성형계에 대한 수치모사를 수행하여 그 결과를 비교 분석하였다. 3차원 알고리듬의 경우에는 구성한 유한요소 평형 방정식에 벌칙함수를 도입하여 비압축성 조건을 만족시켜 해를 얻었으며, membrane approximation을 도입한 알고리듬의 경우에는 두께 방향의 응력을 무시하여 구성한 방정식으로부터 해를 얻었다. 구성방정식은 2nd Piola-Kirchhoff 응력 텐서와 Cauchy-Green 변형 텐서를 사용하여 표현하였고 수지의 물질 모델식으로는 2항의 Mooney-Rivlin 모델을 사용하였으며, total Lagrangian coordinate를 도입하여 지배방정식을 유한요소화함으로써 알고리듬을 구성하였다. 대상계로 선정한 사각평판 수지의 자유 부풀림 거동과 금형이 있는 경우에서의 수지의 부풀림 거동을 3차원 알고리듬과 membrane approximation 알고리듬을 각각 이용하여 분석하였으며 3차원 알고리듬의 경우 clamping 부분의 경계조건을 달리하여 결과를 비교하였다. 금형이 있는 계에 대해서는 slip 경계조건과 no-slip 경계조건을 각각 부여하여 수치모사를 수행, 수지의 변형거동과 응력분포를 비교 분석하였으며, 두께를 달리 한 수지에 대해 두께 방향의 응력을 비교 분석함으로써 membrane approximation 알고리듬의 한계에 대하여 논하였다. 한편 수지 온도 변화에 따른 성형품의 두께 분포의 변화를 살펴보기 위하여 ABS 수지를 대상으로 하여 $137.8^{\circ}C$에서 $171.1^{\circ}C$사이의 온도에서 수행한 인장실험 데이터를 수치모사에 사용하였다. 그 결과 수지의 온도가 높을수록 두께의 표준편차가감소하여 균일한 두께 분포를 얻을 수 있음을 확인하였고 이는 수지의 흐름성이 증가함으로써 나타나는 현상으로 해석할 수 있다.

• Journal of Pharmaceutical Investigation
• /
• 제41권3호
• /
• pp.161-171
• /
• 2011

The objective of the present study is to systematically characterize a linear viscoelastic behavior of petroleum jelly in small amplitude oscillatory shear flow fields correspondent to the rheological ground state. With this aim, using a strain-controlled rheometer, the dynamic viscoelastic properties of commercially available petroleum jelly have been measured at $37^{\circ}C$ (body temperature) over a wide range of angular frequencies at an extremely small strain amplitude of 0.1 %. In this article, the linear viscoelastic behavior was reported in detail and then explained from a structural view-point of petroleum jelly and discussed in depth with respect to the consumer's requirements. Main findings obtained from this study can be summarized as follows : (1) The storage modulus is always greater than the loss modulus over an entire range of angular frequencies studied, meaning that the linear viscoelastic behavior of petroleum jelly is dominated by an elastic nature rather than a viscous nature. (2) Petroleum jelly shows a desirable linear viscoelastic behavior with respect to the consumer's requirements because it is undesirable for the product to flow down from the skin at an initial stage upon contact with the human skin. (3) A fractional derivative model shows an excellent applicability to describe a linear viscoelastic behavior of petroleum jelly. However, this model should be used with a special caution because there exists no physical meaning for the model parameters. (4) A modified form of the Cox-Merz rule gives a good ability to predict the relationship between steady shear flow properties (nonlinear behavior) and dynamic viscoelastic properties (linear behavior) for petroleum jelly.

• 한국건축시공학회지
• /
• 제8권2호
• /
• pp.99-106
• /
• 2008

To improve concrete tensile strength and bending strength, New plan that have more economical and simple manufacture process is groped. By an alternative plan, chemical pre-stressed concrete is presented. In this study, we analyzed the rheological properties of cement paste with the kind and replacement ratio of k-type CSA type expansive additives that is used mainly in domestic. and we suggested that the algorithm of a mixing plan in the chemical pre-stressed concrete and from this, we presented the basic report for the right mixing plan. From the results, Flow increased more or less according to use of expansive additives. This phenomenon was observed by increasing paste amount that shows as substitution for expansive additives that specific gravity is smaller than that of cement. As linear regression a result supposing paste that mix expansive additives by Bingham plastic fluid. The shear rate and shear stress expressed high interrelationship. therefore, flow analysis of quantitative was available. The plastic viscosity following to replacement ratio of expansive additives is no change almost, the yield value is decreased in proportion to the added amount of expansive additives. Through this experiment, we could evaluate rheological properties of cement paste using the expansive additives. Hereafter by an additional experiment, we must confirm stability assessment of material separation by using the aggregate with the kind and replacement ratio of expansive additives.

• 펄프종이기술
• /
• 제44권6호
• /
• pp.79-86
• /
• 2012

The aim of this general remarks is to introduce the results concerning the thermo physical, charging, developing and fusing characteristics of micro-encapsulated (MC) model toners in order to apply to the toner of electrophotographic system at the condition of a low temperature. In order to clarify the fusing mechanism of MC toner, rheological analysis of the toner was chosen. It was suggested that MC toner had a different fusing mechanism compared with non-MC toner. Some kinds of MC model toners showed a good result on adhesion test as well as cohesion test. Also, it was possible to get the good charging and development characteristic of MC toner for printing test with laser printer.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2002년도 학술.기술논문발표회
• /
• pp.29-36
• /
• 2002

High fluid concrete unlike OPC concrete is made with various material, and the phase of fresh concrete is considerably different. In order to understand fluidity phase and mix properties of high fluid concrete, concrete is required to access as suspension structure which consists of aggregate and paste. The focus of this paper is to analyze the test results and quantify the effect of mix proportions of molar and fineness modulus of ,and on the properties of fresh mortar. The effect of water-binder ratio, sand-binder ration, content; of ggbs (by mass of total cementitious materials), and various contents of water reducing agent on the yield stress and plastic viscosity of the mix is studied. Based on the experimental results, the following conclusion; can be drawn: (1) The mixing time needed (or high fluid mortar was approximately two times more than that of ordinary portland mortar. (2) The fluidity phase of mortar could be explained by yield stress of mix and the fluidity of mortar. (3) As the content of ggbs increased, yield stress of mortar was decreased and plastic viscosity of it was increased. (4) For the high fluid mortar, it was appeared that sand-binder ratio should be below 1.5.

• International Journal of Concrete Structures and Materials
• /
• 제1권1호
• /
• pp.11-18
• /
• 2007

In the recent design of high ductile engineered cementitious composites (ECC), optimizing both processing and mechanical properties for specific applications is critical. This study employs a method to develop useful ECC produced with slag particles (slag-ECC) in the field, which possesses different fluid properties to facilitate diverse types of processing (i.e., self-consolidating or spray processing). Control of rheological modulation was regarded as a key factor to allow the performance of the desired processing while retaining the ductile material properties. To control the rheological properties of the composite, the basic slag-ECC composition was initially obtained, determined based on micromechanics and steady-state cracking theory. The stability and consequent viscosity of the suspensions were then mediated by optimizing the dosage of the chemical and mineral admixtures. The rheological properties altered through this approach were revealed to be effective in obtaining ECC-hardened properties, represented by pseudo strain-hardening behavior in uniaxial tension, allowing the readily achievement of the desired function of the fresh ECC.

• Computers and Concrete
• /
• 제2권2호
• /
• pp.97-110
• /
• 2005

Rheological behaviour of fresh concrete is an important factor in controlling concrete quality. It is recognized that the measurement of the slump is not a sufficient test method to adequately characterize the rheology of fresh concrete. To further understand the slump measurement and its relationship to the rheological properties, an elasto-viscoplastic, 2-D axisymmetric finite element (FE) model is developed. The FE model employs the Bingham material model to simulate the flow of a slump test. An experimental program is carried out using the Slump Rate Machine (SLRM_II) to evaluate the finite element simulation results. The simulated slump-versus-time curves are found to be in good agreement with the measured data. A sensitivity study is performed to evaluate the effects of yield stress, plastic viscosity and cone withdrawal rate on the measured flow curve using the FE model. The results demonstrate that the computed yield stress compares well with reported experimental data. The flow behaviour is shown to be influenced by the yield stress, plastic viscosity and the cone withdrawal rate. Further, it is found that the value of the apparent plastic viscosity is different from the true viscosity, with the difference depending on the cone withdrawal rate. It is also confirmed that the value of the final slump is most influenced by the yield stress.