• Title/Summary/Keyword: Rheological properties

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Effects of HLB value on oil-in-water emulsions: Droplet size, rheological behavior, zeta-potential, and creaming index

  • Hong, In Kwon;Kim, Su In;Lee, Seung Bum
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.123-131
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    • 2018
  • Using mixed nonionic surfactants Span/Tween, we investigated the effects of HLB value on the O/W emulsion stability and rheological behaviors. In this study, MS-01 (Span 60 & Tween 60) and MS-02 (Span 80 & Tween 80) was used as mixed nonionic surfactants. We considered required HLB value 10.85 and selected corresponding HLB value range 8-13. The droplet size distributions, droplet morphology, rheological properties, zeta-potential and creaming index of the emulsion samples were obtained to understand the mechanism and interaction of droplets in O/W emulsion. The results indicated that optimal HLB number for O/W emulsions was 10.8 and 10.7, while using MS-01 surfactant and MS-02 surfactant respectively. MS-01 (HLB = 10.8) sample and MS-02 (HLB = 10.7) sample showed smallest droplet size and highest zeta-potential value. Rheological properties are measured to understand rheological behaviors of emulsion samples. All emulsion samples showed no phase separation until 30 days storage time at $25^{\circ}C$.

A Study on the Properties of Porous Concrete according to Rheological Property of Binder and Compaction Energy (결합재의 유동특성 및 다짐에너지에 따른 포러스콘크리트의 특성에 관한 연구)

  • Lee, Jun;Park, Seong-Bum;Kim, Jeong-Hwan;Kim, Bum-Kyou;Kim, Hyung-Seok
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.596-599
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    • 2004
  • The purpose of this study is to investigate properties of porous concrete according to rheological properties of binder and compaction factor. The results of this study, the rheological property of binder is stabilized when a mixing time is over 240 seconds in case of target flow values are $175\%\;and\;200\%$. The void ratio of specimen has a very near value by target void ratio on the whole according as the rheological properties of binder and compaction energy are changed when target flow value is $200\%$, compaction energy is $75kN{\cdot}m/m^2$. The specimen has the excellent compressive strength when compaction energy and target flow value are $100kN{\cdot}m/m^2$ and $200\%$ respectively.

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Rheological, Morphological and Electrical Properties of Polycarbonate/Multi-walled Carbon Nanotube Composites

  • Han, Mi-Sun;Sung, Yu-Taek;Chung, Ji-Woong;Kim, Woo-Nyon;Lee, Heon-Sang;Kum, Chong-Ku
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.220-220
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    • 2006
  • Rheological and electrical properties of the polycarbonate (PC) / multi-walled carbon nanotube (MWNT) were studied. The MWNT was funtoinalized by treating with the hydrogen peroxide ($H_{2}O_{2}$). The electrical conductivity showed higher value for the PC/MWNT ($H_{2}O_{2}$ treated, freeze drying) composites compared that of the PC/MWNT ($H_{2}O_{2}$ treated, thermal drying) composites. From the results of the morphological, rheological, and electrical properties of the PC/MWNT composites, it is suggested that the electrical and rheological properties of the PC/MWNT composites are affected by the MWNT-MWNT network structure which is related with the MWNT morphologies such as the degree of aggregation and aspect ratio of the MWNT.

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Rheological Properties of Cement Pastes Blended Finex-Slag Powder (파이넥스 슬래그 미분말을 혼합한 시멘트 페이스트의 유동특성)

  • Lee, Keun-Jae;Byun, Seung-Ho;Song, Jong-Taek
    • Journal of the Korean Ceramic Society
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    • v.46 no.6
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    • pp.657-661
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    • 2009
  • In this study, rheological properties of cement pastes containing ground Finex-slag (4000, 6000, 7000 c$m^2$/g) were investigated bymini-flow test and coaxial cylinder viscometer. And also blast furnace slag(4000, 6000, 7000 c$m^2$/g) were used for comparison. According to the experimental results, Finex-slag and blast furnace slag showed very similar trend in the rheological properties of the cement pastes. The fluidity of cement pastes blended Finex-slag and blast furnace slag powder were improved by high replacement ratio. In the relationship of plastic viscosity and yield stress appeared the tendency of the proportion greatly. And in the relationship of plastic viscosity, yield stress and mini-flow appeared the tendency of the inverse proportion.

A Study of Rheological Properties of Dough with Waxy Black Rice Flour (찰흑미분을 첨가한 밀가루 반죽의 물리적 특성에 관한 연구)

  • Kim, Woen-Mo;Kim, Tae-Hyung;Lee, Yoon-Shin
    • Culinary science and hospitality research
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    • v.12 no.4 s.31
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    • pp.236-246
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    • 2006
  • The different rheological properties of wheat flour and waxy black rice flour dough were investigated in dough with 10, 20, 30 and 40% of waxy black rice flour(WBRF). Water absorption and weakness of dough was increased, but stability of dough, high initial pasting temperature, viscosity at peak point and the volume were decreased after 2nd fermentation as the addition of WBRF was increased. In the 10% addition of WBRF, the dough showed similar rheological properties with those of control group.

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Effect of Mixed Coagulant on the Rheological Properties of Soybean Curd (이성분 혼합응고제에 의한 두부의 물성 변화)

  • 홍정화;김진우;이재권
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.26 no.6
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    • pp.1096-1101
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    • 1997
  • Soy curd was prepared using imported soybean(U.S.grade A) and changes in quality were evaluated using different types and mixtures of coagulants(CaCl$_2$, CaSO$_4$, MgCl$_2$, MgSO$_4$, and glucono-$\delta$-lactone). Quality of soy curd was determined by rheological properties, yield, and color. Based upon the characteristics of each coagulant, mixtures of two coagulants were prepared in various ratios. The mixture of CaSO$_4$or MgCl$_2$with glucono-$\delta$-lactone(GDL), and that of CaSO$_4$or MgCl$_2$with MgSO$_4$resulted in soy curd of good quality in terms of rheological properties and yield.

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Rheological properties of arabinogalactan solutions related to the carbohydrate composition of different legumes

  • Kyeongyee Kim;Choon Young Kim
    • Food Science and Preservation
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    • v.30 no.5
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    • pp.785-796
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    • 2023
  • The aim of this study was to elucidate chemical structures and rheological properties of arabinogalactans (AGs) isolated from three legumes including black gram (BG), great northern bean (GNB), and California small white bean (CSWB). The ratio of galactose to arabinose (G/A) in three legumes increased in the order of BG > GNB > CSWB. The rheological measurements of 1-5% (w/v) AG solutions revealed Newtonian and non-Newtonian flow behaviors. BG exhibited yield stress, indicating plastic behavior. Small-amplitude oscillatory tests indicated viscoelastic properties of BG, GNB, and CSWB ranging from solid-like, paste-like, and liquid-like behaviors, respectively. Small-strain oscillatory tests were conducted to assess the structure recovery of the AGs after pre-shearing. G" values of BG and GNB increased, but those of CSWB remained constant after shearing. These results suggest that the chemical structures of the AGs, particularly their G/A ratios, influence their rheological properties.

Thixotropic Equation and Rheological Parameters on Non-Newtonian Flow Mechanism (비 뉴톤 유동 메카니즘에서 틱소트로피 식과 유변 파라메타)

  • Kim, Nam Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.3
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    • pp.386-393
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    • 2015
  • The rheological properties of complex materials such as colloid dispersion show complicated non-Newtonian flow phenomena when they are subjected to shear flow. These flow properties are controlled by the characteristics of flow units and the interactions among the flow segments. The rheological parameters of relaxation time $({\beta}_2)_0$, structure factor $C_2$ and shear modulus $X_2/{\alpha}_2$ for various thixotropic flow curves was obtained by applying thixotropic equation to flow curves. The variations of rheological parameters are directly related to non-Newtonian flows, viscosities and activation energies of flow segments.

A Study for The Effect of Variation of Resin Content on The Rheological Characteristics of Ink Vehicle (수지의 함량 변화에 따른 잉크 비히클의 유변학적 특성에 관한 연구)

  • Bang, Jong-Gwan;Kim, Sung-Bin;Kim, Tae-Hwan;Lee, Kyu-Il
    • Journal of the Korean Graphic Arts Communication Society
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    • v.23 no.2
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    • pp.117-128
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    • 2005
  • Printing inks are basically dispersions of solid pigment particles in a vehicle. Pigment flocculation and/or colloidal aggregates created by thixotrope additives form a three- dimensional network in the inks. This structure complicates the flow behaviour of inks. However, if the internal structure is formed under control, the printing process will benefit from it because the ink must satify rheological requirements over a very wide range of shear conditions. The presence of internal structure results in the following prominent non-Newtonian rheological properties: viscoelasticity, yield stress, shear thinning and thixotropy. If the components of printing inks were changed, the rheological characteristics such as viscosity, yield stress, viscoelasticity and tack value were considerably varied. Thus, in this paper, the effects of changing the content of rosin modified phenolic resin on rheological properties of the vehicle will be studied. For that, the rheological properties were found by flow, yield stress, creep and oscillation measurements using Bohlin C-VOR Rotational Rheometer. And Emulsion rheology and its microstructure will be investigated.

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Influence of Rheological Properties of Lightweight Foamed Concrete on Preventing Foam Collapse (경량 기포 콘크리트의 레올로지 특성이 소포억제에 미치는 영향)

  • Lee, Hyang-Sun;Jeon, Jong-Woon;Jo, Mujin;Kee, Seong-Hoon;Han, Dongyeop
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.4
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    • pp.304-310
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    • 2018
  • The aim of the research is to provide possibility of quality controlling by rheological properties for lightweight foamed concrete. The lightweight foamed concrete achieves its low density by containing air bubbles (foam) produced during the mixing process. Therefore, containing foamed volume during setting period is critical for the securing the performance as an insulating material. In this research, regarding foam collapse during the setting period, rheolgocial properties of fresh state lightweight foamed concrete were assessed to get its relationship with volume stability, or foam stability. For the experiment regarding foaming factors including mixing time, mix design of contents for materials, rheological properties of fresh state lightweight foamed concrete were tested with its density and settling depth. Based on the settling depth with various factors, relationship with rheological properties was analyzed, and especially, close relationship of plastic viscosity and settling depth was found. Therefore, from the results of this research, it is considered to contribute on suggesting a new approach of quality controlling for lightweight foamed concrete using rheological test method.