• 한국식품과학회지
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• 제29권5호
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• pp.932-938
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• 1997

Changes in viscosity and dynamic theological properties of Job's-tears were measured by Bohlin dynamic tester as a function of moisture, and measurement was performed within a linear viscoelastic range. The result of the shear stress vs shear rate of Job's-tears at different moisture contents $(50{\sim}75%)$ was applied to mathematical models and Herschel-Bulkley model showed the highest correlation coefficient. Lower moisture content (55%) produced higher yield stress and consistency index, but lower flow behavior index, whereas higher moisture content showed reverse effects. Job's-tears with $50{\sim}70%$ moisture contents showed a higher storage modulus (G') than loss modulus (G') at all frequencies, showing a higher concentrated polymer characteristics. However, higher moisture content (>75%) showed crossover point between G' and G', and frequency dependency. As the moisture content was increased, the amount of viscoelastic properties such as G', G', complex viscosity decreased during heating, and initial temperature and miximum value of viscoelastic properties shifted to higher temperatures, representing the moisture-dependence of Job's-tears upon theological properties.

• ETRI Journal
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• 제38권6호
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• pp.1179-1189
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• 2016

A chemorheological analysis of a no-flow underfill was conducted using curing kinetics through isothermal and dynamic differential scanning calorimetry, viscosity measurement, and solder (Sn/27In/54Bi, melting temperature of $86^{\circ}C$) wetting observations. The analysis used an epoxy system with an anhydride curing agent and carboxyl fluxing capability to remove oxide on the surface of a metal filler. A curing kinetic of the no-flow underfill with a processing temperature of $130^{\circ}C$ was successfully completed using phenomenological models such as autocatalytic and nth-order models. Temperature-dependent kinetic parameters were identified within a temperature range of $125^{\circ}C$ to $135^{\circ}C$. The phenomenon of solder wetting was visually observed using an optical microscope, and the conversion and viscosity at the moment of solder wetting were quantitatively investigated. It is expected that the curing kinetics and rheological property of a no-flow underfill can be adopted in arbitrary processing applications.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2010년도 제35회 추계학술대회논문집
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• pp.300-303
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• 2010

다양한 형상의 인젝터 내부 젤 추진제 유동을 수치적으로 연구하였다. 모사 젤 추진제의 유변학적물성치를 측정하고 plain-orifice, chamfered-orifice 및 venturi 형상 인젝터의 유동 특성을 분석하였다. Plain-orifice 및 chamfered-orifice 인젝터의 경우 하류방향으로 유동이 진행할수록 점도가 높아지는 특성이 나타났으며 Venturi 형상의 경우 인젝터 내부 유동에서 낮은 점도가 지속적으로 유지됨을 알 수 있었다. Reynolds 수가 증가할수록 이러한 경향이 뚜렷하게 나타나는 것이 확인되었다.

• Carbon letters
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• 제27권
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• pp.72-80
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• 2018

In the present work, a comparative study of the mechanical behavior of two series of elastomeric composites, based on carboxylated styrene butadiene rubber (X-SBR) and reinforced with rice bran carbon (RBC) and graphite, is reported. Hybrid composites of X-SBR filled with RBC-graphite were also investigated in terms of the cure characteristics, hardness, tensile properties, abrasion resistance, and swelling. It was observed that the cure times decreased with the incorporation of a carbon filler whereas the torque difference, tensile strength, tensile modulus, hardness, and swelling resistance increased compared to the neat X-SBR revealing a favorable characteristic of crosslinking. Dynamic rheological analysis showed that the G' values of the composites, upon the addition of RBC-graphite, were changed to some extent. This demonstrates that the presence of a strongly developed network of fillers will ensure a reinforcing characteristic in a polymer matrix.

• 한국인쇄학회지
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• 제29권1호
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• pp.45-59
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• 2011

According as gradually increasing the demand for Eco-friendly products it has been progressed fairly development at a field of printing and printing inks. The Inks are used by soy oil beginning of ink industry for preventing environment. Now it is possible to make Eco-friendly inks with vegetable ester. So it is not necessary to use petroleum-based solvents for preventing environment. But There is some problems if using vegetable ester to inks. Vegetable ester has high solubility, it causes misting and low viscosity of the Inks. So resin is required high performance. Thus, in this paper, I studied about the properties variation of the Varnish and inks According to using the phenolic modified rosin ester and Soy oil Methyl esters. The compared in order of average molecular weight by the GPC method, rheological properties were found by rotational rheometer, and emulsion behavior were compared by high speed emulsification tester.

• Tribology and Lubricants
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• 제13권3호
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• pp.115-123
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• 1997

The electrorheological (ER) behavior of suspensions in silicone oil of silica gel powder (average particle size 49 $\mu$m) absorbed water was investigated at room temperature with electric fields up to 2.4 KV/mm. In this paper, for development of succcessful ER fluids used for wide temperature range later, we would like to know a fundamental understanding of water on ER effect. As a first step, the ER fluids involving water activated silica gel were measured not only the electrical characteristics such as dielectric constant, current density and electrical conductivity but also the rheological properties on the strength of electric field, the quantity of dispersed phase and absorbed water. From the experimental results that water absorbed to the particles directly affects to the surface charge density of electric double layer model proposed by Schwarz and makes dielectric constant and current density of ER fluids increase. The current density and dynamic yield stress $($\tau$_y)$ of water activated silica gel suspensions was in exponential proportion to the strength of electric field, the quantity of dispersed phase and absorbed water. And the optimum water quantity and weight concentration of silica gel for electrorheological effect were 4-5 wt% and 15 wt%, respectively.

• Structural Engineering and Mechanics
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• 제59권1호
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• pp.133-151
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• 2016

Self-Compacting Concrete (SCC) has been originally developed in Japan to offset a growing shortage of skilled labors, is a highly workable concrete, which is not needed to any vibration or impact during casting. The utilizing of fibers in SCC improves the mechanical properties and durability of hardened concrete such as impact strength, flexural strength, and vulnerability to cracking. The purpose of this investigation is to determine the effect of steel fibers on mechanical performance of traditionally reinforced Self-Competing Concrete beams. In this study, two mixes Mix 1% and Mix 2% containing 1% and 2% volume friction of superplasticizer are considered. For each type of mixture, four different volume percentages of 60/30 (length/diameter) fibers of 0.0%, 1.0%, 1.5% and 2% were used. The mechanical properties were determined through compressive and flexural tests. According to the experimental test results, an increase in the steel fibers volume fraction in Mix 1% and Mix 2% improves compressive strength slightly but decreases the workability and other rheological properties of SCC. On the other hand, results revealed that flexural strength, energy absorption capacity and toughness are increased by increasing the steel fiber volume fraction. The results clearly show that the use of fibers improves the post-cracking behavior. The average spacing of between cracks decrease by increasing the fiber volume fraction. Furthermore, fibers increase the tensile strength by bridging actions through the cracks. Therefore, steel fibers increase the ductility and energy absorption capacity of RC elements subjected to flexure.

• Elastomers and Composites
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• 제38권1호
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• pp.27-37
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• 2003

This work presents a comparative study of the morphology and structure related properties of thermoplastic elastomer blends based on SEBS/PP/Oil and dynamically vulcanized EPDM/PP/Oil. A combination of ruthenium oxide staining and low voltage scanning electron microscopy (LVSEM) was found to be suitable for the study of morphology of these highly oil extended blends. h close analogy was found in the mechanical, thermal and rheological properties of the two systems made in an internal Brabender mixer and co-rotating turin screw extruder. The morphology of the blends, as made by the two techniques, was found to be significantly different. In the case of TPVs, the blonds made in the extruder had smaller EPDM domains and better tensile properties. In the case of SEBS, the blends made in the Brabender had more co-continuous phases and showed better tensile properties. Crystallization behavior of the isotactic polypropylene in the blends was found to be influenced by the type of rubber. Blends of SEBS/PP crystallized at a lower temperature than the TPVs. These differences were probably caused by differences in the nucleating ability of the two rubbers.

• Computers and Concrete
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• 제32권2호
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• pp.185-206
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• 2023

This article aimed to explore the optimization of mineral admixtures and retarding admixture for high-performance concrete. In essence, fresh concrete can be regarded as a mixture in which both coarse and fine aggregates are suspended in a cement-based matrix paste. Based on this view, the test procedure was divided into three progressive stages of binder paste, mortar, and concrete to explore their rheological behavior and mechanical properties respectively. At each stage, there were four experimental control factors, and each factor had three levels. In order to reduce the workload of the experiment, the Taguchi method with an L9(3⁴) orthogonal array and four controllable three-level factors was adopted. The test results show that the use of the Taguchi method effectively optimized the composition of high-performance concrete. The slump of the prepared concrete was above 18 cm, and the slump flow was above 50 cm, indicating that it had good workability. On the other hand, the 28-day compressive strength of the hardened concretes was between 31.3-59.8 MPa. Furthermore, the analysis of variance (ANOVA) results showed that the most significant factor affecting the initial setting time of the fresh concretes was the retarder dosage, and its contribution percentage was 62.66%. On the other hand, the ANOVA results show that the most significant factor affecting the 28-day compressive strength of the hardened concretes was the water to binder ratio, and its contribution percentage was 79.05%.

• 한국식품과학회지
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• 제15권2호
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• pp.183-188
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• 1983

한국 재래식 국수류인 밀국수와 냉면국수의 점탄성을 연구하기 위하여 실험실에서 tensile시험기계를 만들고 이것을 이용하여 국수발에 대한 creep test를 실시하였다. 밀국수 및 냉면국수 모두 최초 단시간의 creep에서는 선형점탄성(linear viscoelastic)을 나타내었으나 creep시간이 경과함에 따라 비선형 점탄성을 나타내었다. 변형력 범위가 $4{\times}10^4-14{\times}10^4\;dyn\;cm^{-2}$일때 밀국수는 120초간, 냉면국수는 60초간 선형 점탄성을 나타내었다. 2000초 동안의 creep시험에서 추산된 밀국수의 탄성계수(elastic modulus)는 $7.0{\times}10^5\;dyn\;cm^{-2}$이었으며 냉면국수는 $3.9{\times}10^5\;dyn\;cm^{-2}$이었다. 변형력의 증가에 따른 점성변화를 평가한 결과 밀가루 반죽에서 보고된 결과와는 정반대 현상인 stress-hardening 성질을 나타내었다.