• 제목/요약/키워드: Reversible work

검색결과 69건 처리시간 0.025초

에너지의 가용성과 열역학의 재구성 (I) 가역세계 열역학 (Availability of Energy and Reconstruction of Thermodynamics(I) Thermodydamics of the Reversible World)

  • 정평석;노승탁
    • 대한기계학회논문집
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    • 제17권5호
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    • pp.1227-1236
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    • 1993
  • 본 연구에서는 또하나의 새로운 서술방식을 제시하게 되는데, 먼저 에너지 이동현상으로서의 일중에서 가용일을 분리하고, 가역과정만이 가능한 세계 즉 가역세 계 안에서 측정과 산정이 가능하도록 열역학의 가장 중요한 물리량인 온도와 엔트로피, 열 등을, 가용일의 가측성을 이용하여 정의한 다음, 그러한 제한조건하에서 기존 열역 학의 기본 법칙들이 어떻게 표시되는가 살펴보고, 이것을 비가역과정에 확장하는 식의 순서에 따라 열역학의 기존원리들에 대한 서술을 재구성하고자 한다.

가용 에너지에 의한 열역학의 재구성 (II) - 실제세계 열역학 - (Reconstruction of Thermodynamics by the Concept of Available Energy (II) - Thermodynamics of Real World -)

  • 정평석
    • 대한기계학회논문집B
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    • 제28권12호
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    • pp.1573-1581
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    • 2004
  • Thermodynamic principles are described with a new point of view. In present study, the interaction between two systems is focused instead of the behavior of a system in conventional thermodynamics. The state change of a system cannot occur by itself but it is the result of the interaction between systems. However, the interaction itself is also the result of another kind of interaction, the interaction between two interactions. To reconstruct thermodynamics with such a point of view, the reversible world is imagined, in which conservations and measurements are discussed. There exists a conserved quantity for each mode of reversible interaction. The conserved transferring quantity in the interaction between interactions is the effective work, which is supposed to be measurable and conserved in reversible world. Effective work is the primary concepts of energy. It is the key factor to explain measurements, energy conservation and energy dissipation. The concepts developed in reversible world are applied to the real world in which irreversible phenomena may occur. Irreversibility is the result of effective energy dissipation, in which effective work irreversibly changes into entropy. A quantitative relation between the disappearing effective work and the generated entropy is dissipation equation which is given by experiments. A special temperature scale to give a very simple type of the dissipation equation is the absolute temperature scale, which gives the conventional conservation of energy.

두 열적 단순계로 구성된 복합계의 열역학 (Thermodynamics of a composite system composed of two simple thermal systems)

  • 정평석;김수연
    • 대한기계학회논문집B
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    • 제21권2호
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    • pp.275-284
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    • 1997
  • Thermodynamic behavior of a composite system which is composed of two simple thermal subsystems with constant heat capacities is analyzed, and several thermodynamic phenomena are investigated. The changes of the states and the potential work of the composite system are shown as the interaction between the subsystems in the composite system. The potential work is defined as the possible maximum available work from the composite system, and it is a thermodynamic property of the composite system. The decrease of the potential work is the same as the available work output from the composite system in reversible processes. The dissipation of available work is directly connected to the generation of entropy. The concepts of exergy and internal energy can be explained as a special case of the potential work.

Degradation Evaluation of Mechanical Property for Modified 9Cr-1Mo Steel by Reversible Permeability

  • Bong, Chung-Jong;Ryu, Kwon-Sang;Nahm, Seung-Hoon;Kim, Eun-Kyu
    • Journal of Magnetics
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    • 제16권1호
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    • pp.42-45
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    • 2011
  • The present work studies a nondestructive evaluation of the degradation of modified 9Cr-1Mo steel using a magnetic method based on the existence of the peaks of reversible permeability (RP) in the differential magnetization around the coercive force. The apparatus is based on detection of the voltage induced in a coil using a lock-in amplifier tuned to the frequency of the AC perturbing field. Results obtained for the reversible permeability and Vickers hardness on the aged samples showed the peak interval of reversible permeability (PIRP) and Vickers hardness decrease as aging time increased. The correlation between Vickes hardness and the PIRP could be used to evaluate degradation of modified 9Cr-1Mo steel.

평판형 고체산화물 연료전지의 양방향 수전해 특성 연구 (Study on Reversible Electrolysis Characteristic of a Planar Type SOFC)

  • 최영재;안진수
    • 한국수소및신에너지학회논문집
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    • 제28권6호
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    • pp.657-662
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    • 2017
  • This paper presents the reversible electrolysis characteristics of a solid oxide fuel cell (SOFC) using a $10{\times}10cm^2$ anode supported planar cell with an active area of $81cm^2$. In this work, current-voltage characteristic test and reversible electrolysis cycle test were carried out sequentially for 2,114 hours at a furnace temperature of $700^{\circ}C$. The current-voltage characteristics for reversible electrolysis mode was measured at a current of ${\pm}26.7A$ under various $H_2O$ utilization conditions. The reversible electrolysis cycle was performed 50 times at a current of ${\pm}32.4A$. As a result, The performance degradation of SOEC mode was larger than that of SOFC mode.

Reversible Binary Image Watermarking Method Using Overlapping Pattern Substitution

  • Dong, Keming;Kim, Hyoung Joong;Choi, Yong Soo;Joo, Sang Hyun;Chung, Byung Ho
    • ETRI Journal
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    • 제37권5호
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    • pp.990-1000
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    • 2015
  • This paper presents an overlapping pattern substitution (PS) method. The original overlapping PS method as a reversible data hiding scheme works well with only four pattern pairs among fifteen possible such pairs. This paper generalizes the original PS method so that it will work well with an optimal pair from among the fifteen possible pattern pairs. To implement such an overlapping PS method, changeable and embeddable patterns are first defined. A class map is virtually constructed to identify the changeable and embeddable pairs. The run-lengths between consecutive least probable patterns are recorded. Experiments show that an implementation of our overlapping PS method works well with any possible type of pairs. Comparison results show that the proposed method achieves more embedding capacity, a higher PSNR value, and less human visual distortion for a given embedding payload.

가역적 데이터 은닉에서 암호화된 이미지의 공간 상관관계를 측정하기 위한 새로운 섭동 함수 연구 (New Fluctuation Functions to Measure Spatial Correlation of Encrypted Images in Reversible Data Hiding)

  • 파테마 투즈 조허라 카남;김성환
    • 한국통신학회논문지
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    • 제42권2호
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    • pp.331-337
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    • 2017
  • 본 논문에서는 암호화된 이미지에서 Zhang의 가역적 데이터 은닉 기법을 개선하는 알고리즘을 제안한다. 기존의 기법에서는 주변 픽셀의 평균값이 섭동함수로 사용되었고 모의실험 시 오류 성능이 저하됨을 확인되었다. 제안하는 시스템에서는 비트 오류율을 줄이고자 섭동을 측정 할 때 주변 함수와의 차이의 합을 더하여 계산한다. 또한 경계 픽셀을 고려한 변동함수의 새로운 계산법을 제안한다. Zhang과 Hong의 시스템과 비교 시 제안 기법의 성능이 우수함을 모의실험을 통해 확인할 수 있다. 이 결과로부터 제안 시스템을 사용할 경우 오류 없이 정보를 더 전송할 수 있음을 확인할 수 있다.

열병합발전에서 비용배분 방법론의 고찰 (Consideration of Cost Allocation Methodology on Cogeneration)

  • 김덕진
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2009년도 하계학술발표대회 논문집
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    • pp.1197-1202
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    • 2009
  • Cost allocation on cogeneration is a methodology dividing the input of common cost to electricity cost and heat cost. In the cost allocation methodology of the electricity and heat on a cogeneration, there are energy method, work method, proportional method, benefit distribution method, reversible work method, various exergetic methods, and so on. In previous study, various cost allocation methodologies have been applied and analyzed on a gas-turbine cogeneration producing the 33.1 MW of electricity and the 32.2 Gcal/h of heat, a steam-turbine cogeneration producing the 22.2 MW of electricity and the 44.3 Gcal/h of heat, and combined-cycle cogeneration producing the 314.1 MW of electricity and the 279.4 Gcal/h of heat. In this study, we integrately analyze the results of previous studies and examine the generality and rationality each methodology. Additionally, a new point of view on the values of alternative electricity efficiency and alternative heat efficiency in the previous methodologies was proposed. As the integrated result, we conclude that reversible work method of various common cost allocation methodologies is most rational.

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가스터빈 열병합발전에서 생산된 전기와 증기의 원가산정 (Cost Estimating of Electricity and Steam on a Gas-Turbine Cogeneration)

  • 김덕진
    • 설비공학논문집
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    • 제21권4호
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    • pp.252-259
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    • 2009
  • When various kinds of outputs are produced from a single energy system, the methodology which allocates the common cost to each output cost is very important because it is directly related with the profit and loss of producers and purchasers. In the cost allocation methodology of the heat and the electricity on a cogeneration, there are energy method, work method, proportional method, benefit distribution method, various exergetic methods, and so on. On the other hand, we have proposed a worth evaluation method which can be applied to any system. The definition of this methodology is that the unit cost of a product is proportion to the worth. Where, worth is a certain evaluating basis that can equalize the worth of products. In this study, we applied this methodology to a gas-turbine cogeneration which produces 119.2 GJ/h of electricity and 134.7 GJ/h of steam, and then we allocated 3,150 $/h of fuel cost to electricity cost and steam cost. Also, we compared with various cost allocation methods. As the result, we conclude that reversible work of various kinds of worth basis evaluates the worth of heat and electricity most reasonably.

Comparison of Alternate Approaches for Reversible Geminate Recombination

  • Khokhlova, Svetlana S.;Agmon, Noam
    • Bulletin of the Korean Chemical Society
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    • 제33권3호
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    • pp.1020-1028
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    • 2012
  • This work compares various models for geminate reversible diffusion influenced reactions. The commonly utilized contact reactivity model (an extension of the Collins-Kimball radiation boundary condition) is augmented here by a volume reactivity model, which extends the celebrated Feynman-Kac equation for irreversible depletion within a reaction sphere. We obtain the exact analytic solution in Laplace space for an initially bound pair, which can dissociate, diffuse or undergo "sticky" recombination. We show that the same expression for the binding probability holds also for "mixed" reaction products. Two different derivations are pursued, yielding seemingly different expressions, which nevertheless coincide numerically. These binding probabilities and their Laplace transforms are compared graphically with those from the contact reactivity model and a previously suggested coarse grained approximation. Mathematically, all these Laplace transforms conform to a single generic equation, in which different reactionless Green's functions, g(s), are incorporated. In most of parameter space the sensitivity to g(s) is not large, so that the binding probabilities for the volume and contact reactivity models are rather similar.