• Membrane Journal
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• v.14 no.1
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• pp.75-84
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• 2004

In this study, we present a noble study far membrane transport models using chlorine resistance of polyamide RO membranes. Membrane transport mechanism is investigated by the comparison of membrane permeation performance under the continuous and Intermittent operation modes with mixed feed solution containing NaOCl and NaCl. Analysis of permeation performance indicates that solution-diffusion model and preferential adsorption-capillary flow model are relatively efficient according to operation mode. Under the continuous flow state, mass transfer depends on preferential adsorption-capillary flow model rather than solution-diffusion model. On the other hand, it prefers solution-diffusion model to preferential adsorption-capillary flow model under the stationary state. SEM images of NaOCl treated membrane surfaces strongly support these conclusions. These surface images reveal that NaOCl treated membrane in continuous operation mode exhibits ridge and valley structure in some fraction of the surface area, whereas that in intermittent operation mode shows surface degradation entirely.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.3
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• pp.200-205
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• 2013

Pretreatment process is the critical step of RO (Reverse Osmosis) membrane desalination plant in order to prevent RO membrane fouling. The pretreatment as a key component of RO process must be designed to produce a constant and high quality RO feedwater which has low silt density index (SDI). This experiment was conducted to assess parameters affecting SDI value, such as pH, seawater turbidity, temperature, and coagulant dose. The experimental results indicated that the source seawater turbidity did cause little effects on SDI values of filtered water. The 0.45 um hydrophilic membrane was more appropriate than the hydrophobic membrane for measuring SDI. The SDI value was increased with decreasing pH under the condition of below pH 7.0. In addition, the water temperature significantly affected the SDI values, showing higher SDI value with lower water temperature.

• Membrane and Water Treatment
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• v.3 no.1
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• pp.25-34
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• 2012

Carboxylated polysulfone (CPS), poly (1,4-phenylene ether ethersulfone) (PPEES), membranes were prepared and used for the separation of NaCl and $CaCl_2$, in efficient way with less energy consumption. In this work, nanofiltration and reverse osmosis membranes were employed to the salt rejection behavior of the different salt solutions. The influence of applied pressure (1-12 bar), on the membrane performance was assessed. In CM series of membranes, $CM_1$ showed maximum of 97% water uptake and 36% water swelling, whereas, $CM_4$ showed 75% water uptake and 28% water swelling. In RCM series, $RCM_1$ showed 85% water uptake and 32% water swelling whereas, in $RCM_4$ it was 68% for water uptake and 20% for water swelling. Conclusively reverse osmosis membranes gave better rejection whereas nanofiltration membrane showed enhanced flux. CM1 showed 58% of rejection with 12 L/($m^2$ h) flux and $RCM_1$ showed 55% of rejection with 15 L/($m^2$ h) flux for 0.1 wt.% NaCl solution. Whereas, in 0.1 wt.% $CaCl_2$ solution, membrane $CM_1$ showed 78% of rejection with 12 L/($m^2$ h) flux and $RCM_1$ showed 63% rejection with flux of 9 L/($m^2$ h).

• Membrane Journal
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• v.4 no.4
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• pp.213-220
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• 1994

Reverse osmosis(R/O) pilot system, which consists of pretreatments and R/O membranes, was demonstrated to regenerate the petroleum refinery wastewater for the process feedwater supply. Despite of the unsteady quality of the wastewater effluent from the process facilities, relatively high salt rejection of 96~99% was obtained and the product water showed a feasible quality for the use of cooling tower feed water. The results of R/O membrane module cleaning with NaOH solution represented that there was some fouling effects on the membrane performance during the period of test due to the ineffective treatment processes proposed and used in this study.

• Nuclear Engineering and Technology
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• v.31 no.5
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• pp.506-511
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• 1999

The pilot system for radioactive liquid laundry waste was developed with treatment capacity, 1ton/hr and set up in the Yong Kwang unit #4. The system is composed of tank module, RO systems and a UV/$H_2O$$_2$photo-oxidation unit. The RO system consists of the BW unit (low-pressure RO for brackish water desalination) and the SW unit (high-pressure RO for seawater desalination). The BW unit possesses 4 RO membranes and it can reduce the feed water volume down to 1/10. This concentrated feed water can be reduced again up to 1/10 in its volume in the SW unit composed of 4 RO membranes. The UV/$H_2O$$_2$ photo-oxidation process unit was used for the detergent degradation. The operation of the pilot system was carried out and verified in its capability through the continuous operation and concentration operation using the actual liquid waste from the power plant. The design criteria and data for industrialization were yielded. The efficiency of the UV/$H_2O$$_2$ photo-oxidation process and the optimum operational procedure were evaluated. The decontamination factors for radioactive cobalt and cesium were measured. This on-site test showed the experimental result in the DF$\geq$300 and volume reduction factor$\geq$100.

• Membrane Journal
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• v.7 no.2
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• pp.75-83
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• 1997

The disc plate and frame type modules for reverse osmosis were developed using three different types of baffles: linear (Type 1), curved (Type 2) and parallel shapes (Type 3). Separation performance tests were carried out for the modules using NaCl and sucrose solutions under the various concentrations and operating pressures. The permeation flux and solute rejection ratio for Type 3 module were the highest within operating pressure (35bar) and flow rate (6 l/min). The flux improvement ratio of Type 2 or 3 to Type 1 for NaCl solution decreased as operating pressure increased: flux improvement ratios of Type 3 for 1wt% of NaCl solution were about 100 and 10% at 10 and 35bar, respectively. However, the flux improvement ratio for sucrose solutions varied with the operating pressure and concentration. The permeation flux for Type 3 depended on the flow rate linearly, which is higher than that of turbulent flow region in the smooth channel.

• Journal of Korean Society of Water and Wastewater
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• v.33 no.5
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• pp.395-404
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• 2019

The point-of-use water dispenser systems are widely used because of convenience in handling and demand for high-quality drinking water. The application has been increased recently in the public places such as department stores, universities and the rest areas in express ways. Improvement of water qualities by the dispenser systems was compared with tap water in this study. The tap water is supplied to the dispenser as the influent of the dispenser system. The twelve dispensers in the public places were used. The five dispensers used reverse osmosis as the main filter and other dispensers used various filters such as ultrafiltration, nanofiltration, and alumina filter. The water quality indicators for sanitation safety, i.e., turbidity and total coliforms, were evaluated. Other water qualities such as pH, residual chlorine, heterotrophic plate count (HPC), and total cell counts were also analyzed. By the point-of-use water dispenser, the turbidity, residual chlorine and pH were decreased and the HPC and total cell counts were increased. The t-test results revealed that the HPC of the tap waters were not significantly different from the treated waters but the total cell counts of the two groups were significantly different. The low pH of the RO filter treatment was also significantly different from the tap waters. This study will contribute to understand the role of the point-of-use water dispenser in improving water quality and to identify key water quality for the proper maintenance of the dispenser systems.

• Journal of Applied Reliability
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• v.18 no.2
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• pp.114-121
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• 2018

Purpose: This study proposes a process for evaluating the preventive maintenance policy for a system with degradation characteristics and for calculating the appropriate preventive maintenance cycle using time- and condition-based maintenance. Methods: First, the collected data is divided into the maintenance history lifetime and degradation lifetime, and analysis datasets are extracted through preprocessing. Particle filter algorithm is used to estimate the degradation lifetime from analysis datasets and prior information is obtained using LSE. The suitability and cost of the existing preventive maintenance policy are each evaluated based on the degradation lifetime and by using a minimum repair block replacement model of time-based maintenance. Results: The process is applied to the degradation of the reverse osmosis (RO) membrane in a seawater reverse osmosis (SWRO) plant to evaluate the existing preventive maintenance policy. Conclusion: This method can be used for facilities or systems that undergo degradation, which can be evaluated in terms of cost and time. The method is expected to be used in decision-making for devising the optimal preventive maintenance policy.

• Membrane Journal
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• v.31 no.5
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• pp.315-326
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• 2021

Lithium ion battery (LIB) demands increase every year globally to reduce the burden on fossil fuels. LIBs are used in electric vehicles, stationary storage systems and various other applications. Lithium is available in seawater, salt lakes, and brines and its extraction using environmentally friendly and inexpensive methods will greatly relieve the pressure in lithium mining. Membrane separation processes, mainly nanofiltration (NF), is an effective way for the separation of lithium metal from solutions. Electrodialysis and electrolysis are other separation processes used for lithium separation. The process of reverse osmosis (RO) is already a well-established method for the desalination of seawater; therefore, modifying RO membranes to target lithium metals is an excellent alternative method in which the only bottleneck is the interfering presence of other metal elements in the solution. Selectively removing lithium by finding or developing suitable NF membranes can be challenging, but it is nonetheless an exciting area of research. This review discusses in detail about lithium recovery via nanofiltration, electrodialysis, electrolysis and other processes.

• Journal of Korean Society of Water and Wastewater
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• v.34 no.6
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• pp.473-480
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• 2020

High-pressure membrane system like nanofiltration(NF) and reverse osmosis(RO) was investigated as a part of water treatment processes to produce high quality potable water with low organic matter concentration through membrane module tests and design simulation. River water and sand filtration permeate in Busan D water treatment plant were selected as feed water, and NE4040-90 and RE4040-Fen(Toray Chemical Korea) were used as NF and RO membranes, respectively. Total organic carbon(TOC) concentrations of NF and RO permeates were mostly below 0.5 mg/l and the average TOC removal rates of NF and RO membranes were 93.99% and 94.28%, respectively, which means NF used in this study is competitive with RO in terms of organic matter removal ability. Different from ions rejection tendency, the TOC removal rate increases at higher recovery rates, which is because the portion of higher molecular weight materials in the concentrated raw water with increasing recovery rate increases. Discharge of NF/RO concentrates to rivers may not be acceptable because the increased TDS concentration of the concentrates can harm the river eco-system. Thus, the idea of using NF/RO concentrate as the raw water for industrial water production was introduced. The design simulation results with feed water and membranes used in this work reveal that the raw water guideline can be satisfied if the recovery rate of NF/RO system is designed below 80%.