• 제목/요약/키워드: Reusable catalyst

검색결과 47건 처리시간 0.021초

Synthesis, Characterization and Application of Poly(4-vinylpyridine)-Supported Brønsted Acid as Reusable Catalyst for Acetylation Reaction

  • Borah, Kalyan Jyoti;Dutta, Papia;Borah, Ruli
    • Bulletin of the Korean Chemical Society
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    • 제32권1호
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    • pp.225-228
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    • 2011
  • Poly(4-vinylpyridine)-supported $Br{\phi}nsted$ acids (P4VP-HX) were prepared by wet impregnation technique. These supported acids were found as efficient heterogeneous green catalysts for acetylation of alcohol, amine and phenol with different catalytic activities. The wide application of P4VP-HX as reusable solid acid catalyst in organic reactions is possible because of its simple preparation and handling, stability, simple work up procedure.

친환경 촉매 Iron (III) phosphate: 실온/무용매 반응조건에서 알코올과 페놀의 선택적인 아실화 반응 (Iron (III) Phosphate as a Green and Reusable Catalyst Promoted Chemo Selective Acetylation of Alcohols and Phenols with Acetic Anhydride Under Solvent Free Conditions at Room Temperature)

  • Behbahani, F.K.;Farahani, M.;Oskooie, H.A.
    • 대한화학회지
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    • 제55권4호
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    • pp.633-637
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    • 2011
  • 알코올과 페놀 계 화합물을 아실화시키는 반응에서, iron (III) phosphate 촉매를 사용했을 때에, 좋은 수율로 아실화 화합물을 얻었다. Iron (III) phosphate 촉매는 또한 친환경 반응에 재사용할 수 있는 친환경 촉매이다.

Fe/Al-MCM-41: Quinoxaline계 화합물의 효율적인 합성 (Fe/Al-MCM-41: An Efficient and Reusable Catalyst for the Synthesis of Quinoxaline Derivatives)

  • Heravi, Majid. M.;Hosseini, Mariam;Oskooie, Hossein A.;Baghernejad, Bita
    • 대한화학회지
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    • 제55권2호
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    • pp.235-239
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    • 2011
  • Fe/Al-MCM-41을 촉매로 사용하여, 1,2-diamines과 1,2-dicarbonyl 화합물을 축합반응을 통하여 quinoxaline 계 화합물을 좋은 수율로 합성하였다.

Polystyrene Supported Al(OTf)3: a Stable, Efficient, Selective, and Reusable Catalyst for Sulfonylation of Arenes with Sulfonic Acids

  • Boroujeni, Kaveh Parvanak
    • Bulletin of the Korean Chemical Society
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    • 제31권7호
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    • pp.1887-1890
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    • 2010
  • Cross-linked polystyrene supported aluminium triflate (Ps-Al(OTf)$_3$) was found to be an efficient and chemoselective heterogeneous Lewis acid catalyst for the direct conversion of arenes to sulfones using sulfonic acids as sulfonylating agents. The solid acid catalyst is stable (as a bench top catalyst) and can be easily recovered and reused without appreciable change in its efficiency.

Solvent-free Synthesis of Propargylic Alcohols using ZnO as a New and Reusable Catalyst by Direct Addition of Alkynes to Aldehydes

  • Hosseini-Sarvari, Mona;Mardaneh, Zahra
    • Bulletin of the Korean Chemical Society
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    • 제32권12호
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    • pp.4297-4303
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    • 2011
  • Under solvent-free conditions, the synthesis of propargylic alcohols by direct addition of terminal alkynes to aldehydes promoted by ZnO as a novel, commercially, and cheap catalyst is described. Furthermore, the catalyst can be reused for several times without any significant loss of its catalytic activity.

Phosphomolybdic Acid Supported on Silica Gel as an Efficient and Reusable Catalyst for Cyanosilylation of Aldehydes

  • Kadam, Santosh T.;Kim, Sung-Soo
    • Bulletin of the Korean Chemical Society
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    • 제29권7호
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    • pp.1320-1322
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    • 2008
  • Phosphomolybdic acid supported on silica gel (PMA-$SiO_2$) is an efficient catalyst for the activation of TMSCN for the facile cyanosilylation of various aldehydes. Cyano transfer from TMSCN to aldehyde proceeds smoothly at rt in presence of 0.8 mol % of PMA-$SiO_2$ leading to a range of cyanosilylether in excellent yield (mostly over 93%) within short reaction time (30 min). The catalyst can be recovered and reused several times without loss of activity.

Zinc (II) [tetra(4-methylphenyl)] Porphyrin: a Novel and Reusable Catalyst for Efficient Synthesis of 2,4,5-trisubstituted Imidazoles Under Ultrasound Irradiation

  • Safari, Javad;Khalili, Shiva Dehghan;Banitaba, Sayed Hossein;Dehghani, Hossein
    • 대한화학회지
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    • 제55권5호
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    • pp.787-793
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    • 2011
  • An efficient three-component one-step synthesis of 2,4,5-trisubstituted imidazoles by condensation reaction of 1,2-diketones or ${\alpha}$-hydroxyketones with aromatic aldehydes and ammonium acetate using Zinc (II) [tetra (4-methylphenyl)] porphyrin as a novel and reusable catalyst under ultrasound irradiation at ambient temperature is described. In this method, ${\alpha}$-hydroxyketones as well as 1,2-diketones were converted to their corresponding 2,4,5-trisubstituted imidazoles in excellent yields.

Hydrated Ferric Sulfate [Fe2(SO4)3·xH2O]: An Efficient and Reusable Catalyst for One-Pot Synthesis of 2H-Indazolo[2,1-b]phthalazine-triones

  • Choudhury, Abhik;Ali, Shahzad;Khan, Abu T.
    • 대한화학회지
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    • 제59권4호
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    • pp.280-283
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    • 2015
  • Hydrated ferric sulfate can be used as an efficient and reusable catalyst for the synthesis of 2H-indazolo[2,1-b]phthalazine-trione derivatives via one-pot three-component condensation reaction of phthalhydrazide, aromatic aldehydes and cyclic-1,3-diketones in ethanol under reflux conditions.