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http://dx.doi.org/10.5012/bkcs.2008.29.7.1320

Phosphomolybdic Acid Supported on Silica Gel as an Efficient and Reusable Catalyst for Cyanosilylation of Aldehydes  

Kadam, Santosh T. (Department of Chemistry, Inha University)
Kim, Sung-Soo (Department of Chemistry, Inha University)
Publication Information
Bulletin of the Korean Chemical Society / v.29, no.7, 2008 , pp. 1320-1322 More about this Journal
Abstract
Phosphomolybdic acid supported on silica gel (PMA-$SiO_2$) is an efficient catalyst for the activation of TMSCN for the facile cyanosilylation of various aldehydes. Cyano transfer from TMSCN to aldehyde proceeds smoothly at rt in presence of 0.8 mol % of PMA-$SiO_2$ leading to a range of cyanosilylether in excellent yield (mostly over 93%) within short reaction time (30 min). The catalyst can be recovered and reused several times without loss of activity.
Keywords
PMA-SiO2; Heterogeneous catalysis; Cyanosilylation; Aldehydes
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Times Cited By Web Of Science : 7  (Related Records In Web of Science)
Times Cited By SCOPUS : 9
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