• Title/Summary/Keyword: Retention rate

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A study on simultaneous determination of carbamate pesticides by HPLC (HPLC를 이용한 carbamate계 농약의 다성분 동시분석)

  • Song, Young-Gak;Seo, Young-Chul;Hyun, Gong-Yul;Cho, Woo-Young;Lee, Jong-In
    • Korean Journal of Veterinary Service
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    • v.26 no.2
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    • pp.145-149
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    • 2003
  • To explore the most sensitive and useful method for simultaneous determination of 8 carbamate pesticides in livestock productions, the mixture of 8 carbonates was determined by HPLC with scanning fluorescence detector. For mobile phase water, acetonitrile and methanol program gradient showed more applicable sensitivity than water and acetonitrile program gradient used ExW 339 nm and EmW 445 nm for fluorescence detector. On using carbamate columns, the retention time was within 4 to 20 minutes. And this made it possible to separate and detect simultaneously. therefore we could analyze it exactly and efficiently and reduce time. The preparation process of MSPD method showed that the high recovery rate was more than 88.5% in most of the carbamate pesticides. Therefore we could say that it was an efficient and fast method analyzing out of lots of samples.

Reestimation of Hydrologic Design Data in Donghwa Area (동화지구 절계 수문량 재추정)

  • Kwon, Soon-Kuk;Lee, Jae-Hyoung;Jung, Jae-Sung;Chon, Il-Kweon;Kim, Min-Hwan;Lee, Kyung-Do
    • Journal of The Korean Society of Agricultural Engineers
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    • v.46 no.6
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    • pp.3-10
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    • 2004
  • The fundamental study of hydrologic redesign of Donghwa area located in a sccond tributary of Seomjin river was performed. The amounts of hydrologic design were estimated using the available cumulated hydrology data provided by Korea Agricultural and Rural Infrastructure Corporation (KARICO). The management status of The water resources in Donghwa area was also widely surveyed. The probability rainfalls, probable maximum precipitation (PMP) and probability floods were estimated and subsequently their changes analyzed. The amount of 200 year frequency rainfall with l day duration was 351.1 mm, 2.5 % increased from the original design value, and The PMP was 780.2 mm. The concentration time was reestimated as 2.5 hours from existing 2.4 hours. Soil Conservation Service(SCS) method was used to estimate effective rainfall- The runoff curve number was changed from 90 to 78, therefore the maximum potential retention was 71.6 mm, 154 % increased from the original value. The Hood estimates using SCS unit hydrograph showed 8 % increase from original value 623 $m^3$/s to 674 $m^3$/s and The probable maximum Hood was 1,637 $m^3$/s. Although the Row rate at the dam site was increased, the Hood risk at the downstream river was decreased by the Hood control of the Donghwa dam.

Quantitative Analysis of Pulegone in Schizonepeta tenuifolia Briq. (국산과 중국산 형개의 Pulegone함량분석)

  • Kim, Ho-Kyoung;Lee, A-Yeong;Lee, Hye-Won;Chun, Jin-Mi;Choi, Ji-Hyun;Shin, Ja-Won;Ko, Byoung-Seob
    • Applied Biological Chemistry
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    • v.49 no.2
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    • pp.125-128
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    • 2006
  • Schizonepeta tenuifolia Briq. are used in folk medicine as common cold, sore throat, headache and skin infection in Korea, China and Japan. To compare the contents of domestic and Chinese Schizonepeta tenuifolia quantitative HPLC analysis was performed using a Luna $C_{18}$ column $(4.6{\times}250\;mm,\;5{\mu}m)$, with 1 ml/min of flow rate of 0.01% formic acid in water : acetonitrile = 50 : 50 under UV 254 nm of detector. Pulegone was detected at retention time of about 17.14 min.

Analysis of 4-year experimental data from water quality improvement of inflow stream in estuary using wetland (인공습지를 이용한 하구담수호 유입하천수의 4년간 실험결과 분석)

  • Kim, Hyung-Chul;Yoon, Chun-Gyeong;Han, Jung-Yoon;Lee, Sae-Bom;Shin, Hyun-Bhum
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2005.10a
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    • pp.557-562
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    • 2005
  • The field scale experiment was performed to examine the effect of plant coverage on the constructed wetland performance and recommend the optimum development and management of macrophyte communities. Four sets(each set of 0.88ha) of wetland (0.8ha) and pond(0.08ha) systems were used. Water flowing into the Seokmoon estuarine reservoir from the Dangjin stream was pumped into wetland system. Water depth was maintained at $0.3{\sim}0.5m$ and hydraulic retention time was managed to about $2{\sim}5$ days; emergent plants were allowed to grow in the wetlands. After three growing seasons of the construction of wetlands, plant coverage was about 95%, even with no plantation, from bare soil surfaces at the initial stage. Dead vegetation affected nitrogen removal during winter because it is a source of organic carbon which is an essential parameter in denitrification. Biomass harvesting is not a realistic management option for most constructed wetland systems because it could only slightly increase the removal rate and provide a minor nitrogen removal pathway due to lack of organic carbon.

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The Physical Property of PET Coolness Knitted Fabric for High Emotional Garment (고감성 의류용 PET 냉감 니트 소재의 물성)

  • Kim, Hyun Ah;Woo, Ji Yoon;Kim, Seung Jin
    • Textile Coloration and Finishing
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    • v.26 no.2
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    • pp.114-123
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    • 2014
  • This research investigated the physical properties of PET coolness filaments and their knitted fabrics including dyeing characteristics of these knitted fabrics according to the different dyeing time and temperature. The coolness filament(S) with non-circular cross-section and hydrophilic property was spun and another commercialized coolness(A) and regular(R) PET filaments were prepared for comparing coolness and another physical properties. Qmax of coolness knitted fabric made with S filament was higher than that of R-PET filament, and the maximum value of Qmax of S knitted fabric was shown at the dyeing conditions of temperature, $110^{\circ}C$ with 30 min. or 40min. It was shown that hand of S knitted fabric was a little harsh comparing to A and regular knit specimens, but shape retention and wearing performance of garment made with S knit specimen were estimated as good owing to high bending and shear rigidity. K/S of S knitted fabric was higher than those of regular PET and A knit specimens. Dyeing fastness of coolness knitted fabric showed between 4th and 5th grade.

Analysis of body size selectivity of by-catch using the cover net method for a shrimp beam trawl

  • Kim, Yonghae
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.51 no.2
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    • pp.171-178
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    • 2015
  • Selectivity and by-catch are the main features used to define fish catch for fisheries management or to determine fishing gear efficiency. A fish girth distribution analysis was carried out to determine the retention rate of juveniles discarded and to establish common selectivity for a multispecies catch. Total body length, body weight, and girth of juvenile fish retained in the cod-end and cover net separately were collected using an 18-mm mesh cover net during 12 fishing trials with a 41-mm cod-end beam trawl. The by-catch weight ratio in the cod-end was twice that of the by-catch ratio in number. The 50% selectivity of body length and 50% girth of redfin velvet fish were not significantly different between the cod-end and cover net, whereas those of other fish species were significantly different between the cod-end and cover net. The difference in 50% selectivity girth of other fish between the cod-end and cover net was similar between cod-end mesh size and cover net mesh size. Furthermore, the difference in 50% body length selectivity of other fish between the cod-end and cover net was almost double the difference in girth. Girth selectivity in a multispecies catch using towed fishing gear was effectively used to determine fish and net mesh size.

A Study on the Comparison to Source Profile of the Major Terpenes from Pine Tree and Korean Pine Tree (소나무와 잣나무에서 배출되는 주요 테르펜의 배출특성에 관한 비교연구)

  • 지동영;김소영;한진석
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.6
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    • pp.515-525
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    • 2002
  • A field study was conducted to estimate the emission rate of biogenic volatile organic compounds (BVOCs) from pine trees. In addition, the influences of meteological variables on their distribution characteristics have been investigated. A vegetation enclosure chamber was designed and constructed of Tedlar bag and acril. Sorbent tubes made up of Tenax TA and Carbotrap were used to collect biogenic VOCs emitted from each individual tree. Analysis of BVOCs was performed using a GC-FID system. The fundamental analytical parameters including linearity, retention time, recovery efficiency, and breakthrough volume were examined and verified for the determination of monoterpene emission rates. Total average concentration of each component is found to be $\alpha$-pinene (16.5), $\beta$-pinene (4.61) from pine trees, and $\alpha$-pinene (42.4), $\beta$-pinene (18.7 ng(gdw)$^{-1}$ hr$^{-1}$ ) from Korean pine trees. On the basis of our study, $\alpha$-pinene was found to be the major monoterpene emitted from both pine and Korean pine trees which were accompanied by $\beta$-pinene, camphene, and limonene. In ambient air, variable monoterpene compositions of emissions from pine trees were similar to Korean pine trees. Emission rates of monoterpene from each tree were found to depend on such parameters as temperature and solar radiation.

Changes in Physico-Chemical Properties of Salted Sea Mustard (Undaria Pinnatifida) by Gamma Irradiation (염장미역의 감마선 조사에 따른 이화확적 특성 변화)

  • 변명우;권중호;이수정;남상명;조한옥
    • Journal of Food Hygiene and Safety
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    • v.6 no.3
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    • pp.165-169
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    • 1991
  • The effect of gamma irradiation on physico-chemical properties of salted sea mustard (Undaria pinnatifida) was investigated. Chlorophyll and carotenoid pigment of salted sea mustard were partially decreased by irradiation. However there was no significant difference in the retention rate of pigment between control and 2 kGy-irradiated samples after six months of storage at around $10^{\circ}C$, ranging values of 74 to 77% in chlorophyll and 54 to 56% in carotenoid. Total organic acids and volatile acids associated with the organoleptic quality of sea mustard increased in the samples of lower salt concentrations and of higher storage temperatures. The softening of sample tissue by irradiation was shown to be correlated with the extraction properties of alginic acid.

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On the Influence of Estradiol on the Radioactive Calcium Metabolism in Blood, Bone and Young of Lactating Rate (Estradiol이 수유백서(授乳白鼠)의 혈청(血淸), 골(骨) 및 자아(仔兒)의 방사성(放射性) Calcium 대사(代謝)에 미치는 영향(影響)에 관(關)한 연구(硏究))

  • Rha, K.Y.;Chang, Y.S.;Park, K.B.;Rhee, C.H.
    • The Korean Journal of Nuclear Medicine
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    • v.2 no.1
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    • pp.49-52
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    • 1968
  • The influence of estradiol on the radioactive calcium metabolism in blood, bone and young of lactating rats has been studied. Estrogen, in an amount estimated to equal that secreted in late pregnancy, was injected daily into lactating rats for 4 days along with $^{45}Ca$. On the 5th day, radioactivity of blood serum, bone, and young was compared to a similar group of lactating rats not treated with estrogen. Average gain in weight of the litters of the 2 groups was similar. However, radioactivity in serum and bones of treated with estradiol was significantly higher than in the controls. The radioactivity in litters of the 2 groups was similar. Estrogen plays a role in the retention of calcium in the animal body.

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High-Performance Liquid Chromatographic Analysis of Chrysin Derivatives on A $Nova-Pak^{\circledR}C_{18}$ Column

  • Kim, Kyoung-Soon;Shin, Joon-Su;Park, You-Mie;Lee, Sanghyun;Kim, Yang-Bae;Kim, Bak-Kwang
    • Archives of Pharmacal Research
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    • v.25 no.5
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    • pp.613-616
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    • 2002
  • A high-performance liquid chromatographic method has been developed for the separation and quantification of chrysin and synthetic chrysin derivatives (12 chrysin alkyl and 7 chrysin acyl derivatives). The chromatography was performed using a $Nova-Pak^{\circledR}C_{18}$ column. A RP-HPLC was performed by using a binary mixture (MeOH-10 mM H$_3$PO$_4$) as a mobile phase, and the column temperature was maintained at room temperature. A flow rate was 1.0 ml/min, and the effluent was monitored at a wavelenth of 280 nm. The retention times for chrysin acyl and alkyl derivatives were within 10 minutes and 20 minutes, respectively. The absolute recovery of samples were all over 96%. The detection limits were 0.1~18 ng at S/N = 3 ratio.