• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2003년도 추계학술발표논문집
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• pp.306-330
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• 2003

The wet-end dynamics of a paper mill was analyzed to characterize its dynamic behavior during the grade change. The model representing the wet-end section is developed based on the mass balance relationships written for the simplified wet-end white water network. From the linearization of the dynamic model, higher-order Laplace transfer functions were obtained followed by the reduction procedure to give simple lower-order models in the form of $1^{st}$-order or $2^{nd}$-order plus dead times. The dynamic response of the wet-end is influenced both by the white water volume and by the level of wire retention. Effects of key manipulated variables such as the thick stock flow rate, the ash flow rate and the retention aid flow rate on the major controlled variables were analyzed by numerical simulations. The simple dynamic model developed in the present study can be effectively used in the operation and control.

• 펄프종이기술
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• 제35권5호
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• pp.26-36
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• 2003

The wet-end dynamics of a paper mill was analyzed to characterize its dynamic behavior during the grade change of paper. The model representing the wet-end section is developed based on the mass balance relationships written for the simplified wet-end white water network. From the linearization of dynamic model, higher-order Laplace transfer functions were obtained followed by the reduction procedure to give simple lower-order models in the form of 1$^{st}$-order or 2$^{nd}$ -order plus dead times. The dynamic response of the wet-end is influenced both by the white water volume and by the level of wire retention. Effects of key manipulated variables such as the thick stock flow rate, the ash flow rate and the retention aid flow rate on the major controlled variables were analyzed by numerical simulations. The simple dynamic model developed in the present study can be effectively used in the operation and control of paper mills.s.

• Bulletin of the Korean Chemical Society
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• 제32권2호
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• pp.590-594
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• 2011

An aminocarboxy aspartic acid-bonded silica (Asp-Silica) stationary phase was synthesized using L-aspartic acid as ligand and silica gel as matrix. The standard protein mixtures were separated with prepared chromatographic column. The effects of solution pH, salt concentration and metal ion on the retention of proteins were examined, and also compared with traditional iminodiacetic acid-bonded silica (IDA-Silica) column. The results show that Asp-Silica column exhibited an excellent separation performance for proteins. The retention of proteins on Asp-Silica stationary phase was consistent with electrostatic characteristic of cation-exchange. The stationary phase displayed typical metal chelate property after fixing copper ion (II) on Asp-Silica. Under competitive eluting condition, protein mixtures were effectively isolated. Asp ligand showed better ion-exchange and metal chelating properties as compared with IDA ligand.

• Bulletin of the Korean Chemical Society
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• 제13권1호
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• pp.75-79
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• 1992

Differences in chromatographic properties in RPLC of four brands of cyano bonded silica stationary phases are rationalized in terms of the type and relative strength of the solute-stationary phase interactions, which can be readily inferred from multiple linear regression analyses of retention data for a set of standard compounds on the stationary phases under study based on the linear solvation energy relationships (LSERs). Although four brands of cyano bonded columns studied (CPS-Hypersil, Ultrasphere cyano, Spherisorb-CN and ${\mu}$-Bondapak-CN) have similar bonding density and have been prepared from monofunctional cyanopropylsilane reagents, they possess quite different, relative hydrogen bonding (HB) donor and acceptor strengths. Comparison of the retention behavior on a cyano-bonded silica column with that on an ODS column shows that there are significant differences in the strength of HB interactions between the solute and the stationary phase on the two columns with different functionalities. Information on the differences in the interaction characteristics among brands of the cyano-bonded silica columns and between the ODS and cyano-bonded columns can be utilized to optimize the selectivity for a given separation on these columns.

• 한국재료학회지
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• 제29권12호
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• pp.812-817
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• 2019

A zinc-air battery is one of most promising advanced batteries due to its high specific energy density, low cost, and environmental friendliness. However, zinc anodes in zinc-air batteries lead to several issues including self-discharge, corrosion reaction, and hydrogen evolution reaction (HER). In this paper, viscosity of electrolyte has been controlled to suppress the corrosion reaction, HER, and self-discharge behavior. Various viscosity average molecular weights of poly(acrylic acid) (PAA) are adopted to prepare the electrolyte. The evaporation of electrolytes is proportional to the increase in molecular weight. In addition, enhanced self-discharge behavior is obtained when the gelling agent with high molecular weight is used. In addition, the zinc-air cell assembled with lower viscosity average molecular weight of PAA (M_v ~ 450,000) delivers 510.85 mAh/g and 489.30 mAh/g of discharge capacity without storage and with 6 hr storage, respectively. Also, highest capacity retention (95.78 %) is obtained among studied materials.

• 한국지반신소재학회논문집
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• 제5권2호
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• pp.9-15
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• 2006

흙막이벽 굴착배면지반의 변형거동을 해석을 하기 위하여 강제변위법을 이용한 수치해석 프로그램을 개발하였다. 굴착지반의 구성모델은 Drucker Prager의 비선형 탄소성구성방정식을 적용하였으며, 리턴매핑법으로 탄소성해를 구하였다. 수치해석 프로그램의 타당성을 검증하기 위하여 수치해석으로부터 얻은 굴착배면지반의 수평변위와 현장계측결과를 비교하였다. 검토결과 수치해석 프로그램의 정확도는 상당히 높은 것으로 나타났다.

• 한국강구조학회 논문집
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• 제19권4호
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• pp.357-366
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• 2007

본 연구는 비대칭 H형강을 사용한 슬림플로어 보의 화재시 구조성능에 관한 실험 및 해석적 연구로서, 화재시 본 합성부재의 구조거동을 파악하여 합리적 내화설계의 자료를 얻는 것이 목적이다. 화재실험으로 계획된 여러 변수의 시험체를 제작하고 상온과 고온에서 휨실험을 수행하여 시간에 따른 온도분포, 하중-처짐 관계를 분석하였다. 해석적 방법은 설계된 단면에 대하여 완전 합성을 가정으로, 열전도 해석으로 온도분포를 구하고 재료의 잔존강도를 분할된 메쉬에 입력하여 휨강도를 예측하였다. 웨브의 두께와 깊이를 변수로 하여 슬림플로어 보의 화재시 휨내력을 고찰하였다.

• Food Science and Biotechnology
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• 제15권4호
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• pp.572-577
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• 2006

The physiochemical interactions of 1-methylcyclopropene (1-MCP) and adsorbing agents can be described using a very powerful tool, inverse gas chromatography (IGC). Sorption behavior of 1-MCP on various adsorbing agents was assessed using the profile peaks of 1-MCP at an infinite dilution concentration using the IGC technique. Chromatogram peaks of 1-MCP adsorption were not observed for the adsorbing agent activated carbon. The forms of sorption isotherms followed Henry's law, and behaved according to the binding site theory. Specific retention volume and distribution coefficients for 1-MCP on the adsorbing agents were determined at 50, 60, 70, and $80^{\circ}C$, respectively. Silica gel had a much higher number of binding sites for 1-MCP compared to Tenax-TA and activated clay agents. Meanwhile, activated carbon proved to be a very strong binding agent for 1-MCP based on 1-MCP efficiency experiments on the selected adsorbing agents. However, as a proper means of delivering 1-MCP molecules to fresh food products, activated carbon is not fit for the binding and release of 1-MCP gas under dry or high humidity conditions because activated carbon has a strong affinity for 1-MCP, even when treated with distilled water.

• 한국지반공학회논문집
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• 제40권3호
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• pp.7-18
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• 2024

산사태 예측을 위하여 불포화토 거동을 고려한 비탈면 안정성 평가를 수행하였다. 태풍 힌남노시 집중강우로 인한 실제 산사태 현장에서 시료를 채취하였다. 팽창성 불교란 시료와 팽창이전 상태에 대한 재성형시료에 대하여 증발법을 기반으로 함수특성시험을 수행하였다. 이러한 수리-역학적 특성을 고려하여 2차원 침투해석 및 안정해석을 수행하였다. 그 결과, 두 시료는 해석 결과에서 뚜렷한 차이를 보였으며 팽창성 불교란시료의 거동이 실제 비탈면 파괴를 잘 예측할 수 있었다.

• 한국지반공학회논문집
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• 제30권1호
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• pp.37-47
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• 2014

불포화 수리전도도는 Mualem 모세관 모델에 의하여 이론적으로 함수특성곡선으로부터 적분된다. 하지만 예측된 수리전도도는 포화 부근에서 모관흡수력의 미소한 변화에도 극도로 민감하다. 원활한 형태의 함수특성곡선에 의한 Mualem 수리전도도는 포화 부근에서 급격하게 감소하며, 수리적 거동을 신뢰할 수 있게 모델하지 못하거나 수치해의 안정성을 저해 한다. van Genuchten-Mualem(VGM) 수리전도도를 개선하기 위하여, 낮은 모관흡수력 수준에 있는 임의의 공기함입치이내에서 van Genuchten 함수특성곡선을 수정하였다. 수정 VG 곡선은 대수축에서 임의의 공기함입치에서 포화상태까지 선형화된다. 수정 VG 함수특성곡선은 실제 함수특성거동의 회귀분석에 영향을 끼치지 않으며 원래의 VG 함수특성곡선의 계수를 그대로 사용한다. 수정 VG 곡선을 이용하여, VGM 수리전도도는 임의의 공기합입치를 기준으로 구간별 적분하여 수정되었다. 수정 VGM 수리전도도가 해석적 해로 제안되었으며, 포화부근 영역에서 수리전도도가 급격하게 감소하는 현상이 제거되었다. 실제 사면의 2차원 침투해석을 통하여 VGM 수리전도도와 제안된 모델에 따른 수리거동을 비교하였다. 제안된 모델은 여러 강우조건에 따른 해의 수렴성을 확보하였지만, VGM 수리전도도를 적용하면, 포화부근의 수리전도도가 급격하게 감소하여 강우량이 많은 경우 해가 수렴하지 않았다. 특히 선행강우에 의한 초기 안전율과 집중강우 후 최종 안전율을 크게 평가할 수 있었다. 제안된 수리전도도 모델은 침투해석과 안정해석을 통하여 실제 사면의 붕괴를 재현할 수 있었다.