• Title/Summary/Keyword: Resistance-capacitance

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Electrochemical Properties of Electric Double Layer Capacitor with PolyanilineComposite (Polyaniline Composite 전극을 사용한 전기 이중층 캐패시터의 전기화학적 특성)

  • 강광우;김종욱;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.370-373
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    • 1999
  • The purpose of this study is to research and develop PAn composite electrode for EDLC. EDLC cell of PAn composite electrode with 1M LiClO$_4$/PC brings out good capacitor performance below 4.0V. The radius of semicircle of PAn composite electrode adding 15wt% SP270 was absolutely small. The total resistance of EDLC cell mainly depended on internal resistance of the electrode. The discharge capacitance of PAn composite with 15wt% SP270 in 1st and 200th cycles was 42 and 42 F/g at current density of 1mA/cm$^2$. The capacitance of PAn composite with 15wt%. SP270 capacitor was larger than that of PAn capacitor without SP270. The coulombic efficiency of EDLC at discharge process of 1 and 200 cycles were 94 and 100% respectively. PAn composite EDLC with 15wt% SP270 content showed good capacitance and stability with cycling.

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EnhAnced Electric Double Layer Capacitance of New Poly Sodium 4-tyrenesulfonate Intercalated Graphene Oxide Electrodes

  • Jeong, Hye-Gyeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.287.2-287.2
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    • 2013
  • We synthesized a new composite of poly sodium 4-styrenesulfonate intercalated graphene oxide for energy storage devices by controlling oxidation time in the synthesis of graphite oxide. Specific capacitance was improved from 20 F/g of the previous composites to 88 F/g of the new composite at the current density of 0.3 A/g. The capacitance retention was 94% after 3000 cycles, indicating that the new composites of high cyclic stability, prominent performance as electric double layer capacitor, and even low resistance could be an excellent carbon based electrode for further energy storage devices.

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Circuit Performance Prediction of Scaled FinFET Following ITRS Roadmap based on Accurate Parasitic Compact Model (정확한 기생 성분을 고려한 ITRS roadmap 기반 FinFET 공정 노드별 회로 성능 예측)

  • Choe, KyeungKeun;Kwon, Kee-Won;Kim, SoYoung
    • Journal of the Institute of Electronics and Information Engineers
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    • v.52 no.10
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    • pp.33-46
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    • 2015
  • In this paper, we predicts the analog and digital circuit performance of FinFETs that are scaled down following the ITRS(International technology roadmap for semiconductors). For accurate prediction of the circuit performance of scaled down devices, accurate parasitic resistance and capacitance analytical models are developed and their accuracies are within 2 % compared to 3D TCAD simulation results. The parasitic capacitance models are developed using conformal mapping, and the parasitic resistance models are enhanced to include the fin extension length($L_{ext}$) with respect to the default parasitic resistance model of BSIM-CMG. A new algorithm is developed to fit the DC characteristics of BSIM-CMG to the reference DC data. The proposed capacitance and resistance models are implemented inside BSIM-CMG to replace the default parasitic model, and SPICE simulations are performed to predict circuit performances such as $f_T$, $f_{MAX}$, ring oscillators and common source amplifier. Using the proposed parasitic capacitance and resistance model, the device and circuit performances are quantitatively predicted down to 5 nm FinFET transistors. As the FinFET technology scales, due to the improvement in both DC characteristics and the parasitic elements, the circuit performance will improve.

Performance Optimization Study of FinFETs Considering Parasitic Capacitance and Resistance

  • An, TaeYoon;Choe, KyeongKeun;Kwon, Kee-Won;Kim, SoYoung
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.14 no.5
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    • pp.525-536
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    • 2014
  • Recently, the first generation of mass production of FinFET-based microprocessors has begun, and scaling of FinFET transistors is ongoing. Traditional capacitance and resistance models cannot be applied to nonplanar-gate transistors like FinFETs. Although scaling of nanoscale FinFETs may alleviate electrostatic limitations, parasitic capacitances and resistances increase owing to the increasing proximity of the source/drain (S/D) region and metal contact. In this paper, we develop analytical models of parasitic components of FinFETs that employ the raised source/drain structure and metal contact. The accuracy of the proposed model is verified with the results of a 3-D field solver, Raphael. We also investigate the effects of layout changes on the parasitic components and the current-gain cutoff frequency ($f_T$). The optimal FinFET layout design for RF performance is predicted using the proposed analytical models. The proposed analytical model can be implemented as a compact model for accurate circuit simulations.

A Study on the Equivalent Model of an External Electrode Fluorescent Lamp Based on Equivalent Resistance and Capacitance Variation

  • Cho, Kyu-Min;Oh, Won-Sik;Moon, Gun-Woo;Park, Mun-Soo;Lee, Sang-Gil
    • Journal of Power Electronics
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    • v.7 no.1
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    • pp.38-43
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    • 2007
  • An External Electrode Fluorescent Lamp (EEFL) has longer lifespan, higher power efficiency and higher luminance than a Cold Cathode Fluorescent Lamp (CCFL). Moreover, it is easy to drive them in parallel. Therefore, the EEFL is expected to quickly replace the CCFL in LCD backlight systems. However, the EEFL has more complex characteristics than the CCFL with a resistive component, because it has both a resistive component by plasma and a capacitive component by external electrode. In this paper, values of resistance and capacitance are measured at several power levels and at several operating frequencies. They are expressed by a numeral formula based on a linear approximation that represents the equivalent resistance and capacitance as a function of power. Then we made block diagram of the equivalent circuit model using numerical expressions. Simulation waveforms and experimental results are presented to verify the feasibility of the equivalent model.

Development of a variable resistance-capacitance model with time delay for urea-SCR system

  • Feng, Tan;Lu, Lin
    • Environmental Engineering Research
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    • v.20 no.2
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    • pp.155-161
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    • 2015
  • Experimental research shows that the nitric oxides ($NO_X$) concentration track at the outlet of selective catalytic reduction (SCR) catalyst with a transient variation of Adblue dosage has a time delay and it features a characteristic of resistance-capacitance (RC). The phenomenon brings obstacles to get the simultaneously $NO_X$ expected to be reduced and equi-molar ammonia available to SCR reaction, which finally inhibits $NO_X$ conversion efficiency. Generally, engine loads change frequently, which triggers a rapid changing of Adblue dosage, and it aggravates the air quality that are caused by $NO_X$ emission and ammonia slip. In order to increase the conversion efficiency of $NO_X$ and avoid secondary pollution, the paper gives a comprehensive analysis of the SCR system and tells readers the key factors that affect time delay and RC characteristics. Accordingly, a map of time delay is established and a solution method for time constant and proportional constant is carried out. Finally, the paper accurately describes the input-output state relation of SCR system by using "variable RC model with time delay". The model can be used for a real-time correction of Adblue dosage, which can increase the conversion efficiency of $NO_X$ in SCR system and avoid secondary pollution forming. Obviously, the results of the work discover an avenue for the SCR control strategy.

Effect of Thermal Treatment Temperature on Electrochemical Behaviors of Ni/trimesic Acid-based Metal Organic Frameworks Electrodes for Supercapacitors (수퍼커패시터용 니켈/트리메식 산 기반 금속-유기구조체 전극의 전기화학적 거동에 열처리 온도가 미치는 효과)

  • Kim, Jeonghyun;Jung, Yongju;Kim, Seok
    • Applied Chemistry for Engineering
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    • v.30 no.1
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    • pp.11-16
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    • 2019
  • Ni-benzene-1,3,5-tricarboxylic acid based metal organic frameworks were successfully synthesized by hydrothermal method and thermally treated at various temperature. The electrochemical performance of composites was investigated using cyclic voltammetry, galvanostatic charge-discharge, and electrochemical impedance spectroscopy. Among all prepared composites, the samples annealed at $250^{\circ}C$ showed the highest capacitance with a low resistance, and high cycle stability. It was possible to obtain the low electrical resistance and high electric conductivity of the electrode by improved microstructure and morphology after the thermal annealing at $250^{\circ}C$. The samples annealed at $250^{\circ}C$ also displayed the maximum specific capacitance with a value of $953Fg^{-1}$ at a current density of $0.66A/g^{-1}$ in 6 M KOH electrolyte. Moreover, a 86.4% of the initial specific capacitance of the composite was maintained after 3,000 times charge-discharge cycle tests. Based on these properties, it can be concluded that the composite could be applied as potential supercapacitor electrode materials.

A Study on Measuring Electrical Capacitance to Access the Volumetric Water Content of Simulated Soil

  • Rial, W.S.;Han, Y.J.
    • Agricultural and Biosystems Engineering
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    • v.1 no.1
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    • pp.30-37
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    • 2000
  • Wet porous media representing agronomic soil that contains variable water content with variable electrolyte concentration was measured to study the shape of the curves of the electric double layer capacitance versus frequency (from 10 KHz to 10 MHz. This was done in an attempt to find the lowest practical operating frequency for developing low cost dielectric constant soil moisture probes. Cellulose sponge was used as the porous media. A high frequency electronic bridge circuit was developed for measuring the equivalent network parallel resistance and capacitance of porous media. It appears that the effects of the electric double layer component of the total parallel network capacitance essentially disappear at operating frequencies greater than approximately 25 MHz at low electrolyte concentrations but are still important at 50 MHz at higher concentrations. At these frequencies, the double layer capacitance masks the diffusion region capacitance where true water content capacitance values reside. The general shape of the curve of volumetric water content versus porous media dielectric constant is presented, with an empirical equation representing data for this type of curve. It was concluded that the lowest frequency where dielectric constant values which represent true water content information will most likely be found is between 30 and 50 MHz at low electrolyte concentrations but may be above 50 MHz when the total electrolyte concentration is near the upper level required for most mesophyte plant nutrition.

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Capacitance Properties of Degraded Thyristor with Temperature and Voltage (가속열화된 사이리스터의 커패시턴스 특성)

  • Seo, Kil-Soo;Lee, Yang-Jae;Kim, Hyeng-Woo;Kang, In-Ho;Kim, Nam-Kyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.131-132
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    • 2005
  • In this paper, the capacitance properties of degraded thyristor with temperature and voltage were presented. As degraded thyristor, 8 thyristors with each other different reverse blocking voltage used. Its impedance and resistance properties were measured from frequency 100Hz to 10MHz applied with bias voltage from 0V to 40V. As a result, at low frequency region, that is, at the frequency 100 - 10kHz, the abrupt increasement of its capacitance was confirmed. And also, at high frequency region, the capacitance peak move toward low frequency in the region of frequency 4 - 6MHz as degradation of thyristor.

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The Effective Capacitance of a Constant Phase Element with Resistors in Series

  • Byoung-Yong, Chang
    • Journal of Electrochemical Science and Technology
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    • v.13 no.4
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    • pp.479-485
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    • 2022
  • The power of energy storage devices is characterized by capacitance and the internal resistance. The capacitance is measured on an assumption that the charges are stored at the electrode interface and the electric double layer behaves like an ideal capacitor. However, in most cases, the electric double layer is not ideal so a constant phase element (CPE) is used instead of a capacitor to describe the practical observations. Nevertheless, another problem with the use of the CPE is that CPE does not give capacitance directly. Fortunately, a few methods were suggested to evaluate the effective capacitance in the literature. However, those methods may not be suitable for supercapacitors which are modeled as an equivalent circuit of a CPE and resistor connected in series because the time constant of the equivalent circuit is not clearly studied. In this report, in order to study the time constant of the CPE and find its equivalent capacitor, AC and DC methods are utilized in a complementary manner. As a result, the time constants in the AC and DC domains are compared with digital simulation and a proper equation is presented to calculate the effective capacitance of a supercapacitor, which is extended to an electrochemical system where faradaic and ohmic processes are accompanied by imperfect charge accumulation process.