• Corrosion Science and Technology
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• 제6권2호
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• pp.62-67
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• 2007

Several heavy duty coatings at an every kind industry facilities to various systems currently have been applied review to the many industry fields. Corrosion-protective characteristics in the case of novolac epoxy among them and unsaturated polyester have been applied most widely. epoxy and flake heavy duty coatings are applied for such reason in an every kind facilities(stack, FGD, cooler, chemical tank etc) of a fossil-fuel power plants Cases of the fossil-fuel power plants are exposed to more severe corrosion environment compared with other facilities and It is difficult to display the performance of long-term method at apply to be the partial. Our study shows fluoro-polymer composite coating method to overcome of the limit. The comparison did previous method and heavy duty coating about FGD plants most at a corrosion environment among fossil-fuel power plants. Additionally, other facilities examined different heavy duty method. The design mode of fluoro-polymer composite coating according to an every kind facilities show extensive methods that are characteristic revelation of film(top, middle and primer layer) composition of the paint, film thickness in accordance with a facilities corrosion and the corrosion protective effectiveness to come into being use fluoro-polymer composite with heavy duty paint(epoxy).

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2021년도 봄 학술논문 발표대회
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• pp.195-196
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• 2021

The pore distribution of the cement mortar mixed with carbon nanotubes was found to have a large number of pores at (370~80)㎛, and the distribution ratio was larger as the carbon nanotubes were mixed. However, the pores with a fine particle diameter of (10-0.5) ㎛ were found to be larger as the carbon nanotubes were incorporated. However, the distribution of pores of the test specimens of conductive cement mortar with deterioration damage was found to be distributed in a number of particle diameters of (500 to 100) ㎛ and (10 to 0.5) ㎛. It is judged that the particle diameter of the internal pores increased due to the damage. However, as the mixing ratio of the test specimen with carbon nanotubes increased, the distribution of voids was relatively lower than that of plain, and it was judged to have excellent resistance to deterioration damage.

• International Journal of Concrete Structures and Materials
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• 제6권3호
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• pp.145-153
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• 2012

The aim of this study is to explore the possibility of re-cycling a waste material that is now produced in large quantities, while achieving an improvement of the mechanical properties and durability of the mortar. This study examines the mechanical properties and the durability parameters of mortars incorporating plastics bag wastes (PBW) as fine aggregate by substitution of a variable percentage of sand (10, 20, 30 and 40 %). The influence of the PBW on the, compressive and flexural strength, drying shrinkage, fire resistance, sulfuric acid attack and chloride diffusion coefficient of the different mortars, has been investigated and analyzed in comparison to the control mortar. The results showed that the use of PBW enabled to reduce by 18-23 % the compressive strength of mortars containing 10 and 20 % of waste respectively, which remains always close to the reference mortar (made without waste). The replacement of sand by PBW in mortar slows down the penetration of chloride ions, improves the behavior of mortars in acidic medium and improves the sensitivity to cracking. The results of this investigation consolidate the idea of the use of PBW in the field of construction.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 봄학술 발표회 논문집(II)
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• pp.305-308
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• 2005

The sulfuric acid may react with the hardened cement paste and originate expansive products which can induce swelling and disaggregation of concrete. The purpose of this study is to estimate the antibacterial performance of antibiotics and the effect of absorbed condition of restorative mortar, the number of coating times and coating contents with antibiotic on the fundamental properties of restorative mortar spead with antibiotics. Also, testing items such as bonding strength, abrasion contents, contents of water absorption, contents of air permeability was tested to estimate the fundamental properties in this study. In results, the novellus bacillus inhabiting in sewer concrete structures was restrained by antibiotics developed in this study. And bonding strength of restorative mortar spread with antibiotics was similla to that of plain mortar. But, resistance to abrasion, water absorption and air permeability of restorative mortar spread with antibiotics was superior to that of plain mortar.

• 한국표면공학회지
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• 제49권2호
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• pp.125-129
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• 2016

Anodizing is a technology to generate thicker and high-quality films than natural oxide films by treating metals via electrochemical methods. Electrochemical manufacturing method of nano structure is an efficient technology in terms of cost reduction, high productivity and complicated shapes, which receives the spotlight in diverse areas. Especially, artificial films generated by anodizing technology possess excellent mechanical characteristics including hardness and wear resistance. It is also easy to modify thickness and adjust shape of those artificial films so that they are mainly used in sensors, filters, optical films and electrolytic condensers. In this study, experiment was performed to observe the effect of current density on porous film formation in two-step anodizing for Al alloy. Anodizing process was performed with 10 vol.% sulfuric acid electrolyte while the temperature was maintained at $10^{\circ}C$ using a double beaker. and $10{\sim}30mA/cm^2$ was applied for 40 minutes using a galvanostatic method. As a result, both pore diameters and distances between pores tended to increase as the local temperature and electrolysis activity increased due to the increase in applied current density.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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• pp.227-232
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• 2002

To evaluate the practical application of oyster shells as construction materials, an experimental study was performed. More specifically, the long-term mechanical properties and durability of concrete blended with oyster shells were investigated. Test results indicate that long-term strength of concrete blended with 10% oyster shells is almost identical to that of normal concrete. However, the long-term strength of concrete blended with 20% oyster shells Is appreciably lower than that of normal concrete. 1'hereby, concrete with higher oyster shell has the possibility giving a bad influence on the concrete long-term strength. Elastic modulus of concrete blended with crushed oyster shells decreases as the blending mixture ratio increases. Namely, the modulus is reduced by approximately 10∼15% when oyster shells are blended up to 20% replacing the fine aggregate. The drying shrinkage strain increases as the blending ratio increases. In addition, the existing model code of drying shrinkage does not coincide with the test results of this study. An adequate prediction equation needs to be developed. The utilization of oyster shells as the fine aggregate in concrete has an insignificant effect on freezing and thawing resistance, carbonation and sulfuric acid attack of concrete recycling. However, water permeability is considerably improved.

• 한국건설순환자원학회논문집
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• 제9권4호
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• pp.545-552
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• 2021

본 연구에서는 산업부산물인 탈황석고 및 페로니켈슬래그 미분말을 혼합한 진동전압방식 모르타르의 강도 및 내구성의 평가를 실시한다. VR관 제작시 사용되는 석회석미분말 25% 치환을 기준으로 탈황석고 및 페로니켈슬래그 미분말을 복합치환하고, 진동전압방식을 사용하여 시편을 제작하였다. 강도발현 특성을 평가하기 위해 휨 및 압축강도를 실시하였으며, 내구성을 평가하기 위해 염소이온침투저항성 및 내황산저항성 시험을 실시하였다. 휨 및 압축강도에서 혼화재 중 탈황석고의 비율이 20~60% 범위에서 강도가 향상되었으며, 탈황석고의 비율이 20~80% 범위에서 염소이온침투저항성 시험에서 통과 전하량이 감소하는 경향을 보였다. 내황산저항성은 탈황석고의 비율이 40%인 경우 침지기간에 따른 강도 및 질량 감소율이 줄어들었다. 강도 및 내구성 실험결과를 기초로 탈황석고 및 페로니켈슬래그 미분말을 적절하게 혼합해서 사용한다면 강도 및 내구성에서 성능 개선 효과를 기대할 수 있다고 판단된다.

• Bulletin of the Korean Chemical Society
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• 제31권12호
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• pp.3697-3702
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• 2010

We demonstrate that vertically aligned carbon nanotubes can be synthesized directly on tantalum substrate via water-assisted chemical vapor deposition and evaluate their properties as electrochemical capacitors. The mean diameter of the carbon nanotubes was $7.1{\pm}1.5\;nm$, and 70% of them had double walls. The intensity ratio of G-band to D-band in Raman spectra was as high as 5, indicating good quality of the carbon nanotubes. Owing to the alignment and low equivalent series resistance, the carbon nanotube based supercapacitors showed good rate performance. Rectangular shape of cyclic voltammogram was maintained even at the scan rate of > 1 V/s in 1 M sulfuric acid aqueous solution. Specific capacitance was well-retained (~94%) even when the discharging current density dramatically increased up to 145 A/g. Consequently, specific power as high as 60 kW/kg was obtained from as-grown carbon nanotubes in aqueous solution. Maximum specific energy of ~20 Wh/kg was obtained when carbon nanotubes were electrochemically oxidized and operated in organic solution. Demonstration of direct synthesis of carbon nanotubes on tantalum current collectors and their applications as supercapacitors could be an invaluable basis for fabrication of high performance carbon nanotube supercapacitors.

• 한국자기학회지
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• 제3권3호
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• pp.221-228
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• 1993

고밀도기록용 박막재료로서의 충족조건은 높은 보자력, 높은 포화자화, 생산성, 그리고 화학적 안정성으로써 수직자기기록매체 CoCrMo 자성박막을 RF 스퍼터링 방법으로 제조한 후, 부식 특성을 전기화학적 측정, acceleration corrosion test 및 부식후 박막의 표면분석을 통하여 조사 하였다. CoCrMo 박막의 부식특성은 스퍼터링 조건에 따라서 다르게 나타났으며, Mo의 함량이 증가 할수록 내식성은 향상되었다. 전기화학부식실험 결과 박막의 Mo 함량이 증가할수록 뚜렷한 활성- 불활성 전이를 나타내었으며 부동태전류밀도의 감소를 나타내었다. Accelerated corrosion test에 서 CoCrMo 박막의 부식은 전기화학반응에 의하여 일어났으며 Mo첨가에 따라 부식이 일어난 곳의 수는 감소하였다. AES분석결과 부식 장소에는 많은 양의 $Cl_{-}$ 이온이 존재하였고, Cr의 고갈이 부식의 원인이었다.

• 폴리머
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• 제37권4호
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• pp.518-525
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• 2013

폴리프로필렌(PP)을 매트릭스로, 황산처리된 녹조류(SGA)를 보강재로 사용한 바이오복합재료(biocomposites)의 기계적 특성을 향상시키기 위해 그래핀(GNP)의 평균입자크기와 첨가량에 따른 SGA/GNP/PP 복합재료를 제조하고 그 특성을 분석하였다. GNP의 첨가량에 의해 굴곡강도 및 충격강도는 점차 감소하는 경향을 나타내었다. 반면에, SGA와 GNP의 영향으로 인해 굴곡탄성률 및 저장탄성률은 크게 증가하였다. 평균입자크기가 $5{\mu}m$(GNP5)인 크기가 작은 GNP를 보강재로 사용하였을 경우 평균입자크기가 $15{\mu}m$(GNP15)인 GNP를 보강재로 사용한 복합재료와 비교하여 상대적으로 우수한 기계적 특성을 보였다. 이는 상대적으로 GNP5의 효과적인 분산에 기인한 것이다. 반면에, GNP5를 보강재로 사용한 복합재료의 열팽창에 대한 저항 특성은 GNP15와 비교하여 상대적으로 감소한 결과를 나타내었으며, 이는 열전도 특성이 우수한 GNP5가 상대적으로 넓고 고르게 분포되어있기 때문에 복합재료 전체에 열이 쉽게 전달되었기 때문으로 해석할 수 있었다. 결과적으로 SGA/GNP/PP 복합소재는 굴곡저항, 저장탄성률, 댐핑특성 등은 충분히 향상되어 범용 바이오컴포지트로 적용가능하였다.