• Title/Summary/Keyword: Resin synthetic

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Cyclodextrin Glucanotransferase의 고정화와 당전이 스테비오사이드 제조에 관련된 반응 특성

  • In, Man-Jin;Kim, Dong Chung;Chae, Hee Jeong;Choi, Kyung Seok;Kim, Min-Hong
    • Microbiology and Biotechnology Letters
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    • v.25 no.3
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    • pp.305-310
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    • 1997
  • For the continuous production of transglucosylated steviosides, cyclodextrin glucanotransferase from Bacillus macerans was immobilized onto Diaion HPA 75 (styrene-divinylbenzene resin) that was screened from ion exchange resins, synthetic adsorbents and chitosan derivatives. The parameters influencing enzyme immobilization were examined in order to maximize the activity of immobilized enzyme. The optimum conditions for immobilization turned out to be: contact time 2 hr at 30$circ$C, pH 6$sim$9, and enzyme loading 20mg protein/g resin at 4.4 Os/Kg as osmolarity. Competing with other molecules having low molecular weight, enzyme was immobilized reversibly. The activity of immobilized enzyme was as high as 180U/g resin when the diafiltrated solution of stock enzyme was used. The optimum conditions for transglucosylation were as follows: pH 6.0, temperature 50$circ$C, 30% substrate solution composed of 15% stevioside mixture and 15% dextrin of which value of dextrose equivalent was about 9.0.

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A REPORT ON THERMAL LAG OF PAINTED HEAT DETECTORS (도막상태에 따른 열감지기의 감온특성에 관한 시험, 연구(2))

  • Lee, Bok-Yeong;Yu, In-Ho
    • Fire Protection Technology
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    • s.15
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    • pp.11-21
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    • 1993
  • This report is announced about thermal lag of painted heat detectors. Thermal lag is forecast result from painting the part of heat receiving. Test is simulated that heat detector is painted by synthetic resin emulsion paint according to the cricumstance of installation, corrosion, temperature, dust.

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Fabrication of isotropic bulk graphite using artificial graphite scrap

  • Lee, Sang-Min;Kang, Dong-Su;Kim, Woo-Seok;Roh, Jea-Seung
    • Carbon letters
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    • v.15 no.2
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    • pp.142-145
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    • 2014
  • Isotropic synthetic graphite scrap and phenolic resin were mixed, and the mixed powder was formed at 300 MPa to produce a green body. New bulk graphite was produced by carbonizing the green body at $700^{\circ}C$, and the bulk graphite thus produced was impregnated with resin and re-carbonized at $700^{\circ}C$. The bulk density of the bulk graphite was $1.29g/cm^3$, and the porosity of the open pores was 29.8%. After one impregnation, the density increased to $1.44g/cm^3$ while the porosity decreased to 25.2%. Differences in the pore distribution before and after impregnation were easily confirmed by observing the microstructure. In addition, by using an X-ray diffractometer, the degrees-of-alignment (Da) were obtained for one side perpendicular to the direction of compression molding of the bulk graphite (the "top-face"), and one side parallel to the direction of compression molding (the "side-face"). The anisotropy ratio calculated from the Da-values obtained was 1.13, which indicates comparatively good isotropy.

The study of free formaldehyde remained in resin finished fabrics (수지가공시 중에 잔존한 유리 Formaldehyde에 관한 연구)

  • Song Wha Soon;Cho Seung Sik;Kim Sung Reon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.2 no.1
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    • pp.125-131
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    • 1978
  • This study was intended to clarify (1) the release of free formaldehyde (2) transfer of free formaldehyde to the contacted fabrics during storing, and (3) the removal effect of free formaldehyde by washing from resin finished fabrics. The results of this study were as follow; 1. The decrease rate of free formaldehyde content in fabrics was higher during storing in open air, poly bag, and glass tube in descending order and the content of free formaldehyde in fabrics was decreased in glyoxal resin finished but, increased in Melamine M-3 resin finished when the fabrics was stored in polybag and in glass tube. 2. Increased amount of formaldehyde transfer to contacted fabrics was noted with Melamine M-3 resin finished than that of glyoxal resin finished. Increased amount of formaldehyde transfer as well as more free formaldehyde were noted in cotton fabrics than in polyester/ cotton blend. 3. The effect of removing free formaldehyde from the fabrics was better in case of solid alkaline soap, synthetic alkaline powdered detergents, neutral detergents in descending order. The romoval of free formaldehyde was marked after the 1st washing and almost no increase in free formaldehyde was found after three times of washing. 4. After first washing, the content of formaldehyde in Melamine M-3 resin finished fabrics increased more rapidly than that of glyoxal resin finished fabrics in condition of closed storing.

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Experimental Study on Reducing Effect for Surface Temperature of Recycled Synthetic-Resin Permeable Block (재생 합성수지 투수블록의 표면온도 저감효과에 관한 실험적 연구)

  • Lee, Chul-Hee;Lee, Arum;Shin, Eun-Chul;Ryu, Byung-Hyun
    • Journal of the Korean Geosynthetics Society
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    • v.18 no.1
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    • pp.79-89
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    • 2019
  • The field measurement and laboratory experiment were conducted to investigate the effect of reducing the surface temperature of the functional aspect of the heat island phenomenon of the permeable block which is made the recycled synthetic resin rather than the existing concrete permeable block. Field measurement was taken for 3 days in consideration of dry condition and wet condition and laboratory experiment was divided into dry condition, rainfall simulating condition, and wetting condition. The variations of temperature and the evaporation rate of water moisture content after experiment were confirmed. As a result of field measurement, it is confirmed that the surface temperature decreases due to the difference in albedo of the pore block surface rather than the cooling effect due to the latent heat of vaporization. The evaporation of moisture in a dry state where drought persisted or a certain level of moisture was not maintained in the surface layer. As a result of laboratory experiment, resin permeable block gives higher surface temperature when it is dry condition than concrete permeable block, but the evaporation of water in the pore is kept constant by capillary force in rainfall simulation condition, and higher temperature reduction rate. As a result of measuring the evaporation rate after laboratory experiment, it is confirmed that the effect of reducing temperature is increased as the evaporation rate of water is higher. Based on these results, correlation formula for evaporation rate and temperature reduction rate is derived.

Anti-static behavior of Synthetic fabrics treated by anti-static agents (대전방지처리된 합성섬유의 대전성에 관한 연구)

  • Choi Suk-Chul;Kim Mi-Sung
    • Journal of the Korean Society of Clothing and Textiles
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    • v.11 no.1
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    • pp.51-62
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    • 1987
  • In this study, electrostatic behavior of polyester and nylon fabric treated with anti-static agents were investigated. The effects of the concentration of the agents and curing conditions on the electrostatic charge of the fabrics were studied. And washfastness, lightfastness and physicalproperties of the treated fabrics were also investigated. The results were as follows: 1) Polyethylene glycol alkylester was more effective in antistatic behavior than polyethylene laurylphosphate, and polyester is more effective in anti-static behavior than nylon. 2) Concentration of anti-static agents were suitable in concentration of $4\%$. 3) Glyoxal resin was more effective in anti-static behavior than melamine resin, and it was also good in the retaing anti-static behavior after treatments of lightfastness and washfastness. 4) As the condition of curing treatment, $190^{\circ}C$, 1min. for glyoxal resin and $130^{\circ}C$, 4min. for melamine resin is appropriate. 5) In comparison of anti-static behavior according to treating conditions, the simultaneous treatment was more effective than any other treatments. 6) Change of electrostatic charge of anti-static nylon cloths after treatments of lightfastness and washfastness increased greatly in above 10 laundering time and 20 fade-O-meter time. 7) In physical properties according to concentration of treating agents. decrease of physical properties scarcely appeared in concentration of treating agents $4\~5\%$.

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Experimental Studies on the Improving Surface Hardness of Dental Stone (치과용(齒科用) 경석고(硬石膏) 의 표면경도(表面硬度) 강화(强化)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Kim, Chang-Whe
    • The Journal of Korean Academy of Prosthodontics
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    • v.9 no.1
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    • pp.23-27
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    • 1969
  • The purpose of this studies is to determine the surface hardness of dental stone and to investigate the methods which increase the surface hardness of dental stone using the dissolved solution of various synthetic resin, the obtained results of hardness value calculated Rockwell Hardness Number by means of Rockwell Hardness Tester. 1) In this experiment, 10% polystyrene dissolved in 100cc amylacetate is excellent solution which provides the surface hardness of dental stone after setting of specimen, and there is no effective way that stone specimen is immersed into polystyrene in amylacetate, polystyrene in benzene and polystyrene in butylacetate above 1 hour. 2) When the stone specimen is immersed into acrylic resin in benzene and melamin resin in amylacetate at least 1 hour to 3 hours, the hardening effect of stone surface is valuable. 3) The stone specimen immersing into urea resin in butylacetate, the surface hardness of the stone specimen decreased within 1 hour, but increased after 3 houre. 4) For the separating medium, the easyfoil is superior to the olive oil in the aspect of improving the hardening effect of the immersed specimen.

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Resin Synthesis of 1-Aza-15-Crown-5-Styrene-divinylbenzene with Crosslink (가교도를 가진 1-Aza-15-Crown-5-스틸렌-디비닐벤젠 수지 합성)

  • 박성규;김준태;노기환
    • Journal of environmental and Sanitary engineering
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    • v.17 no.1
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    • pp.63-68
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    • 2002
  • Amount of styrene and divinylbenzene(DVB) was adjusted under injection of nitrogen, copolymer having crosslink of 1%, 2% and 5% was synthesized and zinc chloride was added to it. Put into benzene, swell it, add potassium iodide and 1-aza-15-crown-5 of 21.93g in toluene solution and functional resin which can adsorb heavy metal ions by stir reflex at $55^{\circ}C$ for 30 hours was synthesized. The content of divinylbenzene of this resin was increased as crosslink increase, macroporous gets smaller and the content of chlorine was reduced, which affects macrocyclic ligand in the process of substitution and content of nitrogen was also reduced. And the form of functional synthetic resin was distorted by substitution reaction of hydrogen and chlorine atoms.

Adsorption of Metal Ions on Synthetic Resin with Styrene Hazardous Materials in Water Fire Extinguishing Agent (물 소화약제에서 스타이렌 위험물을 포함한 합성수지에 의한 금속 이온들의 흡착)

  • Lee, Chi-Young;Kim, Joon-Tae
    • Applied Chemistry for Engineering
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    • v.21 no.2
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    • pp.142-147
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    • 2010
  • Cryptand resins have been synthesized from 1-aza-18-crown-6 macrocyclic ligand attached to styrene (2th petroleum in 4th class hazardous materials) divinylbenzene copolymer with crosslinkage of 1%, 2%, 10%, and 18% by substitution reaction. The synthesis of these resins was confirmed by the content of chlorine, element analysis, surface area (BET), and IR-spectroscopy. The effects of pH, time and crosslinkage on adsorption of metal ion from water fire extinguishing agentby synthetic resin adsorbent were investigated. Metal ions showed a great adsorption over pH 3 and adsorption equilibriumof metal ions was about two hours. The adsorption selectivity determined in water was in the increasing order of sodium ($Na^{1+}$) > zinc ($Zn^{2+}$) > chromium ($Cr^{3+}$) ion. The adsorption was in the order of 1%, 2%, 10%, and 18% crosslinkage resin.

Separation of Ni(II), Co(II), Mn(II), and Si(IV) from Synthetic Sulfate and Chloride Solutions by Ion Exchange (황산과 염산 합성용액에서 이온교환에 의한 니켈(II), 코발트(II), 망간(II) 및 실리케이트(IV)의 분리)

  • Nguyen, Thi Thu Huong;Wen, Jiangxian;Lee, Man Seung
    • Resources Recycling
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    • v.31 no.3
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    • pp.73-80
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    • 2022
  • Reduction smelting of spent lithium-ion batteries at high temperature produces metallic alloys. Following solvent extraction of the leaching solutions of these metallic alloys with either sulfuric or hydrochloric acid, the raffinate is found to contain Ni(II), Co(II), Mn(II), and Si(IV). In this study, two cationic exchange resins (Diphonix and P204) were employed to investigate the loading behavior of these ions from synthetic sulfate and chloride solutions. Experimental results showed that Ni(II), Co(II), and Mn(II) could be selectively loaded onto the Diphonix resin from a sulfate solution of pH 3.0. With a chloride solution of pH 6.0, Mn(II) was selectively loaded onto the P204 resin, leaving Ni(II) and Si(IV) in the effluent. Elution experiments with H2SO4 and/or HCl resulted in the complete recovery of metal ions from the loaded resin.