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Adsorption of Metal Ions on Synthetic Resin with Styrene Hazardous Materials in Water Fire Extinguishing Agent  

Lee, Chi-Young (Department of Clinical Pathology, Gwangju Health College)
Kim, Joon-Tae (Department of Chemistry, Chosun University)
Publication Information
Applied Chemistry for Engineering / v.21, no.2, 2010 , pp. 142-147 More about this Journal
Abstract
Cryptand resins have been synthesized from 1-aza-18-crown-6 macrocyclic ligand attached to styrene (2th petroleum in 4th class hazardous materials) divinylbenzene copolymer with crosslinkage of 1%, 2%, 10%, and 18% by substitution reaction. The synthesis of these resins was confirmed by the content of chlorine, element analysis, surface area (BET), and IR-spectroscopy. The effects of pH, time and crosslinkage on adsorption of metal ion from water fire extinguishing agentby synthetic resin adsorbent were investigated. Metal ions showed a great adsorption over pH 3 and adsorption equilibriumof metal ions was about two hours. The adsorption selectivity determined in water was in the increasing order of sodium ($Na^{1+}$) > zinc ($Zn^{2+}$) > chromium ($Cr^{3+}$) ion. The adsorption was in the order of 1%, 2%, 10%, and 18% crosslinkage resin.
Keywords
1-aza-18-crown-6; macrocyclic ligand; styrene; crosslinkage; divinylbenzene;
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