• Title/Summary/Keyword: Resin series

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Synthesis of Ultra High Refractive Index Monomer for Plastic Optical Lens and Its Ophthalmic Lens Preparation (플라스틱 안경렌즈용 초고굴절 모노머 합성 및 이를 이용한 안경렌즈 제조)

  • Jang, Dong Gyu;Kim, Jong Hyo;Lee, Soo Min;Roh, Soo Gyun
    • Journal of Korean Ophthalmic Optics Society
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    • v.13 no.3
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    • pp.1-6
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    • 2008
  • Purpose: Plastic optical monomer materials having ultra high refractive index have an income of the whole quantity from advanced nations to domestic companies which are related to plastic optical lens. It is necessary to develop novel plastic optical lens materials in order to overcome a FTA provision and revitalize a stagnating optical lens industry in the interior optical lens industries. The new plastic optical lens materials against the substitution effect of income should be gradually demanded. This work will be synthesized novel super high refractive monomer resin materials of urethane lens series and studied the properties of optical lens using it. Methods: ETS-4 (2-(2-mercaptoethylthio)-3-{2-[3-mercapto-2-(2-mercaptoethylthio)propyl thio]ethylthio}propane -1-thiol), which is optical lens monomer resin having super high refractive index, was synthesized and identified its structure and property by elemental analysis, EI-MS, TGA, FT-IR spectroscopy, $^1H$ and $^{13}C$ NMR spectroscopies. After mixing evenly from mixed monomer resin and diisocyanate series, it was casting in glass mold. After thermal curing, the obtained optical lenses were measured and compared with the refractive index and Abbe number for studies of their optical properties. Results: We have synthesized the novel ultra high refractive index monomer resin, ETS-4, and have identified its structure and property by elemental analysis, EI-MS, TGA, FT-IR spectroscopy, $^1H$ and $^{13}C$ NMR spectroscopies. The existence of three isomers for EST-4 was identified by $^{13}C$ NMR spectroscopy. The refractive index ($N_d$ at $25^{\circ}C$) of monomer resin in liquid state obtained from the Abbe refractometer was 1.647. The refractive indexes of raw plastic optical lenses prepared from the mixed ETS-4 monomer and diisocyanate series were in the range of 1.656~1.680. Conclusions: Novel super high refractive index plastic optical lens monomer was synthesized and analysed, the optical lenses prepared using it were colorless transparency and excellent properties. It is of utility for the industrialization.

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A Study on the Antibiosis and Physical & Mechanical Characteristics of Dental Resin (치과용 레진의 항균성 및 물리·기계적 특성에 대한 연구)

  • Kim, Ju-Won;Choi, Sung-Suk
    • Journal of Korean society of Dental Hygiene
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    • v.4 no.2
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    • pp.179-191
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    • 2004
  • A series of experiments were conducted on dental denture base resins for their antibiosis. They were also compared in terms of physical and mechanical characteristics, which led to the following results: 1. As for bacterial deposition, the old products showed a wide range of distribution, while those products containing C. S. had restraints. 2. Among the products containing C. S., those ones of 7, 12 and 20% all had restraints of similar size to slop further bacterial growth. In the meanwhile, the old products had only small-size restraints for bacterial growth. 3. The following changes were observed in the aspect physical characteristics: There were no significance between the old products and the C. S. products. Thus, as for compressive force, the average${\pm}$standard deviation of the old products was $27.4083.{\pm}1.7397$, and those C. S. products of 20% showed the similar $27.5600{\pm}.1976$. In addition, there were no significance between the old products and those ones containing C. S. in terms of tensile force. The tensile force of the old products was $114.5600{\pm}.8916$ in average${\pm}$standard deviation, while there was no differences among the C. S. products of 7, 12, and 20% in that matter.

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Analysis on the Hot-spot Temperature Location of a 24MVA Cast Resin Transformer by FEM (FEM을 이용한 24MVA 몰드변압기의 Hot-spot 위치 분석 연구)

  • Kim, Yong-Bae;Ha, Jung-Woo;Shin, Pan-Seok
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.26 no.9
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    • pp.26-32
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    • 2012
  • This paper calculates the core and copper losses as heating sources of a 24MVA cast resin transformer, and analyzes the thermal distribution of the transformer to find out its hot-spot area by FEM program. Since the winding of the transformer is composed with many series and parallel circuits, the analyzing model of the winding is simplified and modelled by axi-symmetric domain. As the results, the maximum temperature is estimated by $137^{\circ}C$ in the upper part of the low-voltage winding. The maximum temperature has discrepancy of approximately $10^{\circ}C$, which is able to be considered as an acceptable error range in the design stage of power transformers. For the overall pattern of the temperature distribution is almost same as test results, the analyzing method can be a useful tool to find out a hot-spot area of the winding.

The Effects of Injection Molding Conditions of Polypropylene on the Linear Shrinkage and Weight of Molded Parts (폴리프로필렌의 사출성형조건이 성형품의 선형수축률과 중량에 미치는 영향)

  • 유중학;김희송
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.2
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    • pp.322-329
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    • 1995
  • Series of experimental work was performed to mold tensile specimens by using the injection molding machine Mold temperature, melt temperature and packing time were chosen as processing parameters for studying the effects of those conditions on the linear shrinkage of final product. Here, each processing variable was decided from the numerical simulation and resin manufacturer's suggested value. The effects of molding conditions on the linear shrinkage in flow direction of the resin were analyzed by measuring the parts 2, 10, 30 and 60 days after molding. As a result, the linear shrinkage increased with the higher mold and melt temperature, and the change of mold temperature has shown more influence. The linear shrinkage of polypropylene has been found to progress up to 30 day with the lapse of the time, and the amount of the linear shrinkage has shown to be between 2.14% and 2.75%. In addition, the effects of packing pressure on the weight has shown to be extremely significant up to freezing time, and proper packing time of the tensile specimen has been found to be 2.0 seconds.

Conservation Treatment of Comb-shaped Bone Jewelry from Daeseong-dong Tomb No.88, Gimhae (김해 대성동 88호분 출토 골제 빗 모양 장신구의 보존처리)

  • Kim, Midori;Choi, Jiae
    • Conservation Science in Museum
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    • v.16
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    • pp.114-121
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    • 2015
  • Two pieces of comb-shaped jewelry which are made of animal bones were discovered in Daeseong-dong tomb No.88 in Gimhae. Foreign material was removed from the surface of the objects using ethanol and various small instruments. Fractures or cracks were repaired using cellulose-type synthetic resin and epoxy resin. Acrylic paint was applied repaired areas to match the color and finished conservation treatment. The two comb-shaped accessories, although differing in number of teeth and thickness, were produced by using the same method. A series of fine bone pieces, shaped like comb teeth, are placed between two long bones, assuming animal ulnas, and are fastened together by tying silk thread around them several times, then by placing a coat of lacquer.

Case series of implant-supported fixed prostheses using a high-performance polymer (PEKK) framework veneered with three different materials for six years (고기능성 폴리머(PEKK)를 프레임워크로 하는 임플란트 지지 고정성 보철물의 6년 경과관찰 증례)

  • Yeon-Kyung Park;Ji-Suk Shim;Jeong-Yol Lee
    • The Journal of Korean Academy of Prosthodontics
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    • v.62 no.1
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    • pp.20-27
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    • 2024
  • As a high-performance polymer, Polyetherketoneketone (PEKK) has good biocompatibility and excellent physical properties and is used in several areas, including dentistry. Many successful cases of implant-supported fixed prostheses with a PEKK framework have been reported; however, a long-term observation of the reported cases and discussion of complications are not available. In this case report, we present three cases of implant-supported fixed prostheses with a PEKK framework veneered with composite resin, lithium disilicate crown, and high-impact polymethyl methacrylate (PMMA), and discuss their 6-year follow-up results.

A Study on Rheology Characteristics of Ag Paste for Screen Printing Method for Silicon Solar Cells Electrodes Capable of Forming High Aspect Ratio (고온 소결형 실리콘 태양 전지의 High Aspect Ratio 전극 형성이 가능한 Ag 페이스트의 레오로지 특성 연구)

  • Oh, Tae-Hun;Kim, Sung-Bin;Nam, Su-Yong
    • Journal of the Korean Graphic Arts Communication Society
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    • v.28 no.1
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    • pp.15-24
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    • 2010
  • Photovoltaic solar cells are all in the incident because they are not converted into electrical energy, high-efficiency solar cells in order to reduce the loss of elements must be. Significant factor in the loss of solar cells, optical loss and electrical loss can be divided into. Optical losses occur when the sun will be joined on the surface of the reflection, the shadow loss due to electrodes, and the losses are in the solar wavelengths. Commercialization is currently the most common solar cells on the front of the light incident on the electrode is formed. Therefore, the shadow caused by the electrode to cover the dead area of the sun, due to factors that hinder the absorption of sunlight which is shadowing them and conversion efficiency of solar cells is the inhibition factor. These barriers to eliminate the electrode linewidth reduces the shadowing to reduce, but simply of the electrode line width is reduced electrode area by reducing the series resistance elevates this because to improve the electrode Aspect ratio(height/width) to increase Ag development of paste is required. In this study, aspect ratio of screen-printing method to increase the electrode Ag paste composition of the binder for the characterization of rheology in the shadow of the electrode by reducing the optical loss of the photoelectric conversion efficiency of solar cells to boost the performance measures was. Properties and printability of the paste, the binder resin sintered characteristics that affect the thermal properties are excellent with a good screen printability acrylic resin, ethyl cellulose, using a resin were evaluated. Prepared paste rheology properties, was formed to evaluate the electrode conductivity and aspect ratio.

Effect of Bentonite on the Mechanical Properties of ABS Resin (Bentonite가 ABS 수지의 기계적 물성에 미치는 영향)

  • Don, Yoon-Seung;Shim, Mi-Ja;Kim, Sang-Wook
    • Applied Chemistry for Engineering
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    • v.5 no.6
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    • pp.981-989
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    • 1994
  • For the development of new material used bentonite in ceramic/organic material composite, ABS(acrylonitrile-butadiene-styrene) material was used as a matrix polymer and a series of bentonite was blended together. This bentonite, filler like talc or mica for plastic material, was used since natural bentonite(Ca type) is easily obtainable in Korea, Na-bentonite changed from natural bentonite by $Na_2CO_3$ based on the specified compositions, changes in the static and dynamic mechanical properties. It was discovered that the increased content of natural and Na- bentonite results in higher modulus with reduced impact strength. And Rockwell hardness was constant. And Na- bentonite filled polymer showed improvement in impact strength and lower in modulus as the natural bentonite filled polymer. The storage modulus(E') of Na- bentonite filled ABS resin was higher than that of Ca- bentonite filled ABS resin, while higher temperature, storage modulus(E') decreased. At higher frequency, tan ${\delta}$ peak was shifted at high temperature.

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Synthesis and Ion Exchange Capacity of 2-Vinylpyridine Series Ion Exchange Resins (2-비닐피리딘계 이온교환수지의 합성과 그의 이온교환능)

  • Dong Won Kim;Hae Yong Song
    • Journal of the Korean Chemical Society
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    • v.25 no.3
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    • pp.160-165
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    • 1981
  • Radical copolymerization of the complexed 2-vinylpyridine with vinyl acetate and divinylbenzene initiated by azobisisobutyronitrile was carried out in N, N-dimethylformamide in presence of barium chloride at $98{\circ}C$. In the preparation of 2-vinylpyridine-vinylacetate-divinylbenzene terpolymer, the optimum reaction conditions were studied by means of various temperatures and times. 2-vinylpyridine-vinylalcohol-divinybenzene resin was prepared by transesterificating 2-vinylpyridine-vinylacetate-divinylbenzene terpolymer with a 1% methanolic sodium hydroxide solution. 2-Vinylpyridine-vinylphosphate-divinyldenzene was prepared by phosphorylating 2-vinylpyridine-vinylalcohol-divinylbenzene resin with phosphoric acid and urea. The compositions of each synthetic resin were identified by means of infrared absorption spectroscopy. The ion exchange capacities of each 2-vinylpyridine-vinylalcohol-divinylbenzene and 2-vinylpyridine-vinylphosphate-divinylbenzene terpolymer was 3.69 meq/g and 5.38 meq/g.

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Heat Dissipation Analysis of High Voltage Diode Package for Microwave oven (전자레인지용 고압다이오드의 방열특성)

  • Kim, Sang-Cheol;Kim, Nam-Kyun;Bahng, Wook;Seo, Gil-Soo;Moon, Seoung-Ju;Oh, Bang-Won
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.205-208
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    • 2001
  • Steady state and transient thermal analysis has been done by a finite element method in a diode of 12kV blocking voltage for microwave oven. The diode was fabricated by soldering ten pieces of 1200V diodes in series, capping a dummy wafer at the far end of diode series, and finally copper wire bonded for building anode and cathode terminal. In order to achieve high voltage and reliability, the edge of each diode was beveled and passivated by resin and epoxy with a thickness of $25{\mu}m$ and $3700{\mu}m$, respectively. The chip size, thickness and material properties were very important factor for high voltage diode package. And also, thermal stress value was highest in the edge of diode and solder. So, design of edge in silicon was very important to thermal stress.

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