• Title/Summary/Keyword: Resin composites

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Impacts of halloysite clay nanoparticles on the structural and γ-ray shielding properties of the epoxy resin

  • K.G. Mahmoud;M.I. Sayyed;S. Hashim;Aljawhara H. Almuqrin;Abu El-Soad A.M
    • Nuclear Engineering and Technology
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    • v.55 no.4
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    • pp.1585-1590
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    • 2023
  • In this study, halloysite nanoparticles-doped epoxy resin was synthesised using the casting method. The MH-300A density metre revealed that the density of the fabricated composites changed from 1.132 to 1.317 g/cm3 as the halloysite nanoparticle concentration increased. The Fourier transform infrared was recorded for the synthesised composites. Furthermore, the γ-ray shielding properties of the synthesised composites were evaluated using Monte Carlo simulation and a theoretical programme, XCOM. The linear attenuation coefficient of the epoxy resin increased by 43% (at γ-energy of 15 keV) and 14% (at γ-photon energy of 662 keV) when the concentration of the halloysite nanoparticles was increased from 0 wt% to 40 wt%, respectively.

Behavior of abrasive wear on counterpart roughness of glass fiber reinforcement polyurethane resin composites (상대재의 거칠기에 따른 GF/PUR 복합재료의 연삭마모거동)

  • Kim, Hyung-Jin;Koh, Sung-Wi;Kim, Jae-Dong
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.47 no.3
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    • pp.267-272
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    • 2011
  • The behavior of abrasive wear on counterpart roughness of glass fiber reinforcement polyurethane resin (GF/PUR) composites were investigated at ambient temperature by pin-on-disc friction test. The friction coefficient, cumulative wear volume and surface roughness of these materials against SiC abrasive paper were determined experimentally. The major failure mechanisms were lapping layers, ploughing, delamination, deformation of resin and cracking by scanning electric microscopy (SEM) photograph of the tested surface. As increasing the counterpart roughness the GF/PUR composites indicated higher friction coefficient. The surface roughness of the GF/PUR composites was increased as the sliding velocity was higher and the counterpart roughness was rougher in wear test.

Influence of Surface Free Energy of Carbon Black/Thermoplastic Resin Composites on PTC Characteristics

  • Park, Soo-Jin;Kim, Hyun-Chel;Lee, Jae-Rock
    • Carbon letters
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    • v.1 no.1
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    • pp.1-5
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    • 2000
  • The effect of surface free energy on the positive temperature coefficient (PTC) of carbon black/thermoplastic resin composites was investigated. The thermoplastic resins such as EVA, LDPE, LLDPE and HDPE were used with the addition of 30 wt.% of the carbon black. The surface free energy of the composites was studied in the context of two-liquid contact angle measurements, i.e., deionized water and diiodomethane. It was observed that the resistivity on PTC composites Was greatly increased near the crystalline melting temperature, due to the thermal expansion of polymeric matrix. From the experimental results, it was proposed that the decrease of surface free energy induced by interactions between carbon black surfaces and polymer chains is an important factor to the fabrication of a PTC composite made of carbon black and polymeric matrix.

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Parametric study on design of sandwich structures composing of fibre reinfoced composites, polymer foam and resin concrete (섬유강화 복합재료, 고분자 포움 및 레진 콘크리트로 구성된 샌드위치 구조 설계를 위한 파라메트릭 연구)

  • Kim D.I.;Chang S.H.
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2005.05a
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    • pp.429-434
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    • 2005
  • In this paper sandwich structures like beams and plates are optimised by using parametric study. The structures are composed of fibre reinforced composites for facial material and resin concrete and PVC foam for core materials. The stacking sequences and thickness of the composites are controlled as major parameters to find out the optimal condition for machine tool components. For the plate structure for machine tool bed composites-skined sandwich structure which has several ribs are proposed to enhance both directional bending stiffnesses at the same time. From the results optimal configuration and materials for high precesion machine tools are proposed.

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RHEOLOGICAL PROPERTIES OF RESIN COMPOSITES ACCORDING TO THE CHANGE OF MONOMER AND FILLER COMPOSITIONS (단량체 및 무기질 filler 조성 변화에 따른 복합레진의 유변학적 특성)

  • Lee In-Bog;Lee Jong-Hyuck;Cho Byung-Hoon;Son Ho-Hyun;Lee Sang-Tag;Um Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.29 no.6
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    • pp.520-531
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    • 2004
  • The aim of this study was to investigate the effect of monomer and filler compositions on the rheological properties related to the handling characteristics of resin composites. Methods. Resin matrices that Bis-GMA as base monomer was blended with TEGDMA as diluent at various ratio were mixed with the Barium glass (0.7 um and 1.0 um), 0.04 um fumed silica and 0.5 um round silica. All used fillers were silane treated. In order to vary the viscosity of experimental composites, the type and content of incorporated fillers were changed, Using a rheometer, a steady shear test and a dynamic oscillatory shear test were used to evaluate the viscosity ($\eta$) of resin matrix, and the storage shear modulus (G'), the loss shear modulus (G"), the loss tangent ($tan{\delta}$) and the complex viscosity (${\eta}^*$) ofthe composites as a function of frequency ${\omega}{\;}={\;}0.1-100{\;}rad/s$. To investigate the effect of temperature on the viscosity of composites, a temperature sweep test was also undertaken. Results. Resin matrices were Newtonian fluid regardless of diluent concentration and all experimental composites exhibited pseudoplastic behavior with increasing shear rate. The viscosity of composites was exponentially increased with increasing filler volume%. In the same filler volume, the smaller the fillers were used, the higher the viscosities were. The effect of filler size on the viscosity was increased with increasing filler content. Increasing filler content reduced $tan{\delta}$ by increasing the G' further than the G". The viscosity of composites was decreased exponentially with increasing temperature.

Nanoparticle effect on the mechanical properties of polymer composites (에폭시수지의 물성에 미치는 나노입자의 영향)

  • Moon, Chang-Kwon;Kim, Bu-Ahn
    • Journal of Power System Engineering
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    • v.19 no.5
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    • pp.12-16
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    • 2015
  • $TiO_2$ nanoparticle can be used for the improvement of performance of the epoxy resin composites. In this study, the effect of the size of $TiO_2$ nanoparticle on the mechanical properties for the epoxy resin composites was investigated. The size of $TiO_2$ nanoparticle was easily controlled by heat treatment. The heat treatment of $TiO_2$ nanoparticle was conducted between $700^{\circ}C$ and $900^{\circ}C$. The obtained size of $TiO_2$ nanoparticle was 20 nm, 100 nm and 200 nm respectively. As the diameter of $TiO_2$ nanoparticle is smaller, the epoxy resin composite specimen showed higher tensile strength. It was also found that Vickers hardness of epoxy resin was increased by the addition of $TiO_2$ nanoparticle. But the size of $TiO_2$ nanoparticle did not strongly affected to the Vickers hardness of this material. The fracture surface of epoxy resin showed clear difference by the size of $TiO_2$ nanoparticlet.

Comparison of Resin Impregnation and Mechanical Properties of Composites Based on Fiber Plasma Treatment (섬유 플라즈마 처리에 따른 복합재료의 수지 함침성 및 기계적 특성 비교)

  • Seong Baek Yang;Donghyeon Lee;Yongseok Lee;Dong-Jun Kwon
    • Composites Research
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    • v.36 no.6
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    • pp.388-394
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    • 2023
  • In composites manufacturing, increasing resin impregnation is a key way to speed up the manufacturing process and improve product quality. While resin improvement is important, simple fiber surface treatments can also improve resin flowability. In this study, different plasma treatment times were applied to carbon fiber fabrics to improve the impregnation between resin and fiber. Electrical resistivity measurements were used to evaluate the dispersion of resin in the fibers, which changed with plasma treatment. The effect of fiber surface treatment on resin spreadability could be observed in real time. When inserting a carbon fiber tow into the resin, the amount of resin that soaked into the tow was measured to objectively compare resin impregnation. Five minutes of plasma treatment improved the tensile and compressive strength of the composite by more than 50%, while reducing the void content and increasing the fire point impregnation flow rate. Finally, a dynamic flexural fatigue test was conducted using a portion of the composite used as an architectural composite part, and the composite part did not fail after one million cycles of a 3 kN load.

Strengthening of C/C Composites through Ceramer Matrix

  • Dhakate, S.R.;Mathur, R.B.;Dhami, T.L.
    • Carbon letters
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    • v.5 no.4
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    • pp.159-163
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    • 2004
  • The polymer-ceramic hybrid, known as 'ceramer', was synthesized by a sol-gel process by incorporating different amount of alkoxide as source of silicon in resorcinol-formaldehyde in presence of basic catalyst to get different percentage of silicon in ultimate carbonized composites. FTIR of the ceramer confirms that it is a network of Si-O-Si, Si-O-$CH_2$ and Si-OH type groups linked with benzene ring. Different amount of silicon in the ceramer exhibits varying temperature of thermal stability and lower coefficient of thermal expansion as compared to pure resorcinol-formaldehyde resin. The lower value of CTE in ceramer is due to existence of silica and resorcinol -formaldehyde in co-continuous phase. Unidirectional composites prepared with ceramer matrix and high-strength carbon fibers show lower value of flexural strength at polymer stage as compared to those prepared with resorcinol-formaldehyde resin. However, after heat treatment to $1450^{\circ}C$, the ceramer matrix composites show large improvement in the mechanical properties, i.e. with 7% silicon in the ceramer, the flexural strength is enhanced by 100% and flexural modulus value by 40% as compared to that of pure resorcinol-formaldehyde resin matrix composites.

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Development and mechanical properties of bagasse fiber reinforced composites

  • Cao, Yong;Goda, Koichi;Shibata, Shinichi
    • Advanced Composite Materials
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    • v.16 no.4
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    • pp.283-298
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    • 2007
  • Environment-friendly composites reinforced with bagasse fiber (BF), a kind of natural fiber as the remains from squeezed sugarcane, were fabricated by injection molding and press molding. As appropriate matrices for injection molding and press molding, polypropylene (PP) and polycaprolactone-cornstarch (PCL-C) were selected, as a typical recyclable resin and biodegradable resin, respectively. The mechanical properties of BF/PP composites were investigated in view of fiber mass fraction and injection molding conditions. And the mechanical properties and the biodegradation of BF/PCL composites were also evaluated. In the case of injection molding, the flexural modulus increased with an increase in fiber mass fraction, and the mechanical properties decreased with an increase in cylinder temperature due to the thermal degradation of BF. The optimum conditions increasing the flexural properties and the impact strength were $90^{\circ}C$ mold temperature, 30 s injection interval, and in the range of 165 to $185^{\circ}C$ cylinder temperature. On the other hand, as to BF/PCL-C fully-green composites, both the flexural properties and the impact strength increased with an increase in fiber mass fraction. It is considered that the BF compressed during preparation could result in the enhancement in mechanical properties. The results of the biodegradability test showed the addition of BF caused the acceleration of weight loss, which increased further with increasing fiber content. This reveals that the addition and the quantities of BF could promote the biodegradation of fully-green composites.