• Tribology and Lubricants
• /
• 제31권3호
• /
• pp.86-94
• /
• 2015

We perform lacquer formation experiments with various combinations of marine fuel oils and lubricant oils. We also investigate the influences of base number (BN) in lubricant oil and sulfur content in fuel oil. A dissolution test with 10% dilute sulfuric acid and pull-off force test are accomplished to distinguish whether the residual layers are lacquering or not. The lacquering layers are dissolved by dilute sulfuric acid and have a strong pull-off force. Moreover, the calcium content detected in the residual layers is compared by energy dispersive x-ray spectroscopy (EDS). More calcium is detected in the lacquer layers than in other residual layers. Distillate fuels containing low sulfur levels are more prone to lacquering when mixed with lubricant oil with a high BN. On the other hand, residual fuels with a high sulfur content do not form lacquer. We investigate the effect of mixture volume ratio. The mixture with higher fuel oil content is more prone to generate lacquer. These experiments indicate that a lubricant with an appropriate BN should be used to prevent lacquer forming on the surfaces such as cylinder liners depending on the sulfur content of fuel oil.

• Environmental Engineering Research
• /
• 제24권2호
• /
• pp.202-210
• /
• 2019

In order to maximize the utilization of sewage sludge, a waste from wastewater treatment facility, the residual sewage sludge generated after lipid and carbohydrate extraction for biodiesel and bioethanol production was used to produce bio-oil by pyrolysis. Thermogravimetric analysis showed that sludge pyrolysis mainly occurred between 200 and $550^{\circ}C$ (with peaks formed around 337.0 and $379.3^{\circ}C$) with the decomposition of the main components (carbohydrate, lipid, and protein). Bio-oil was produced using a micro-tubing reactor, and its yield (wt%, g-bio-oil/g-residual sewage sludge) increased with an increase in the reaction temperature and time. The maximum bio-oil yield of 33.3% was obtained after pyrolysis at $390^{\circ}C$ for 5 min, where the largest amount of energy was introduced into the reactor to break the bonds of organic compounds in the sludge. The main components of bio-oil were found to be trans-2-pentenoic acid and 2-methyl-2-pentenoic acid with the highest selectivity of 28.4% and 12.3%, respectively. The kinetic rate constants indicated that the predominant reaction pathway was sewage sludge to bio-oil ($0.1054min^{-1}$), and subsequently to gas ($0.0541min^{-1}$), rather than the direct conversion of sewage sludge to gas ($0.0318min^{-1}$).

• 한국기술사회:학술대회논문집
• /
• 한국기술사회 1984년도 제14회 한일기술사 합동 심포지움 참관기
• /
• pp.84-91
• /
• 1984

Heavy Residual Fuel oils is a mixture of reduced crude from crude unit, bottom products from vacuum and/or catalytic cracking unit with distillate to meet the specification and generally used as Heavy Fuel Oil for large combustion engines, boilers, etc…. But this study was made to investigate Heavy Residual Fuel oils for using as industrial raw material and resulted the following possibilties as valuable raw material as well as Heavy Fuel Oil. 1) Production of straight asphalt through vacuum distillation unit. 2) Using straight asphalt from vacuum distillation unit for manufacturing of Blown Asphalts, Cut Back Asphalts, Emulsified Asphalts and Asphalt Compound, etc…. 3) Using waxy oil side streams for manufacturing of raw oil to be Lube Oil base stocks through solvent dewaxing. 4) Production of lube base oils from dewaxed raw oil through chemical treatments. 5) Manufacturing of paraffine wax from slack wax to be produced as by product of dewaxing process.

• 한국식품위생안전성학회지
• /
• 제12권2호
• /
• pp.107-110
• /
• 1997

To examine the effects of residual phosphorus content on color reversion and storage stability of corn germ oil, the changes of Lovibond total color and stability of oxidation were determined according to the different storage periods at room and incubating temperature, respectively. The residual phosphorus content and storage temperature had the synergistic effect on color reversion during short time storage. The extent of color change was the greatest when oils were stored for 1.0∼1.5 years at room temperature and thereafter gradually tended to reverse color reversion. It is supposed that the double bonds of carotenoids in oils were oxidized and then turned to the volatiles such as epoxide, ionone, and etc. In contrast, the residual phosphorus content increased oxidation stability of oils. The residual phosphorus content was closely correlated with the color reversion and storage stability, respectively.

• 한국수소및신에너지학회논문집
• /
• 제22권4호
• /
• pp.534-545
• /
• 2011

This paper describes the evaluation of kinetic parameters for pyrolysis and carbon char oxidation of residual oil. The non-isothermal pyrolysis of residual oil was carried out with TGA (Thermo-Gravimetric Analyzer) at heating rate of 2, 5, 10 and $20^{\circ}C/min$ up to $800^{\circ}C$ under N2 atmosphere. The first order and nth order pyrolysis models were used to fit the experimental data, and the nth order model was turned out to follow the experimental data more precisely than the first order model. For carbon char oxidation experiment, TGA and four heating rates used in pyrolysis experiment were also adapted. The kinetic parameters for the residual carbon char particle were obtained with three char oxidation model, that is, volume reaction, grain and random pore model. Among them, the random pore model described the char oxidation behaviour quite well, compared to other two models. The non-linear regression method was used to obtain kinetic parameters for both pyrolysis and carbon char oxidation of residual oil.

• 대한조선학회논문집
• /
• 제56권3호
• /
• pp.263-272
• /
• 2019

The aim of this study is to develop a rapid calculation technique of the residual strength in order to prevent sequential events under grounding accidents. Very Large Crude-Oil Carrier (VLCC), Suezmax, and Aframax double hull oil tankers carrying large quantities of crude oil were selected for target structures. The rock geometries are chosen from the published regulation by Marine Pollution Treaty (MARPOL) of the International Maritime Organization (IMO). Oceanic rocks as the most frequently encountered obstruction with ships are applied in this work. Damage condition was predicted using ALPS/HULL program based on grounding scenario with selected parameters, i.e. depth of penetration, damage location and tanker type. The results of the scenarios are quantified to form an empirical formula which can evaluate the residual strength. The proposed formula is validated by applying a series of random grounding scenarios.

• 한국식품영양과학회지
• /
• 제24권2호
• /
• pp.214-218
• /
• 1995

Elimination of residual captan during the storage and cooking process was investigated. The concentration of residual captan after sticking and drying fo captan on spinach was 2.938ppm. During storage of 5, 10, 15 and 20 days at 15$^{\circ}C$, the amount of residual captan decreased to 73.18, 80.80, 89.99 and 98.40% of the initial amount, respectively. When spinach was stored at 3$^{\circ}C$, the concentration of residual captan decreased to 58.20, 61.37, 72.84 and 76.31% and the storage was carried out at -17$^{\circ}C$, residual captan amount decreased to 7.18, 22.67, 34.58 and 40.91% of the initial amout, respectively according to the storage period. In the case of the residual captan of seasoned spinach, the storage of 2, 24 and 48 hours at 15$^{\circ}C$, the amout of residual captan decreased to 0.772(39.69%), 0.661(77.50%) and 0.063ppm(97.86%) of the initial amount, respectively. When spinach was stored at 3$^{\circ}C$, the amount of residual captan decreased to 2.344 (20.22%), 1.021(65.25%) and 0.329ppm(88.80%) and the storage was carried out at -17$^{\circ}C$, residual captan amount decreased to 2.428(17.36%), 1.520(48.26%) and 0.726ppm(75.29%) of the initial amount, respectively according to the storage period. In the case of the residual captan of spinach cooked with edible oil for 2, 4 and 6 minutes and then cooking oil was discarded, each decreasing rate of the captan sticked to thespinach was 96.29, 97.86 and 99.18%, respectively. The rate of removed the captan sticked to the spinach with oil was 73.32, 86.32 and 87.13%, respectively. From these results, the storage in room temperature and the addition of seasoning to the spinach could lead to decrease in the concentration of the residual captan, furthemore the cooking could inhance decreasing of residual captan.

• Elastomers and Composites
• /
• 제20권2호
• /
• pp.115-131
• /
• 1985

Heavy residual fuel oils is a mixture of reduced crude from crude unit, bottom products from vacuum and/or catalytic cracking unit with distillate to meet the specification and generally used as heavy fuel oil for large combustion engines, boilers, etc$\cdots$. But this study was made to investigate heavy residual fuel oils for using as industrial raw material and resulted the following possiblities as valuable raw material as well as heavy fuel oil. 1) Production of straight asphalt through vacuum distillation unit. 2) Using straight asphalt from vacuum distillation unit for manufacturing of blown asphalts, cut back asphalts, emulsified asphalts and asphalt compound, rubber/asphalt sheet, etc$\cdots$. 3) Using waxy oil side streams for manufacturing of raw oil to be lube oil base stocks through solvent dewaxing. 4) Production of lube base oils and rubber process oils from dewaxed raw oil through chemical treatments. 5) Manufacturing of paraffine wax from slack wax to be produced as by product of dewaxing process.

• 한국수산과학회지
• /
• 제43권6호
• /
• pp.705-714
• /
• 2010

The residual oil concentrations in seawater and sediments were investigated along the Taean coast of Korea, following the Hebei Spirit oil spill, which occurred on 7 December 2007. The oil concentration in seawater ranged from 0.059 to $0.866\;{\mu}g/L$ for the tidal flat culture grounds and from 0.016 to $0.943\;{\mu}g/L$ in the fish cage areas in 2008. These were dominated by the seawater temperature relationship. Polycyclic aromatic hydrocarbons (PAHs) in sediments were also analyzed and the concentrations ranged from 3.4 to 509.7 ng/g dry weight. The average PAH level was higher in seawater from the Sinduri area than the Padori area, while the average PAH level in sediments was higher in Padori. The diagnostic ratio of PAHs was investigated to determine the origins of the PAHs. The PAHs in the Seongam area, which was not affected by the oil spill, are of pyrolytic origin, while the PAHs in Padori and Sinduri were of petrogenic origin. The residual oils in the areas affected by the oil spill tended to decrease over time, except in summer. The oils in pore water remained 6- to 16-fold higher, as compared to the seawater overlying the tidal flat, implying that residual oils will continue to influence the affected region for the foreseeable future.

• 에너지공학
• /
• 제17권2호
• /
• pp.107-115
• /
• 2008

신에너지원으로 주목받고 있는 중질 잔사유를 기존 중유화력의 대체 연료로 사용하는 경우에 대하여 상용 해석코드로 플랜트의 에너지 및 물질 수지, 플랜트의 성능을 분석하였다. 국내 A 중유 화력발전소에 대한 플랜트 성능분석 모델을 구축하였으며 플랜트의 성능 및 효율 등에 대한 시뮬레이션 결과를 설계 및 실제 운전 데이터와 비교하여 그 건전성을 확인하였다. 중질 잔사유 적용에 대한 시뮬레이션 결과 출력은 315 MW로서 중유 적용시의 300 MW 보다 높게 나타났으며 플랜트 효율은 약간 감소함을 알 수 있었다. 외기온도 및 냉각수 온도, 배가스 순환량, 출력에 따른 열소비율의 민감도 분석으로부터 중질 잔사유 연소시의 최적 운전을 위한 기본 자료를 얻을 수 있었다.