• Title/Summary/Keyword: Research Synthesis

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Luminescent Characteristics of CdSe Quantum Dot Phosphor Depending on Se Precursor Ratio (Se 전구체 함량 따른 CdSe 양자점 형광체의 발광특성)

  • Eom, Nu Si A;Kim, Taek-Soo;Choa, Yong-Ho;Kim, Bum Sung
    • Journal of Powder Materials
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    • v.19 no.6
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    • pp.442-445
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    • 2012
  • The quantum dots (QD) have unique electrical and optical properties due to quantum dot confinement effect. The optical properties of QDs are decided by various synthesis conditions. In a prior QDs study, a study on the QDs size with synthesis condition such as synthesis time and temperature is being extensively researched. However, the research on QDs size with composition ratio has hitherto received scant attention. In order to evaluate the ratio dependence of CdSe crystal, synthesis ratio of Se precursor is changed from 16.7 mol%Se to 44 mol%Se. As the increasing Se ratio, the band gap was increased. This is caused by red shift of emission. We confirmed optical property of CdSe QDs with composition ratio.

Control System Synthesis Using BMI: Control Synthesis Applications

  • Chung, Tae-Jin;Oh, Hak-Joon;Chung, Chan-Soo
    • International Journal of Control, Automation, and Systems
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    • v.1 no.2
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    • pp.184-193
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    • 2003
  • Biaffine Matrix Inequality (BMI) is known to provide the most general framework in control synthesis, but problems involving BMI's are very difficult to solve because nonconvex optimization should be solved. In the previous paper, we proposed a new solver for problems involving BMI's using Evolutionary Algorithms (EA). In this paper, we solve several control synthesis examples such as Reduced-order control, Simultaneous stabilization, Multi-objective control, $H_{\infty}$ optimal control, Maxed $H_2$ / $H_{\infty}$control design, and Robust $H_{\infty}$ control. Each of these problems is formulated as the standard BMI form, and solved by the proposed algorithm. The performance in each case is compared with those of conventional methods.

THERMAL PLASMA SYNTHESIS OF NANO-SIZED POWDERS

  • Seo, Jun-Ho;Hong, Bong-Guen
    • Nuclear Engineering and Technology
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    • v.44 no.1
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    • pp.9-20
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    • 2012
  • A brief review on the thermal plasma synthesis of nano-sized powders is presented according to the application materials, such as, metals, ceramics, glasses, carbonaceous materials and other functional composites, such as, supported metal catalyst and core-shell structured nano materials. As widely adopted plasma sources available for thermal plasma synthesis of nanosized powders, three kinds of plasma torches, such as transferred and non-transferred DC and RF plasma torches, are introduced with the main features of each torch system. In the basis of the described torch features and the properties of suggested materials, application results including synthesis mechanism are reviewed in this paper.

Electrochemical Synthesis of Compound Semiconductor Photovoltaic Materials

  • Yu, Bong-Yeong;Jeon, Byeong-Jun;Lee, Dong-Gyu
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.11.1-11.1
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    • 2010
  • As one of the non-vacuum, low temperature fabrication route, electrochemical synthesis has been focused for pursuing the cost-effective pathway to produce high efficiency photovoltaic devices. Especially the availability to form the thin film structure on flexible substrate would be the great advantage of electrochemical process. The successful synthesis of the most favorable absorber materials such as CdTe and CIGS has been reported by many researchers, however, the efficiency of electrochemically synthesized could not exceed that from vacuum process, because of microstructural controllability and compositional variation on devices. In this study, we represent the effect of process parameters on the microstructure and composition of compound semiconductor during the synthesis, and propose the photovoltaic characteristics of electrochemically synthesized solar cells.

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Phosgen-free Synthesis of Oligoureas Having Amino End-groups: Their Application to the Synthesis of Poly(urea-imide)

  • Chang, Ji-Young;Kim, Beom-Jin
    • Fibers and Polymers
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    • v.3 no.2
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    • pp.55-59
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    • 2002
  • The thermal reaction of acetoacetanilide in the presence of aniline or phenol yielded carbanilide in quantitative yields. This reaction was applied to the synthesis of polyurea. Bisacetoacetamides were prepared from diamines and diketene in DMF. They were thermally polymerized in the presence of phenol or a diamine (6FDA) to yield polyureas of low molecular weights. The polymers were soluble in DMSO and NMP. $^1{H-NMR}$ analysis showed that they had amino group terminated structures. Poly(urea-imide) was synthesized by the reaction of an oligourea diamine with pyromellitic dianhydride in NMP. The concentration of terminal amino groups was determined by an acid-base titration. The thermal property of poly(urea-imide) was evaluated by thermogravimetric analysis (TGA). Initial decompisition took place at 332-$350^{\circ}C$.

CONJUGATED MOLECULES FOR OPTOELECTRONIC DEVICES

  • Chuah, Beng-Sim;Li, Xiao-Chang;Cacialli, Franco;Davies, John-E.;Feeder, Neil;Friend, Richard-H.;Garnier, Francis;Holmes, Andrew-B.;Moratti, Stephen-C.;Sirringhaus, Henning
    • Proceedings of the Materials Research Society of Korea Conference
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    • 1998.08a
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    • pp.69.4-69
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    • 1998
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One-pot synthesis of PdAu bimetallic composite nanoparticles and their catalytic activities for hydrogen peroxide generation

  • Xiao, Xiangyun;Kang, Tae-Uook;Nam, Hyobin;Bhang, Suk Ho;Lee, Seung Yong;Ahn, Jae-Pyung;Yu, Taekyung
    • Korean Journal of Chemical Engineering
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    • v.35 no.12
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    • pp.2379-2383
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    • 2018
  • We report a facile one-pot aqueous-phase synthesis of PdAu bimetallic nanoparticles with different Pd/Au ratio. The synthesis was conducted by co-reduction of Pd and Au precursor using ascorbic acid as a reducing agent and in the presence of polyallylamine hydrochloride (PAH). By high-angle annular dark field scanning transmission electron microscopy (HAADF-STEM) and energy-dispersive X-ray spectrometry (EDS) analyses, we found that the synthesized nanoparticles had an onion-like core/shell/shell/shell structure with Au-rich core, Pd-rich shell, Au-rich shell, and Pd shell, respectively. We also investigated the catalytic performance of the synthesized PdAu nanoparticles toward hydrogen peroxide generation reaction.

Improving Mycoplasma ovipneumoniae culture medium by a comparative transcriptome method

  • Wang, Xiaohui;Zhang, Wenguang;Hao, Yongqing
    • Journal of Veterinary Science
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    • v.21 no.2
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    • pp.30.1-30.11
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    • 2020
  • Mycoplasma ovipneumoniae (Mo) is difficult to culture, resulting in many difficulties in related research and application. Since nucleotide metabolism is a basic metabolism affects growth, this study conducted a "point-to-point" comparison of the corresponding growth phases between the Mo NM151 strain and the Mycoplasma mycoides subsp. capri (Mmc) PG3 strain. The results showed that the largest difference in nucleotide metabolism was found in the stationary phase. Nucleotide synthesis in PG3 was mostly de novo, while nucleotide synthesis in NM151 was primarily based on salvage synthesis. Compared with PG3, the missing reactions of NM151 referred to the synthesis of deoxythymine monophosphate. We proposed and validated a culture medium with added serine to fill this gap and prolong the stationary phase of NM151. This solved the problem of the fast death of Mo, which is significant for related research and application.

View Synthesis and Coding of Multi-view Data in Arbitrary Camera Arrangements Using Multiple Layered Depth Images

  • Yoon, Seung-Uk;Ho, Yo-Sung
    • Journal of Multimedia Information System
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    • v.1 no.1
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    • pp.1-10
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    • 2014
  • In this paper, we propose a new view synthesis technique for coding of multi-view color and depth data in arbitrary camera arrangements. We treat each camera position as a 3-D point in world coordinates and build clusters of those vertices. Color and depth data within a cluster are gathered into one camera position using a hierarchical representation based on the concept of layered depth image (LDI). Since one camera can cover only a limited viewing range, we set multiple reference cameras so that multiple LDIs are generated to cover the whole viewing range. Therefore, we can enhance the visual quality of the reconstructed views from multiple LDIs comparing with that from a single LDI. From experimental results, the proposed scheme shows better coding performance under arbitrary camera configurations in terms of PSNR and subjective visual quality.

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Versatile Strategies for Fabricating Polymer Nanomaterials with Controlled Size and Morphology

  • Yoon, Hyeon-Seok;Choi, Moon-Jung;Lee, Kyung-Jin;Jang, Jyong-Sik
    • Macromolecular Research
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    • v.16 no.2
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    • pp.85-102
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    • 2008
  • The development of reliable synthetic routes to polymer nanomaterials with well-defined size and morphology is a critical research topic in contemporary materials science. The ability to generate nanometer-sized polymer materials can offer unprecedented, interesting insights into the physical and chemical properties of the corresponding materials. In addition, control over shape and geometry of polymer nanoparticles affords versatile polymer nanostructures, encompassing nanospheres, core-shell nanoparticles, hollow nanoparticles, nanorods/fibers, nanotubes, and nanoporous materials. This review summarizes a diverse range of synthetic methods (broadly, hard template synthesis, soft template synthesis, and template-free synthesis) for fabricating polymer nanomaterials. The basic concepts and significant issues with respect to the synthetic strategies and tools are briefly introduced, and the examples of some of the outstanding research are highlighted. Our aim is to present a comprehensive review of research activities that concentrate on fabrication of various kinds of polymer nanoparticles.