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A Study on the Improvement of Tool's Life by Applying DLC Sacrificial Layer on Nitride Hard Coated Drill Tools (드릴공구의 이종질화막상 DLC 희생층 적용을 통한 공구 수명 개선 연구)

  • Kang, Yong-Jin;Kim, Do Hyun;Jang, Young-Jun;Kim, Jongkuk
    • Journal of the Korean institute of surface engineering
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    • v.53 no.6
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    • pp.271-279
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    • 2020
  • Non-ferrous metals, widely used in the mechanical industry, are difficult to machine, particularly by drilling and tapping. Since non-ferrous metals have a strong tendency to adhere to the cutting tool, the tool life is greatly deteriorated. Diamond-like carbon (DLC) is one of the promising candidates to improve the performance and life of cutting tool due to their low frictional property. In this study, a sacrificial DLC layer is applied on the hard nitride coated drill tool to improve the durability. The DLC coatings are fabricated by controlling the acceleration voltage of the linear ion source in the range of 0.6~1.8 kV. As a result, the optimized hardness(20 GPa) and wear resistance(1.4 x 10-8 ㎣/N·m) were obtained at the 1.4 kV. Then, the optimized DLC coating is applied as an sacrificial layer on the hard nitride coating to evaluate the performance and life of cutting tool. The Vickers hardness of the composite coatings were similar to those of the nitride coatings (AlCrN, AlTiSiN), but the friction coefficients were significantly reduced to 0.13 compared to 0.63 of nitride coatings. The drilling test were performed on S55C plate using a drilling machine at rotation speed of 2,500 rpm and penetration rate of 0.25 m/rev. The result showed that the wear width of the composite coated drills were 200 % lower than those of the AlCrN, AlTiSiN coated drills. In addition, the cutting forces of the composite coated drills were 13 and 15 % lower than that of AlCrN, AlTiSiN coated drills, respectively, as it reduced the aluminum clogging. Finally, the application of the DLC sacrificial layer prevents initial chipping through its low friction property and improves drilling quality with efficient chip removal.

Reduction of VOCs and the Antibacterial Effect of a Visible-Light Responsive Polydopamine (PDA) Layer-TiO2 on Glass Fiber Fabric (Polydopamine (PDA)-TiO2 코팅 유리섬유 직물을 이용한 VOCs의 저감 성능 및 항균성 연구)

  • Park, Seo-Hyun;Choi, Yein;Lee, Hong Joo;Park, Chan-gyu
    • Journal of Environmental Health Sciences
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    • v.47 no.6
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    • pp.540-547
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    • 2021
  • Background: Indoor air pollutants are caused by a number of factors, such as coming in from the outside or being generated by internal activities. Typical indoor air pollutants include nitrogen dioxide and carbon monoxide from household items such as heating appliances and volatile organic compounds from building materials. In addition there is carbon dioxide from human breathing and bacteria from speaking, coughing, and sneezing. Objectives: According to recent research results, most indoor air pollution is known to be greatly affected by internal factors such as burning (biomass for cooking) and various pollutants. These pollutants can have a fatal effect on the human body due to a lack of ventilation facilities. Methods: We fabricated a polydopamine (PDA) layer with Ti substrates as a coating on supported glass fiber fabric to enhance its photo-activity. The PDA layer with TiO2 was covalently attached to glass fiber fabric using the drop-casting method. The roughness and functional groups of the surface of the Ti substrate/PDA coated glass fiber fabric were verified through infrared imaging microscopy and field emission scanning electron microscopy (FE-SEM). The obtained hybrid Ti substrate/PDA coated glass fiber fabric was investigated for photocatalytic activity by the removal of ammonia and an epidermal Staphylococcus aureus reduction test with lamp (250 nm, 405 nm wavelength) at 24℃. Results: Antibacterial properties were found to reduce epidermal staphylococcus aureus in the Ti substrate/PDA coated glass fiber fabric under 405 nm after three hours. In addition, the Ti substrate/PDA coated glass fiber fabric of VOC reduction rate for ammonia was 50% under 405 nm after 30 min. Conclusions: An electron-hole pair due to photoexcitation is generated in the PDA layer and transferred to the conduction band of TiO2. This generates a superoxide radical that degrades ammonia and removes epidermal Staphylococcus aureus.

Effect of Nitrogen Plasma Surface Treatment of Rice Husk-Based Activated Carbon on Electric Double-Layer Capacitor Performance (질소 플라즈마 표면처리가 쌀겨 기반 활성탄소의 전기 이중층 커패시터 성능에 미치는 영향)

  • Lee, Raneun;Kwak, Cheol Hwan;Lee, Hyeryeon;Kim, Seokjin;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.71-77
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    • 2022
  • To increase biomass utilization, rice husk-based activated carbon (RHAC) followed by nitrogen plasma surface treatment was prepared and the electric double-layer capacitor performance was investigated. Through nitrogen plasma surface treatment, up to 2.17% of nitrogen was introduced to the surface of RHAC, and in particular the sample reacted for 5 min with nitrogen plasma showed dominant formation of pyrrolic/pyridine N functional groups. In addition, mesopores were formed on the RHAC material by the removal of silica, and the surface roughness of the carbon material increased by nitrogen plasma surface treatment, resulting in the formation of many micropores. As a result of cyclic voltammetry measurement, at a scan rate of 5 mV/s, the specific capacitance of the RHAC treated with nitrogen plasma increased up to 200 F/g, showing an 80.2% improvement compared to that of using untreated RHAC (111 F/g). This is attributed to the synergetic effect of the introduction of pyrrolic/pyridine-based nitrogen functional groups and the increase of the micropore volume on the surface of the carbon material. This study has a positive effect on the environment in terms of recycling waste resources and using plasma surface treatment.

Appropriate Technology and Field Application of Non-powered Water Purification System Using Nanofiber Membrane (나노섬유 멤브레인 기반 무동력 정수 시스템의 적정기술 및 현장 적용)

  • Lee, Jin;Yun, Byeong Gweon;Han, Kyoung Gu;Lee, Seung Hoon;Kim, Cheol Hyeon;Kim, Chan;Lee, Yunho;Lee, Dongwhi;Lee, Seunghyeok;Kim, Kyoung-Woong
    • Journal of Appropriate Technology
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    • v.7 no.1
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    • pp.72-81
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    • 2021
  • Gravity-driven membrane (GDM) filtration system based on the nanofiber membrane was investigated. This system can be operated with little energy demand due to a gravitational pressure-driven filtration and biological fouling control strategy. Moreover, the optimal module configuration based on the high permeance of nanofiber membrane can provide a significantly high water productivity. In order to evaluate its applicability potential, the pilot-scale (3000-5000 L/day) systems with nanofiber membranes were operated in developing countries (Kiribati and Tuvalu). Our results showed that the 14-92 L/(m2×h) of the permeate flux was determined indicating a stabilized water productivity. In addition, the permeate water indicated a high removal rate (more than 99.99%) of turbidity and bacteria. Consequently, the system can provide a stabilized water production with safe permeate water quality during long-term operation. These findings exemplify an effective approach to decentralized drinking water treatment for developing countries.

Recovery Process of Vanadium from the Leaching Solution of Salt-Roasted Vanadate Ore (바나듐광 염배소물 수침출 용액으로부터 바나듐 회수공정 고찰)

  • Yoon, Ho-Sung;Heo, Seo-Jin;Park, Yu-Jin;Kim, Chul-Joo;Chung, Kyeong Woo;Kim, Rina;Jeon, Ho-Seok
    • Resources Recycling
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    • v.31 no.2
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    • pp.40-48
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    • 2022
  • In this study, the effects of solution components were investigated in the recovery of vanadium as ammonium metavanadate from vanadium-ore-salt roasting-water leaching solution. The vanadium-containing solution is strongly alkaline (pH 13), so the pH must be lowered to 9 or less to increase the ammonium metavanadate precipitation efficiency. However, in the process of adjusting the solution pH using sulfuric acid, aluminum ions are co-precipitated, which must be removed first. In this study, aluminum was precipitated in the form of an aluminum-silicate compound using sodium silicate, and the conditions for minimizing vanadium loss in this process were investigated. After aluminum removal, the silicate was precipitated and removed by adjusting the solution pH to 9 or less using sulfuric acid. In this process, the concentration and addition rate of sulfuric acid have a significant influence on the loss of vanadium, and vanadium loss was minimized as much as possible by slowly adding dilute sulfuric acid. Ammonium metavanadate was precipitated using three equivalents of ammonium chloride at room temperature from the aluminum-free, aqueous solution of vanadium following the pH adjustment process. The recovery yield of vanadium in the form of ammonium metavanadate exceeded 81%. After washing the product, vanadium pentoxide with 98.6% purity was obtained following heat treatment at 550 ℃ for 2 hours.

Antioxidant and Elastase Inhibitory Effects of Equisetum hyemale Extract (속새(Equisetum hyemale) 추출물의 항산화 및 Elastase 저해 효과)

  • Song, Jin Hwa;Song, Hyun Sook;Lee, Geo Lyong
    • Journal of Naturopathy
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    • v.10 no.2
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    • pp.86-92
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    • 2021
  • Background: The presence of antioxidants was not confirmed in the medicinal plant Equisetum hyamale grass. Purposes: This study was to determine the antioxidant and elastase inhibition effects of extracts of E. hyemale. Methods: Antioxidant functions of E. hyemale stems and roots were measured and extracted with hot water (HW) and ethyl alcohol (70EOH, 100EOH). Results: The extraction yield of stems was higher in HW extraction than in ethyl alcohol extraction. The polyphenol content was significantly higher in the root extract than in the stem. Total flavonoid content of 70EOH extract was significantly higher in root extract than in stem. The elastase inhibitory function of the extract was 46% in the root and 49% in the stem at 100 ppm of the extract. The ABTS free radical scavenging function was in the order of HW<70EOH<100EOH

Scavenging Efficiency Based on Long-Term Characteristics of Precipitation and Particulate Matters in Seoul, Korea (서울지역 장기간 강수와 미세먼지의 특성 분석에 기반한 미세먼지 세정효과)

  • Suji Han;Junshik Um
    • Atmosphere
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    • v.33 no.4
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    • pp.367-385
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    • 2023
  • The variabilities of precipitation and particulate matters (i.e., PM10 and PM2.5) and the scavenging efficiency of PMs by precipitation were quantified using long-term measurements in Seoul, Korea. The 21 years (2001~2021) measurements of precipitation and PM10 mass concentrations, and the 7 years (2015~2021) of PM2.5 mass concentrations were used. Statistical analysis was performed for each period (i.e., year, season, and month) to identify the long-term variabilities of PMs and precipitation. PM10 and PM2.5 decreased annually and the decreasing rate of PM10 was greater than PM2.5. The precipitation intensity did not show notable variation, whereas the annual precipitation amount showed a decreasing trend. The summer precipitation amount contributed 61.10% to the annual precipitation amount. The scavenging efficiency by precipitation was analyzed based on precipitation events separated by 2-hour time intervals between hourly precipitation data for 7 years. The scavenging efficiencies of PM10 and PM2.5 were quantified as a function of precipitation characteristics (i.e., precipitation intensity, amount, and duration). The calculated average scavenging efficiency of PM10 (PM2.5) was 39.59% (35.51%). PM10 and PM2.5 were not always simultaneously scavenged due to precipitation events. Precipitation events that simultaneously scavenged PM10 and PM2.5 contributed 42.24% of all events, with average scavenging efficiency of 42.93% and 43.39%. The precipitation characteristics (i.e., precipitation intensity, precipitation amount, and precipitation duration) quantified in these events were 2.42 mm hr-1, 15.44 mm, and 5.51 hours. This result corresponds to 145% (349%; 224%) of precipitation intensity (amount; duration) for the precipitation events that do not simultaneously scavenge PM10 and PM2.5.

Environmental Maintenance Technology for Concrete Manufacturing Industry by Using an Automatic Fugitive Dust Reduction System (비산먼지 자동 저감시스템을 이용한 콘크리트 제조업 환경 유지관리 기술)

  • Hyun-Woo Cho;Yoon-Seok Chung;Deuk-Hyun Ryu;Yun-Yong Kim
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.27 no.4
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    • pp.70-77
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    • 2023
  • Fine dust is a cause of serious ecological problems, and fugitive dust generated from construction sites is a major source of fine dust in Korea. However, at construction sites, including concrete manufacturing industry sites, measurements are rarely made at the fugitive dust generation stage, and passive removal methods are the majority. Therefore, in this study, a fugitive dust measurement method suitable for managing fugitive dust generated during aggregate unloading in the concrete manufacturing industry sites was selected. In addition, the purpose was to analyze the amount of fugitive dust reduction according to the operation of the reduction system by applying the automatic fugitive dust reduction system to the aggregate unloading site. As a result, the reliability of the light scattering method was secured through the comparative measurement of the beta-ray absorption method and the light scattering method, and the light scattering method correction coefficient was calculated and applied to the measured value of the fugitive dust particle mass concentration at the concrete manufacturing industry sites. In addition, the fugitive dust reduction rate according to the operation of the automatic fugitive dust reduction system was derived.

Improvement of Consolidation Characteristics around PVD Using the Thermal Method (열적 방법을 이용한 연직배수재 주변의 압밀특성 연구)

  • Bergado, Dennes T.;Shin, Eun-Chul;Park, Jeong-Jun
    • Journal of the Korean Geotechnical Society
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    • v.23 no.10
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    • pp.5-11
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    • 2007
  • This paper is to investigate the removal of the smear at elevated temperatures. This study utilized both small cylinder cell and large consolidometer apparatus to investigate the combination of PVD with heat and without heat. Two types of heaters are used in this study. The heater drain made of copper tube is used for all tests except large consolidometer and flexible wire heater is used for large consolidometer. Specimens demonstrated volume contraction upon heat and without heat. This contraction is dependent on temperature magnitude. When the specimen is heated, the magnitude of settlements is higher and rate of consolidation is faster. After treatment using PVD combined without heat and with heat for undisturbed specimens the $C_h$ values obtained were $3.45m^2/yr$ and $3.83m^2/yr$, respectively, from $3.2m^2/yr$ before treatment. The $K_h/K_s$ ratios were 3 for the specimen without heat and 2 for the specimen with heat. Similarly, in reconstituted specimens without heat and with heat, the $C_h$ values were $2.1m^2/yr$ and $2.5m^2/yr$ with $K_h/K_s$ ratios of 1.75 and 1.5, respectively.

An Estimation on the Applicability of Hollow FRP Soil Nailing System (중공식 FRP쏘일네일링 시스템의 적용성 평가)

  • Lee, Hyuk-Jin;Koh, Hyung-Seon;Han, Yong-Hee;Kim, Hong-Taek
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.6C
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    • pp.385-393
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    • 2006
  • Soil nailing is a reinforcement method used for stabilizing excavated walls or slopes. Due to its much advantages such as ease of construction and economical efficiency, use of soil nailing is increased. However, the soil nail has much disadvantages for use in urban area. The soil nail needs to be installed inevitably beyond private land boundary, which causes rent for use. For this reason, removable soil nailing system was developed. However, the removal rate of this system is just about 50¢¦70%. To resolve this problem, the Fiber Reinforced Plastic (FRP) soil nailing system which does not need to be removed and allows for the installation beyond private land, is developed. In this paper, through theoretical and experimental studies in laboratory and field such as prototype tests, pullout tests, we evaluate the stability and behavior characteristics of the FRP soil nailing system. And, numerical analyses using FLAC2D were performed with respect to various soil conditions, where prototype test for excavation wall and pullout tests were carried out. As a result of this study, the FRP soil nailing systems show similar behavior characteristics with those of removable soil nailing system. Finally, considering the serviceability and mechanical stability of FRP soil nailing systems, it is enough to be used as a good alternative of general soil nailing system.